Abstract
The prompt-γ activation analysis (PGAA) laboratory of the Budapest Neutron Centre has been actively involved in national, international collaborations and EU-funded transnational access programs since 1999. The main applications are in material science, nuclear data measurement, method development, cultural heritage science and geology. PGAA was found to be ideal for the analysis of many light and medium-Z elements as major and minor components (down to 10–100 ppm), plus some traces, like H, B, Cl, Hg, noble metals and rare-earth elements. Being a real-time probing method, it is also possible to generate time- or spatially-resolved data. This paper reviews our activities in the past fifteen years, presents highlights of user-driven research projects and gives a summary about currently running and future access programs.
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References
Molnár GL (ed) (2004) Handbook of prompt gamma activation analysis with neutron beams. Kluwer Academic Publisher, Dordrecht, pp 1–423
Lehmann EH, Vontobel P, Frei G, Kuehne G, Kaestner A (2011) How to organize a neutron imaging user lab? 13 years of experience at PSI, CH. Nucl Instrum Methods Phys Res A 651:1–5
Révay Zs, Kudějová P, Kleszcz K, Söllradl S, Genreith C (2015) In-beam activation analysis facility at MLZ, Garching. Nucl Instrum Methods A 799:114–123
Paul RL, Sahin D, Cook JC, Brocker C, Lindstrom RM, O’Kelly DJ (2015) NGD cold-neutron prompt gamma-ray activation analysis spectrometer at NIST. J Radioanal Nucl Chem 304:189–193
Molnár G, Belgya T, Dabolczi L, Fazekas B, Révay Zs, Veres Á, Bikit I, Kis Z, Östör J (1997) The new prompt gamma-activation analysis facility at Budapest. J Radioanal Nucl Chem 215:111–115
Belgya T, Révay Zs, Fazekas B, Héjja I, Dabolczi L, Molnár GL, Kis Z, Östör J, Kaszás Gy (1997) In: Molnár G, Belgya T, Révay Zs (eds) Proceedings of 9th international symposium on capture gamma-ray spectroscopy and related topics, Budapest, Hungary, 8–12 October. Springer, Budapest, p 826
Rosta L, Belgya T, Cser L, Grosz T, Kaszás G, Molnár G, Révay Z, Török G (1997) Neutron guide system at the Budapest Research Reactor. Physica B 234:1196
Révay Zs, Belgya T, Kasztovszky Zs, Weil JL, Molnár GL (2004) Cold neutron PGAA facility at Budapest. Nucl Instrum Methods B 213:385
Ember PP, Belgya T, Weil JL, Molnár GL (2002) Coincidence measurement setup for PGAA and nuclear structure studies. Appl Radiat Isot 57:573–577
Révay Zs, Belgya T, Szentmiklósi L, Kis Z (2008) Recent developments and applications at the prompt gamma activation analysis facility at Budapest. J Radioanal Nucl Chem 278:643–646
Szentmiklósi L, Belgya T, Révay Z, Kis Z (2010) Upgrade of the prompt-gamma activation analysis (PGAA) and the neutron induced prompt-gamma spectroscopy (NIPS) facilities at the Budapest Research Reactor. J Radioanal Nucl Chem 286:501–505
Belgya T, Kis Z, Szentmiklósi L, Kasztovszky Z, Festa G, Andreanelli L, De Pascale MP, Pietropaolo A, Kudejova P, Schulze R, Materna T (2008) A new PGAI–NT setup at the NIPS facility of the Budapest Research Reactor. J Nucl Radioanal Chem 278(3):713–718
