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Promotional Synergistic Effect of Cs–Au NPs on the Performance of Cs–Au/MgFe2O4 Catalysts in Catalysis 3,4-Dihydropyrimidin-2(1H)-Ones and Degradation of RhB Dye

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Abstract

The recent paper deals with the immobilization of hybrid gold–cesium nanoparticles (Au–Cs NPs) onto magnesium ferrites (MgFe2O4) surface, and then the prepared composites were characterized by several techniques such as XRD, TEM, SEM, FTIR, UV–Vis diffuse reflectance spectroscopy (DRS), thermal TGA analysis, and N2 adsorption–desorption. It was found that the MgFe2O4 structure was retained after loading of Au–Cs NPs, and the surface area increased, but the pore diameter decreased that may be due to the deposition of Au–Cs NPs on MgFe2O4 that cause pore blockage. Also, the catalytic performance toward the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and photocatalytic degradation of Rhodamine B dye (10 ppm/100 ml), under a Hg lamp (150 W) as a simulated source of sun-light were investigated by changing various parameters such as Au–Cs content, catalyst weight, reaction time, and the recycling of the catalyst. The catalytic performance of 3,4-dihydropyrimidin-2(1H)-ones over 3.0 wt% Au–Cs/MgFe2O4 nanocomposite (NC) was reached to 99.0% after 2 h. Also, the results showed that the photocatalytic activity of Au–Cs/MgFe2O4 nanocomposite (NC) increases with the modification of MgFe2O4 by changing the content from 1.0 to 5.0 wt% Au–Cs NPs, the sample of 3.0 wt% Au–Cs/MgFe2O4 nanocomposite showed the higher photocatalytic activity. The catalyst is found to be reusable.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Saba Region, Marb, Yemen

    Fares T. Alshorifi

  2. Department of Chemistry, Faculty of Science, Sana’a University, Sana’a, Yemen

    Fares T. Alshorifi

  3. Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt

    Shaimaa L. Ali

  4. Basic Science Department, Faculty of Engineering, Delta University for Science and Technology, Gamasa, Egypt

    Reda S. Salama

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  1. Fares T. Alshorifi
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Alshorifi, F.T., Ali, S.L. & Salama, R.S. Promotional Synergistic Effect of Cs–Au NPs on the Performance of Cs–Au/MgFe2O4 Catalysts in Catalysis 3,4-Dihydropyrimidin-2(1H)-Ones and Degradation of RhB Dye. J Inorg Organomet Polym 32, 3765–3776 (2022). https://doi.org/10.1007/s10904-022-02389-8

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