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Effect of the chemical nature of different transition metal ferrocyanides to entrap Cs

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Abstract

Transition metal ferrocyanides are used since many years to selectively entrap radio-cesium from nuclear contaminated effluents. We investigate the cesium sorption properties on a series of ferrocyanides containing different transition metal ions (Ni2+, Co2+ and Cu2+) and outline the role of the chemical nature of the bivalent metal ion, the iron oxidation state, the presence of K+ in the structure and the grain size of the powders on the equilibrium time and efficiency of the Cs+ sorption.

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Acknowledgments

We acknowledge Cyrielle Rey for its help for the analysis of the compounds and of the Cs from solution; Bruno Corso for XRD experiments; Johann Ravaux for SEM experiments; and Véronique Dubois for its help for ICP-AES analysis. This work was supported financially by CEA, University of Montpellier and MEMFIS ANR project.

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Authors and Affiliations

  1. Institut de Chimie Séparative de Marcoule, ICSM, UMR 5257 CEA-CNRS-UM2-ENSCM, BP 17171, 30207, Bagnols sur Cèze, France

    Agnès Grandjean, Carole Delchet & Jérémy Causse

  2. CEA, DEN, DTCD, Laboratoire des Procédés Supercritiques et de Décontamination, BP 17171, 30207, Bagnols sur Cèze, France

    Agnès Grandjean & Yves Barré

  3. Institut Charles Gerhardt Montpellier, ICGM, UMR 5253 CNRS-UM2-ENSCM-UM1, Ingénierie Moléculaire & Nano-Objets, Place E. Bataillon, 34095, Montpellier Cedex 5, France

    Carole Delchet, Yannick Guari & Joulia Larionova

Authors
  1. Agnès Grandjean
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  2. Carole Delchet
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  3. Jérémy Causse
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  4. Yves Barré
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  5. Yannick Guari
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  6. Joulia Larionova
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Correspondence to Agnès Grandjean.

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Grandjean, A., Delchet, C., Causse, J. et al. Effect of the chemical nature of different transition metal ferrocyanides to entrap Cs. J Radioanal Nucl Chem 307, 427–436 (2016). https://doi.org/10.1007/s10967-015-4098-1

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  • DOI: https://doi.org/10.1007/s10967-015-4098-1

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