Belgya T, Kis Z, Szentmiklósi L, Kasztovszky Z, Kudejova P, Schulze R, Materna T, Festa G, Caroppi PA (2008) First elemental imaging experiments on a combined PGAI and NT setup at the Budapest Research Reactor. J Nucl Radioanal Chem 278(3):751–754
Szentmiklósi L, Kis Z, Belgya T, Berlizov AN (2013) On the design and installation of a Compton-suppressed HPGe spectrometer at the Budapest neutron-induced prompt gamma spectroscopy (NIPS) facility. J Nucl Radioanal Chem 298(3):1605–1611
Kis Z, Szentmiklosi L, Belgya T (2015) NIPS–NORMA station—a combined facility for neutron-based nondestructive element analysis and imaging at the Budapest Neutron Centre. Nucl Instrum Methods Phys Res A 779:116–123
Révay Zs, Firestone RB, Belgya T, Molnár GL (2004) Catalog and atlas of prompt gamma rays. In: Molnár GL (ed) Handbook of prompt gamma activation analysis with neutron beams. Kluwer Academic Publishers, Dordrecht, pp 173–364
Fazekas B, Molnár G, Belgya T, Dabolczi L, Simonits A (1997) Introducing HYPERMET-PC for automatic analysis of complex gamma-ray spectra. J Nucl Radioanal Chem 215(2):271–277
Révay Z (2009) Determining elemental composition using prompt gamma activation analysis. Anal Chem 81:6851–6859
Revay Z, Belgya T, Szentmiklosi L, Kis Z, Wootsch A, Teschner D, Swoboda M, Schlogl R, Borsodi J, Zepernick R (2008) In situ determination of hydrogen inside a catalytic reactor using prompt gamma activation analysis. Anal Chem 80(15):6066–6071
Teschner D, Borsodi J, Wootsch A, Revay Z, Havecker M, Knop-Gericke A, Jackson SD, Schlogl R (2008) The roles of subsurface carbon and hydrogen in palladium-catalyzed alkyne hydrogenation. Science 320(5872):86–89
Kovnir K, Armbrüster M, Teschner D, Venkov T, Szentmiklósi L, Jentoft FC, Knop-Gericke A, Grin Yu, Schlögl R (2009) In situ surface characterization of the intermetallic compound PdGa—a highly selective hydrogenation catalyst. Surf Sci 603:1784–1792
Armbruster M, Kovnir K, Friedrich M, Teschner D, Wowsnick G, Hahne M, Gille P, Szentmiklosi L, Feuerbacher M, Heggen M, Girgsdies F, Rosenthal D, Schlogl R, Grin Y (2012) Al13Fe4 as a low-cost alternative for palladium in heterogeneous hydrogenation. Nat Mater 11(8):690–693
Teschner D, Farra R, Yao LD, Schlogl R, Soerijanto H, Schomacker R, Schmidt T, Szentmiklosi L, Amrute AP, Mondelli C, Perez-Ramirez J, Novell-Leruth G, Lopez N (2012) An integrated approach to Deacon chemistry on RuO2-based catalysts. J Catal 285(1):273–284
Teschner D, Novell-Leruth G, Farra R, Knop-Gericke A, Schlogl R, Szentmiklosi L, Hevia MG, Soerijanto H, Schomacker R, Perez-Ramirez J, Lopez N (2012) In situ surface coverage analysis of RuO2-catalysed HCl oxidation reveals the entropic origin of compensation in heterogeneous catalysis. Nat Chem 4(9):739–745
Farra R, García-Melchor M, Eichelbaum M, Hashagen M, Frandsen W, Allan J, Girgsdies F, Szentmiklósi L, López N, Teschner D (2013) Promoted ceria: a structural, catalytic, and computational study. ACS Catal 3(10):2256–2268
Moser M, Vilé G, Colussi S, Krumeich F, Teschner D, Szentmiklósi L, Trovarelli A, Perez-Ramirez J (2015) Structure and reactivity of ceria-zirconia catalysts for bromine and chlorine production via the gas-phase oxidation of hydrogen halides. J Catal 331:128–137
