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Composites of Recycled Polypropylene from Cotton Swab Waste with Pyrolyzed Rice Husk

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Abstract

The manufacture of consumer goods from thermoplastic polymers leads to a considerable amount of scrap or off-specifications products, generating post-industrial waste that is typically landfilled. In present study, polypropylene (PP) wastes from the cotton swabs manufacture were used to the preparation of polymeric composites with agro-industrial waste of rice husk (RH). The RH was employed in the natural form as well as it was also treated by controlled pyrolysis for surface modification before incorporation to the PP. The PP/RH composites prepared by extrusion with contents from 2 to 20 wt% of non-pyrolyzed (NRH) and pyrolyzed (PRH) rice husk were submitted to the injection molding for preparation of tensile and impact specimens and characterized by mechanical testing, thermal analysis, melt flow rate, infrared spectroscopy and scanning electron microscopy. The controlled pyrolysis treatment on the RH caused significant changes in the thermal, chemical, rheological and mechanical properties of the PP/RH composites, mainly on the mechanical properties Young’s modulus, elongation at break and impact resistance that presented variation up to 100% when compared the composites containing NRH. The recycled PP/RH composites present suitable properties for several applications such as wood-plastic, furniture, doors and are an alternative for decrease the pollution generated by cotton swab waste.

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References

  1. Ragaert K, Delva L, Van Geem K (2017) Mechanical and chemical recycling of solid plastic waste. Waste Manag 69:24–58

    CAS  PubMed  Google Scholar 

  2. Rahimi A, García JM (2017) Chemical recycling of waste plastics for new materials production. Nat Rev Chem 1:0046

    Google Scholar 

  3. Niaounakis M (2019) Recycling of biopolymers—the patent perspective. Eur Polym J 114:464–475

    CAS  Google Scholar 

  4. Brüster B et al (2016) Thermo-mechanical degradation of plasticized poly(lactide) after multiple reprocessing to simulate recycling: multi-scale analysis and underlying mechanisms. Polym Degrad Stab 131:132–144

    Google Scholar 

  5. Singh N et al (2017) Recycling of plastic solid waste: a state of art review and future applications. Composites B 115:409–422

    CAS  Google Scholar 

  6. Maris J, Bourdon S, Brossard J, Cauret L (2018) Mechanical recycling: compatibilization of mixed thermoplastic wastes. Polym Degrad Stab 147:245–266

    CAS  Google Scholar 

  7. Panaitescu DM et al (2016) Vasilievic, Influence of hemp fibers with modified surface on polypropylene composites. J Ind Eng Chem 35:137–146

    Google Scholar 

  8. Sun L et al (2016) Thermal decomposition of fire-retarded wood flour/polypropylene composites. J Therm Anal Calorim 123:309–318

    CAS  Google Scholar 

  9. Zhao Y, Lv X, Ni H (2018) Chemosphere solvent-based separation and recycling of waste plastics: a review. Chemosphere 209:707–720

    CAS  PubMed  Google Scholar 

  10. Lopez G et al (2017) Thermochemical routes for the valorization of waste polyole fi nic plastics to produce fuels and chemical: a review. Renew Sustain Energy Rev 73:346–368

    CAS  Google Scholar 

  11. Maddah HA (2016) Polypropylene as a promising plastic: a review. Am J Polym Sci 6:1–11

    CAS  Google Scholar 

  12. Geyer R, Jambeck JR, Law KL (2017) Production, use, and fate of all plastics ever made. Sci Adv 3:e1700782

    PubMed  PubMed Central  Google Scholar 

  13. Delva L, Hubo S, Cardon L, Ragaert K (2018) On the role of flame retardants in mechanical recycling of solid plastic waste. Waste Manag 82:198–206

    CAS  PubMed  Google Scholar 

  14. Sanchez FAC, Boudaoud H, Hoppe S, Camargo M (2017) Polymer recycling in an open-source additive manufacturing context: mechanical issues. Addit Manuf 17:87–105

