Skip to main content
Log in

The numerical simulation of vanadium RedOx flow batteries

  • Original Paper
  • Published:
Journal of Mathematical Chemistry Aims and scope Submit manuscript

Abstract

In this article a theoretical model of a RedOx flow cell (RFC), based on an equation system of fluid dynamics and of electrochemistry, is presented. A numerical algorithm of the solution of the equation system is developed. The results of numerical simulation of processes in the RFC are analyzed and validated in a test cell. The effects of different electrode collectors and current densities on the operation of the RFC are studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Skyllas-Kazacos, G. Kazacos, G. Poonl et al, Int. J. Energy Res. doi:10.1002/er.1658 (2009)

  2. M. Skyllas-Kazacos, R.G. Robins, US Patent No. 4,786,567 (1986)

  3. Rahman F., Skyllas-Kazacos M.: J. Power Sources 189, 1212 (2009)

    Article  CAS  Google Scholar 

  4. Skyllas-Kazacos M.: J. Power Sources 124, 299 (2003)

    Article  CAS  Google Scholar 

  5. Al-Fetlawi H., Shah A.A., Walsh F.C.: Electrochim. Acta 55, 78 (2009)

    Article  CAS  Google Scholar 

  6. Shah A.A., Watt-Smith M.J., Walsh F.C.: Electrochim. Acta 53, 8087 (2008)

    Article  CAS  Google Scholar 

  7. Youa D., Zhanga H.: J. Chena Electrochim. Acta 54, 6827 (2009)

    Article  Google Scholar 

  8. O.M. Belotserkovskii, Y.M. Davydov, Method of coarse particles in gas dynamics (in Russian). (Nauka, Moscow, 1982)

  9. S.K. Godunov, V.C. Ryabenkii, Difference schemes. Introduction in theory (in Russian). (Nauka, Moscow, 1977)

  10. Tomadakis M.M., Robertson T.J.: J. Compos. Mater. 39, 163 (2005)

    Article  Google Scholar 

  11. Verbrugge M., Hill R.J.: J. Elecrochem. Soc. 137, 886 (1990)

    Article  CAS  Google Scholar 

  12. Schmal D., Van Erkel J., Van Duin P.J.: J. Appl. Electrochem 16, 422 (1986)

    Article  CAS  Google Scholar 

  13. A.A. Samarskii, Introduction in theory of difference schemes (in Russian). (Nauka, Moscow, 1971)

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. M. Bayanov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bayanov, I.M., Vanhaelst, R. The numerical simulation of vanadium RedOx flow batteries. J Math Chem 49, 2013–2031 (2011). https://doi.org/10.1007/s10910-011-9872-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10910-011-9872-x

Keywords

Navigation