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Magnetic Properties of Polycrystalline Compounds Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O

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Abstract

In this work, polycrystalline powder samples of Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1 H2O have been synthesized by a coprecipitation method. The lattice parameter a is 10.053(8) Å and 10.083 Å for Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O, respectively. When the temperature reaches to 5 K, the magnetization is 7.262 emu/g and 0.142 emu/g for Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O, respectively. The coercive field and the remanent magnetization of Cu0.64Mn0.86[Fe(CN)6]·7.2H2O are 1204 Oe and 0.382 μB/fu, respectively. The coercive field and the remanent magnetization of Cu0.84Mn0.66[Fe(CN)6]·7.1H2O are 833 Oe and 0.681 μB/fu, respectively. In the initial magnetization curve, under the external magnetic field of 7 T, the magnetization of Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O is 2.13 μB/fu and 2.44 μB/fu, respectively. The difference between the calculated magnetic moment and the theoretical magnetic moment is quite large, which may be due to spin frustration.

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Funding

This work was partially supported by National Natural Science Foundation of China (Grant No. 11447231), the National Undergraduate Innovation and Entrepreneurship Training Program Support Projects of China (Grant No. 201810555007), Research Foundation of Education Bureau of Hunan Province, China (Grant No. 14B151), and the Opening Project of Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment, University of South China (Grant No. 2019KFY10).

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Authors and Affiliations

  1. College of Nuclear Science and Technology, University of South China, Hengyang, 421001, China

    Yanfang Xia, Ge Zhang & Min Liu

  2. National Key Laboratory for Powder Metallurgy, Central South University, Changsha, 410006, China

    Yanfang Xia & Duxin Li

  3. Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment, University of South China, Hengyang, China

    Yanfang Xia, Ge Zhang & Min Liu

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  1. Yanfang Xia
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  2. Ge Zhang
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Correspondence to Min Liu or Duxin Li.

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Xia, Y., Zhang, G., Liu, M. et al. Magnetic Properties of Polycrystalline Compounds Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O. J Supercond Nov Magn 32, 3831–3835 (2019). https://doi.org/10.1007/s10948-019-05166-w

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