Abstract
In this paper investigation on thermoplastic elastomers (TPE) and thermoplastic vulcanizates (TPV) derived from waste polypropylene (WPP) of Municipal Solid Waste (MSW) and acrylonitrile-butadiene rubber (NBR) are reported. The WPP was segregated, cleaned, dried and melt processed with NBR at 180 °C in a Brabender Plasticorder at different blend ratios. TPV was prepared by dynamic vulcanization of the TPE with conventional sulfur accelerator curing system. The mechanical properties measured were found to decrease with increase in NBR proportion in the blend; however the dynamic vulcanization of the nitrile rubber phase enhanced the strength properties of the corresponding TPE. The crystallinity of the WPP reduced with increase in NBR ratio. The dynamic modulus decreased with nitrile rubber content in the TPE. Interestingly, the storage modulus of the TPV at higher rubber content enhanced significantly and damping characteristics increased sharply. The rheology studies reveal that the damping of the blend has been reduced with the addition of high storage modulus rubber at melt processing conditions and hence increased viscosity. The amorphous rubber content with higher storage modulus imparts higher viscosity for the polypropylene (PP) matrix at the processing temperature. The SEM study reveals that the dynamic vulcanization of the rubber phase in the blend caused a smoother and finer surface morphology.
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References
Shonaike GO, Simon GP (1999) Polymer blends and alloys. Marcel Dekker, Inc, New York
Paul DR, Bucknall CB (1999) Polymer blends, vol 1. Wiley, New York
Paul DR, Bucknall CB (1999) Polymer blends, vol 2. Wiley, New York
Prachayawarakorn J, Yaembunying N (2005) Songklanakarin. J Sci Technol 27:343–352
English B (1992) Pacific rim bio-based composites symposium, Rotorua, New Zealand, 9–13 November 1992
Kumar CR, George KE, Thomas S (1996) J Appl Polym Sci 61:2383
Sonnier R, Leroy E, Clerc L, Bergeret A, Lopez-Cuesta J (2006) Polym Degrad Stab 91:2375–2379
Fortelny I, Michalkova D, Krulis Z (2004) Polym Degrad Stab 85:975
Stelling FC, Huff T, Speed CS, Wissler G (1981) Polym Eng Sci 26:2693
Strapasson R, Amico SC, Pereira MFR, Sydenstricker THD (2005) Polym Testing 24:468–473
Burlett DJ (1991) United state patent No. 5023301
Huff T (1978) United state patent No. 4087485
George S, Joseph R, Varughese KT, Thomas S (1995) Polymer 36:4405
Hernandez M, Gonzalez J, Albano C, Ichazo M, Lovera D (2003) Polym Bull 50:205–212
Katbab AA, Anaraki MS, Nazokdast H (1993) Iran J Polym Sci Technol 1:12–18
George S, Ramamurthy K, Anand JS, Groeninckx G, Varughese KT, Thomas S (1999) Polymer 40:4325
Pieroni P, Ercoli D, Goizueta G, Capiati N (2001) J Reinf Plast Compos 20:182–190
Jose J, Satapathy S, Nag A, Nando GB (2007) Process Saf Environ Prot IChemE J 85:318–326
Jose J, Nag A, Nayak SK, Nando GB (2009) J Appl Polym Sci (in press)
Jose J, Nag A, Nando GB (2010) J Appl Polym Sci (accepted)
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Jose, J., Nag, A. & Nando, G.B. Processing and Characterization of Recycled Polypropylene and Acrylonitrile Butadiene Rubber Blends. J Polym Environ 18, 155–166 (2010). https://doi.org/10.1007/s10924-010-0195-y
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DOI: https://doi.org/10.1007/s10924-010-0195-y