Mukherji D, Gilles R, Karge L, Strunz P, Beran P, Eckerlebe H, Stark A, Szentmiklósi L, Mácsik Z, Schumacher G, Zizak I, Hofmann M, Hoelzel M, Rosler J (2014) Neutron and synchrotron probes in the development of Co–Re-based alloys for next generation gas turbines with an emphasis on the influence of boron additives. J Appl Crystallogr 47:1417–1430
Mukherji D, Rösler J, Wehrs J, Strunz P, Beran P, Gilles R, Hofmann M, Hoelzel M, Eckerlebe H, Szentmiklósi L, MácSik Z (2013) Application of in situ neutron and X-ray measurements at high temperatures in the development of Co–Re-based alloys for gas turbines. Metall Mater Trans A 44(1):22–30
Mukherji D, Rösler J, Krueger M, Heilmaier M, Bölitz M-C, Völkl R, Glatzel U, Szentmiklósi L (2012) Effects of boron addition on microstructure and mechanical properties of Co–Re-based high temperature alloys. Scr Mater 66:60–63
Hosseini AM, Tungler A, Schay Z, Szabo S, Kristof J, Szeles E, Szentmiklosi L (2012) Comparison of precious metal oxide/titanium monolith catalysts in wet oxidation of wastewaters. Appl Catal B 127:99–104
Pamukchieva V, Szekeres A, Todorova K, Fabian M, Svab E, Revay Z, Szentmiklosi L (2009) Evaluation of basic physical parameters of quaternary Ge.Sb–(S, Te) chalcogenide glasses. J Noncryst Solids 355(50–51):2485–2490
Käppeler F, Belgya T, Dillmann I, Domingo Pardo C, Giesen U, Heil M, Lederer C, Petrich D, Uberseder E (2011) EFNUDAT synergies in astrophysics. In: Chiaveri E (ed) Proceedings of the final scientific EFNUDAT workshop, 30 August–2 September 2010. European Laboratory for Particle Physics: CERN, Geneva, p 9–15
Rossbach M, Genreith C, Randriamalala T, Mauerhofer E, Revay Z, Kudejova P, Söllradl S, Belgya T, Szentmiklosi L, Firestone RB, Hurst AM, Bernstein LA, Sleaford B, Escher JE (2015) TANDEM: a mutual cooperation effort for transactinide nuclear data evaluation and measurement. J Nucl Radioanal Chem 304:1359–1363
Genreith C, Rossbach M, Mauerhofer E, Belgya T, Caspary G (2013) Measurement of thermal neutron capture cross sections of Np-237 and Pu-242 using prompt gamma neutron activation. J Nucl Radioanal Chem 296(2):699–703
Belgya T, Bouland O, Noguere G, Plompen A, Schillebeeckx P, Szentmiklosi L (2007) The thermal neutron capture cross section of 129I. In: International conference on nuclear data for science and technology, 2008. EDP Sciences, Niza, p 631–634
Hurst AM, Firestone RB, Basunia MS, Sleaford B, Summers N, Escher J, Révay Z, Szentmiklósi L, Belgya T (2014) A structural evaluation of the tungsten isotopes via thermal neutron capture. Phys Rev C 89(1):014606
Borella A, Belgya T, Kopecky S, Gunsing F, Moxon MC, Rejmund M, Schillebeeckx P, Szentmiklósi L (2011) Determination of the 209Bi(n, γ)210Bi and 209Bi(n, γ)210m,gBi reaction cross sections in a cold neutron beam. Nucl Phys A 850(1):1–21
Massarczyk R, Schramm G, Junghans AR, Schwengner R, Anders M, Belgya T, Beyer R, Birgersson E, Ferrari A, Grosse E, Hannaske R, Kis Z, Kögler T, Kosev K, Marta M, Szentmiklósi L, Wagner A, Weil JL (2013) Electromagnetic dipole strength up to the neutron separation energy from 196Pt(γ, γ′) and 195Pt(n, γ) reactions. Phys Rev C 87:044306