    Google Scholar 

  15. Al-oqla FM, Sapuan SM, Ishak MR, Nuraini AA (2015) A decision-making model for selecting the most appropriate natural fiber—polypropylene-based composites for automotive applications. J Compos Mater 50:543–556

    Google Scholar 

  16. Carbonell A, Samper MD, Balart R (2015) Green composites based on polypropylene matrix and hydrophobized spend coffee ground (SCG) powder. Composites B 78:256–265

    Google Scholar 

  17. Jiménez-Cervantes E et al (2014) Composites from chicken feathers quill and recycled polypropylene. J Compos Mater 49:275–283

    Google Scholar 

  18. Mustafa WA et al (2018) Structure analysis on polypropylene maleic anhydride (PPMAH)/polypropylene (PP)/recycled acrylonitrile butadiene rubber (NBRr) /banana skin powder (BSP) composites treatment. J Adv Res Fluid Mech Therm Sci 50:40–46

    Google Scholar 

  19. Ashenai F, Ghasemi I, Menbari S, Ayaz M (2016) Optimization of mechanical properties of polypropylene /talc/graphene composites using response surface methodology. Polym Test 53:283–292

    Google Scholar 

  20. Ashori A, Menbari S, Bahrami R (2016) Mechanical and thermo-mechanical properties of short carbon fiber reinforced polypropylene composites using exfoliated graphene nanoplatelets coating. J Ind Eng Chem 38:37–42

    CAS  Google Scholar 

  21. Assarar M et al (2016) Acoustic emission characterization of damage in short hemp-fiber reinforced polypropylene composites. Polym Compos 37:1101–1112

    CAS  Google Scholar 

  22. Ibrahim ID et al (2016) Mechanical properties of sisal fibre-reinforced polymer composites: a review. Compos Interfaces 23:15–36

    Google Scholar 

  23. Jiang X, Wang J, Wu G, Peng X (2019) Significant reinforcement of polypropylene/wood flour composites by high extent of interfacial interaction. J Thermoplast Compos Mater 32:577–592

    CAS  Google Scholar 

  24. Sullins T, Pillay S, Komus A, Ning H (2017) Hemp fiber reinforced polypropylene composites: the effects of material treatments. Composites B 114:15–22

    CAS  Google Scholar 

  25. Demirbas Ö, Ulus O (2017) Synthesis and characterization of polypropylene and CTAB modified diatomite composites. Int Res J Pure Appl Chem 13:1–9

    Google Scholar 

  26. Mulinari DR et al (2009) Sugarcane bagasse cellulose/HDPE composites obtained by extrusion. Compos Sci Technol 69:214–219

    CAS  Google Scholar 

  27. Aridi NAM, Sapuan SM, Zainudin ES, Al-Oqla FM (2016) Mechanical and morphological properties of injection-molded rice husk polypropylene composites. Int J Polym Anal Charact 21:305–313

    CAS  Google Scholar 

  28. Ummah H, Suriamihardja DA, Selintung M, Wahab AW (2015) Analysis of chemical composition of rice husk used as absorber plates sea water into clean water. ARPN J Eng Appl Sci 10:6046–6050

    CAS  Google Scholar 

  29. Soltani N, Bahrami A, González LA (2015) Review on the physicochemical treatments of rice husk for production of advanced materials. Chem Eng J 264:899–935

    CAS  Google Scholar 

  30. Jia E, Zhao S, Shangguan Y, Zheng Q (2019) A facile fabrication of polypropylene composites with exellent low-temperature toughness through tunning interfacial area between matrix and rubber dispersion by silica nanoparticles located at the interface. Compos Sci Technol 184:107846

    CAS  Google Scholar 

  31. Mohamed SAN et al (2020) Energy behavior assessment of rice husk fibres reinforced polymer composite. J Mater Res Technol 9:383–393

    CAS  Google Scholar 

  32. Guna V et al (2020) Groundnut shell/rice husk agro-waste reinforced polypropylene. J Build Eng 27:100991

    Google Scholar 

  33. Wang L, He C (2019) Effects of rice husk fibers on the properties of mixed-particle-size fiber-reinforced polyvinyl chloride composites under soil accelerated aging conditions. J Eng Fib Fab 14:1–9

