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Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n

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Abstract

A novel nano-cauliflower-shaped lead(II) metal–organic coordination polymer, [Pb(μ-2-pinh)N3 H2O]n (1), was synthesized using an ultrasonic method. The nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction, IR spectroscopy, elemental analysis, and thermal analysis. The compound was structurally characterized by single-crystal X-ray diffraction. The coordination compound takes the form of a zig-zag one-dimensional polymer in solid state. The coordination number of the lead(II) ions is six (PbN4O2) with three nitrogen atoms and one oxygen atom from two linker organic ligands, as well as one oxygen from coordinated water and one nitrogen atom from terminal coordinated azide anion. It has a stereo-chemically active lone electron pair, and the coordination sphere is hemidirected. The zig-zag 1D chains interact with neighbouring chains through weak interactions, creating a 3D supramolecular metal–organic framework. Lead oxide nanoparticles were obtained by thermolysis of the new nano coordination compound at 180 °C with oleic acid as a surfactant. The morphology and size were further studied using SEM. Natural bond orbital analyses demonstrate the electronic properties of the lead centre and other atoms.

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Acknowledgments

Support from the University of Qom is gratefully acknowledged. This work was funded by Grant NRF-2015-002423 of the National Research Foundation of Korea. The theoretical calculations were financed by a statutory activity subsidy from the Polish Ministry of Science and Higher Education for the Faculty of Chemistry of Wrocław University of Technology. DB acknowledge generous computer time from the Wrocław Supercomputer and Networking Center.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Iran

    Babak Mirtamizdoust

  2. Faculty of Chemistry, Wrocław University of Technology, Wybrzez˙e Wyspian´skiego 27, ul Smoluchowskiego 23, 50-370, Wrocław, Poland

    Dariusz C. Bieńko

  3. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyongsan, 712-749, South Korea

    Younes Hanifehpour & Sang Woo Joo

  4. Research Centre for Crystalline Materials, Faculty of Science and Technology, 47500, Bandar Sunway, Selangor Darul Ehsan, Malaysia

    Edward R. T. Tiekink

  5. Department of Chemistry, Faculty of Arts and Sciences, Uludag University, 16059, Bursa, Turkey

    Veysel T. Yilmaz

  6. School of Chemical Engineering, University of Adelaide, Adelaide, SA, 5005, Australia

    Pejman Talemi

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  1. Babak Mirtamizdoust
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Correspondence to Babak Mirtamizdoust, Younes Hanifehpour or Sang Woo Joo.

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Mirtamizdoust, B., Bieńko, D.C., Hanifehpour, Y. et al. Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n . J Inorg Organomet Polym 26, 819–828 (2016). https://doi.org/10.1007/s10904-016-0385-8

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