Schramm G, Massarczyk R, Junghans AR, Belgya T, Beyer R, Birgersson E, Grosse E, Kempe M, Kis Z, Kosev K, Krticka M, Matic A, Schilling KD, Schwengner R, Szentmiklosi L, Wagner A, Weil JL (2012) Dipole strength in Se-78 below the neutron separation energy from a combined analysis of Se-77(n, γ)and Se-78(γ, γ′) experiments. Phys Rev C 85(1):014311
Wallner A, Belgya T, Bichler M, Buczak K, Dillmann I, Käppeler F, Lederer C, Mengoni A, Quinto F, Steier P, Szentmiklósi L (2014) Novel method to study neutron capture of U-235 and U-238 simultaneously at keV energies. Phys Rev Lett 112(19):192501.6
Wallner A, Buczak K, Belgya T, Bichler M, Coquard L, Dillmann I, Forstner O, Golser R, Käppeler F, Kutschera W, Lederer C, Mengoni A, Priller A, Reifarth R, Steier P, Szentmiklosi L (2010) Precise measurement of the neutron capture reaction 54Fe(n, γ)55Fe via AMS, in Nuclear Physics in Astrophysics IV. 2010, Journal of Physics Conference Series 202: Lab. Nazionali di Frascati with Lab. Nazionali del Gran Sasso, 8–12 June 2009, p 012020
Oberstedt S, Belgya T, Billnert R, Borcea R, Cano-Ott D, Göök A, Hambsch FJ, Karlsson J, Kis Z, Martinez T, Oberstedt A, Szentmiklósi L, Takács K (2010) Correlation measurements of fission–fragment properties. In: EFNUDAT user and collaboration workshop: measurements and models of nuclear reactions, EPJ web of conferences 8, Paris, France, 25–27 May 2010, p 03005
Oberstedt S, Billnert R, Belgya T, Borcea R, Bryś T, Geerts W, Göök A, Hambsch F-J, Kish Z, Martinez Perez T, Oberstedt A, Szentmiklósi L, Vidali M (2014) New prompt fission γ-ray data in response to the OECD/NEA high priority request. Nucl Data Sheets 119:225–228
Oberstedt A, Belgya T, Billnert R, Borcea R, Bryå T, Geerts W, Göök A, Hambsch FJ, Kis Z, Martinez T, Oberstedt S, Szentmiklosi L, Takàcs K, Vidali M (2013) Improved values for the characteristics of prompt-fission γ-ray spectra from the reaction 235U(nth, f). Phys Rev C 87(5):051602.5
Oberstedt S, Billnert R, Belgya T, Bryś T, Geerts W, Guerrero C, Hambsch F-J, Kis Z, Moens A, Oberstedt A, Sibbens G, Szentmiklósi L, Vanleeuw D, Vidali M (2014) High-precision prompt-γ-ray spectral data from the reaction 241Pu(nth, f). Phys Rev C 90(2):024618.6
Kiss V, Fischl K, Horváth E, Káli G, Kasztovszky Z, Kis Z, Maróti B, Szabó G (2015) Non-destructive analyses of bronze artefacts from Bronze Age Hungary using neutron-based methods. J Anal At Spectrom 30(3):685–693
Mödlinger M, Piccardo P, Kasztovszky Z, Kovács I, Szokefalvi-Nagy Z, Káli G, Szilágyi V (2013) Archaeometallurgical characterization of the earliest European metal helmets. Mater Charact 79:22–36
Rogante M, Kasztovszky Z, Manni A (2010) Prompt Gamma Activation Analysis of bronze fragments from archaeological artefacts. Not Neutroni Luce Sincrotrone 15(1):12–23
Corsi J, Maroti B, Re A, Kasztovszky Z, Szentmiklosi L, Torbagyi M, Agostino A, Angelici D, Allegretti S (2015) Compositional analysis of a historical collection of Cisalpine Gaul’s coins kept at the Hungarian National Museum. J Anal At Spectrom 30(3):730–737