    Google Scholar 

  34. Ibrahim ID (2016) Dependency of the mechanical properties of sisal fiber reinforced recycled polypropylene composites on fiber surface treatment, fiber content and nanoclay. J Polym Environ 25:427–434

    Google Scholar 

  35. Gu F et al (2017) Science of the total environment from waste plastics to industrial raw materials : a life cycle assessment of mechanical plastic recycling practice based on a real-world case study. Sci Total Environ J 601:1192–1207

    Google Scholar 

  36. Luo G et al (2017) Coupling effects of glass fiber treatment and matrix modification on the interfacial microstructures and the enhanced mechanical properties of glass fiber/polypropylene composites. Composites B 111:190–199

    CAS  Google Scholar 

  37. Uzunova S et al (2014) Changes in structure of solid pyrolysis residue during slow pyrolysis of rice husk. Bulg Chem Commun 46:184–191

    CAS  Google Scholar 

  38. Meek N et al (2016) Synthesis and characterization of lignin carbon fiber and composites. Compos Sci Technol 137:60–68

    CAS  Google Scholar 

  39. Foong SY et al (2020) Valorization of biomass waste to engineered actived bichar by microwave pyrolysis: progress, challenges, and future directions. Chem Eng J 389:124401

    CAS  Google Scholar 

  40. ASTM D638 (2014) Standand test method for tensile properties of plastics. Barr Harbor Drive, West Cosnhohocken

    Google Scholar 

  41. ASTM D 256 (2014) Standard test method for determining the Izod pendulum impact resistance of plastics. Barr Harbor Drive, West Cosnhohocken

    Google Scholar 

  42. ASTM D1238 (2013) Standard test method for melt flow rates of thermoplastics by extrusion plastometer. Barr Harbor Drive, West Cosnhohocken

    Google Scholar 

  43. Abida M et al (2020) A viscoelastic-viscoplastic model with hygromechanical coupling for flax fibre reinforced polymer composites. Compos Sci Technol 189:108018

    CAS  Google Scholar 

  44. Hirayama D, Saron C (2018) Morphological and mechanical properties of blends from recycled acrylonitrile-butadiene-styrene and high-impact polystyrene. Polymer 135:271–278

    CAS  Google Scholar 

  45. Margolina A, Wu S (1988) Percolation model for brittle-tough transition in nylon /rubber blends. Polymer 29:2170–2173

    CAS  Google Scholar 

  46. Wu S (1990) Chain structure, phase morphology and toughness relationship in polymer blends. Polym Eng Sci 30:753–764

    CAS  Google Scholar 

  47. Moreno DDP, Saron C (2018) Influence of compatibilizer on the properties of low-density polyethylene/polyamide 6 blends obtained by mechanical recycling of multilayer film waste. Waste Manag Res 36:729–736

    CAS  PubMed  Google Scholar 

  48. Usman A, Zango ZU (2017) Application of DSC in the study of thermal history of cable insulation wire. Am J Polym Sci 7:45–50

    CAS  Google Scholar 

  49. Moreno DDP, Hirayama D, Saron C (2018) Accelerated aging of pine wood waste/recycled LDPE composite. Polym Degrad Stab 149:39–44

    CAS  Google Scholar 

  50. Silvertein RM, Webster FX, Kiemle DJ, Bryce DL (2014) Spectrometric identification of organic compounds, 8th edn. Wiley, New York

    Google Scholar 

Download references

Acknowledgements

The authors would like to thank the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior-CAPES and Fundação de Amparo à Pesquisa do Estado de São Paulo-FAPESP (Proc. 2017/05851-0) for their financial support.

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Correspondence to Clodoaldo Saron.

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Moreno, D.D.P., de Camargo, R.V., dos Santos Luiz, D. et al. Composites of Recycled Polypropylene from Cotton Swab Waste with Pyrolyzed Rice Husk. J Polym Environ 29, 350–362 (2021). https://doi.org/10.1007/s10924-020-01883-9

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