Abstract
A new method for the determination of radiostrontium in large soil samples has been developed at the Savannah River Environmental Laboratory (Aiken, SC, USA) that allows rapid preconcentration and separation of strontium in large soil samples for the measurement of strontium isotopes by gas flow proportional counting. The need for rapid analyses in the event of a radiological dispersive device or improvised nuclear device event is well-known. In addition, the recent accident at Fukushima Nuclear Power Plant in March, 2011 reinforces the need to have rapid analyses for radionuclides in environmental samples in the event of a nuclear accident. The method employs a novel pre-concentration step that utilizes an iron hydroxide precipitation (enhanced with calcium phosphate) followed by a final calcium fluoride precipitation to remove silicates and other matrix components. The pre-concentration steps, in combination with a rapid Sr Resin separation using vacuum box technology, allow very large soil samples to be analyzed for 89,90Sr using gas flow proportional counting with a lower method detection limit. The calcium fluoride precipitation eliminates column flow problems typically associated with large amounts of silicates in large soil samples.
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Acknowledgments
This work was performed under the auspices of the Department of Energy, DOE Contract No. DE-AC09-96SR18500.
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Maxwell, S.L., Culligan, B.K. & Shaw, P.J. Rapid determination of radiostrontium in large soil samples. J Radioanal Nucl Chem 295, 965–971 (2013). https://doi.org/10.1007/s10967-012-1863-2
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DOI: https://doi.org/10.1007/s10967-012-1863-2