Rehren T, Belgya T, Jambon A, Káli G, Kasztovszky Z, Kis Z, Kovács I, Maróti B, Martinón-Torres M, Miniaci G, Pigott VC, Radivojević M, Rosta L, Szentmiklósi L, Szokefalvi-Nagy Z (2013) 5,000 years old Egyptian iron beads made from hammered meteoritic iron. J Archaeol Sci 40(12):4785–4792
Watkinson D, Rimmer M, Kasztovszky Z, Kis Z, Maróti B, Szentmiklósi L (2014) The use of neutron analysis techniques for detecting the concentration and distribution of chloride ions in archaeological iron. Archaeometry 56(5):841–859
Abraham E, Bessou M, Ziegle A, Herve MC, Szentmiklósi L, Kasztovszky Z, Kis Z, Menu M (2014) Terahertz, X-ray and neutron computed tomography of an Eighteenth Dynasty Egyptian sealed pottery. Appl Phys A 117(3):963–972
Prudêncio M, Dias M, Burbidge C, Kasztovszky Z, Marques R, Marques J, Cardoso G, Trindade M, Maróti B, Ruiz F, Esteves L, Matos M, Pais A (2016) PGAA, INAA and luminescence to trace the “history” of “The Panoramic View of Lisbon”: Lisbon before the earthquake of 1755 in painted tiles (Portugal). J Radioanal Nucl Chem 307:541–547
Bernardini F, De Min A, Lenaz D, Kasztovszky Z, Turk P, Velušček A, Szilágyi V, Tuniz C, Montagnari E (2014) Kokelj, mineralogical and chemical constraints on the provenance of Copper Age polished stone axes of ‘Ljubljana Type’ from Caput Adri. Archaeometry 56(2):175–202
Kasztovszky Zs, Kunicki-Goldfinger J (2011) Applicability of prompt gamma activation analysis to glass archaeometry. In: Proceedings of the 37th international symposium on archaeometry, Siena, Italy, 13–16 May 2008, p 83–90
Zöldföldi J, Richter S, Kasztovszky Zs, Mihály J (2006) Where does lapis lazuli come from? In: 34th International symposium on archaeometry, Zaragoza, 2004. Insttitución “Fernando el Católico” (C.S.I.C.) Excma. Diputación de Zaragoza, p 353–361
Marschall HR, Kasztovszky Z, Gméling K, Altherr R (2005) Chemical analysis of high-pressure metamorphic rocks by PGNAA: comparison with results from XRF and solution ICP-MS. J Radioanal Nucl Chem 265(2):339–348
Marschall HR, Altherr R, Ludwig T, Kalt A, Gméling K, Kasztovszky Z (2006) Partitioning and budget of Li, Be and B in high-pressure metamorphic rocks. Geochim Cosmochim Acta 70(18):4750–4769
Kodolányi J, Pettke T, Spandler C, Kamber BS, Gméling K (2012) Geochemistry of ocean floor and fore-arc serpentinites: constraints on the ultramafic input to subduction zones. J Petrol 53(2):235–270
NIST SRM 57b. https://www-s.nist.gov/srmors/view_detail.cfm?srm=57B. Accessed on 5 Jan 2016
Acknowledgments
We are thankful to the NMI3, C-ERIC, CHARISMA, IPERION, EFNUDAT, ERINDA and CHANDA access projects for financial support and our user community for inspiration and fruitful collaboration.
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Szentmiklósi, L., Kasztovszky, Z., Belgya, T. et al. Fifteen years of success: user access programs at the Budapest prompt-gamma activation analysis laboratory. J Radioanal Nucl Chem 309, 71–77 (2016). https://doi.org/10.1007/s10967-016-4774-9
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DOI: https://doi.org/10.1007/s10967-016-4774-9