Skip to main content
Log in

Structural and Dielectrical Properties of Ag- and Ba-Substituted Hydroxyapatites

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Ag- and Ba-doped hydroxyapatite (HAp) samples were synthesized by sol–gel method. The crystallite sizes for all the samples were found to vary from 26 to 39 nm. Neither Ag nor Ba did result in dramatic changes in the morphology of all the samples, and the Ca/P molar ratio was varied. The dielectric parameters of the samples were changed with the dopant content. The maximum and minimum values of the dielectric constant were observed for 2.0 %Ba-HAp and 0.5 %Ba-HAp samples. The alternating current conductivity indicates that all the samples exhibit the insulator behavior. The results of the biological tests revealed that Ag-containing samples have an antimicrobial activity, while no antimicrobial activity was detected for both HAp and Ba-doped HAp samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. S.V. Dorozhkin, Calcium Orthophosphates: Applications in Nature, Biology, and Medicine (Pan Stanford, Singapore, 2012)

    Book  Google Scholar 

  2. O. Kaygili, S. Keser, R.H. Al Orainy, T. Ates, F. Yakuphanoglu, Mat. Sci. Eng. C 35, 239 (2014)

    Article  CAS  Google Scholar 

  3. S.V. Dorozhkin, Materials 6, 3840 (2013)

    Article  CAS  Google Scholar 

  4. S. Samavedi, A.R. Whittington, A.S. Goldstein, Acta Biomater. 9, 8037 (2013)

    Article  CAS  Google Scholar 

  5. B. Singh, A.K. Dubey, S. Kumar, N. Saha, B. Basu, R. Gupta, Mat. Sci. Eng. C 31, 1320 (2011)

    Article  CAS  Google Scholar 

  6. T.N. Kim, Q.L. Feng, J.Q. Kim, J. Wu, H. Wang, G.C. Chen, F.Z. Cui, J. Mater. Sci. Mater. M. 9, 129 (1998)

    Article  Google Scholar 

  7. N.A. Trujillo, R.A. Oldinski, H. Ma, J.D. Bryers, J.D. Williams, K.C. Popat, Mat. Sci. Eng. C 32, 2135 (2012)

    Article  CAS  Google Scholar 

  8. J.H. Hsieh, C.C. Chang, C. Li, S.J. Liu, Y.K. Surf, Coat. Technol. 205, S337 (2010)

    Article  CAS  Google Scholar 

  9. M. Honda, Y. Kawanobe, K. Ishii, T. Konishi, M. Mizumoto, N. Kanzawa, M. Matsumoto, M. Aizawa, Mat. Sci. Eng. C 33, 5008 (2013)

    Article  CAS  Google Scholar 

  10. A.A. Yanovska, A.S. Stanislavov, L.B. Sukhodub, V.N. Kuznetsov, V.Y. Illiashenko, S.N. Danilchenko, L.F. Sukhodub, Mat. Sci. Eng. C 36, 215 (2014)

    Article  CAS  Google Scholar 

  11. A. Akhavan, N. Sheikh, F. Khoylou, F. Naimian, E. Ataeivarjovi, Radiat. Phys. Chem. 98, 46 (2014)

    Article  CAS  Google Scholar 

  12. A. Yasukawa, M. Nakajima, K. Kandori, T. Ishikawa, J. Colloid Interf. Sci. 212, 220 (1999)

    Article  CAS  Google Scholar 

  13. S. Sugiyama, H. Matsumoto, H. Hayashi, J.B. Moffat, Colloid Surf. A 169, 17 (2000)

    Article  CAS  Google Scholar 

  14. Z. Xiu, M. Lü, S. Liu, G. Zhou, B. Su, H. Zhang, Mat. Res. Bull. 40, 1617 (2005)

    Article  CAS  Google Scholar 

  15. M. Kikuchi, A. Yamazaki, M. Akao, H. Aoki, Bio-Med. Mater. Eng. 6, 405 (1996)

    CAS  Google Scholar 

  16. C.M. Collins, P.M. Lyne, Microbiological Methods (Buttermorths-Heinemann, London, 1989)

    Google Scholar 

  17. B.D. Cullity, Elements of X-ray Diffraction (Addison-Wesley Publishing Company, Massachusetts, 1978)

    Google Scholar 

  18. A.H. Rajabi-Zamani, A. Behnamghader, A. Kazemzadeh, Mat. Sci. Eng. C 28, 1326 (2008)

    Article  CAS  Google Scholar 

  19. N. Pleshko, A. Boskey, R. Mendelsohn, Biophys. J. 60, 786 (1991)

    Article  CAS  Google Scholar 

  20. E. Landi, A. Tampieri, G. Celotti, S. Sprio, J. Eur. Ceram. Soc. 20, 2377 (2000)

    Article  CAS  Google Scholar 

  21. K.P. Sanosh, M.C. Chu, A. Balakrishnan, T.N. Kim, S.J. Cho, Bull. Mat. Sci. 32, 465 (2009)

    Article  CAS  Google Scholar 

  22. N. Rameshbabu, T.S. Sampath Kumar, T.G. Prabhakar, V.S. Sastry, K.V.G.K. Murty, K. Prasad Rao, J. Biomed. Mater. Res. A 80, 581 (2006)

    Google Scholar 

  23. S. Jadalannagari, K. Deshmukh, S.R. Ramanan, M. Kowshik, Appl. Nanosci. 4, 133 (2014)

    Article  CAS  Google Scholar 

  24. O. Kaygili, C. Tatar, F. Yakuphanoglu, S. Keser, J. Sol Gel Sci. Technol. 65, 105 (2013)

    Article  CAS  Google Scholar 

  25. O. Kaygili, C. Tatar, F. Yakuphanoglu, Ceram. Int. 38, 5713 (2012)

    Article  CAS  Google Scholar 

  26. E.R. Kramer, A.M. Morey, M. Staruch, S.L. Suib, M. Jain, J.I. Budnick, M. Wei, J. Mat. Sci. 48, 665 (2013)

    Article  CAS  Google Scholar 

  27. H. Wang, K. Sun, A. Li, W. Wang, P. Chui, Powder Technol. 209, 9 (2011)

    Article  CAS  Google Scholar 

  28. O. Kaygili, S. Keser, T. Ates, F. Yakuphanoglu, Ceram. Int. 39, 7779 (2013)

    Article  CAS  Google Scholar 

  29. M.P. Mahabole, R.U. Mene, R.S. Khairnar, Adv. Mater. Lett. 4, 46 (2013)

    Google Scholar 

  30. C.C. Silva, M.A. Valente, M.P.F. Graça, A.S.B. Sombra, J. Non-Cryst, Solids 351, 2945 (2005)

    CAS  Google Scholar 

  31. O. Kaygili, S. Keser, T. Ates, A.A. Al-Ghamdi, F. Yakuphanoglu, Powder Technol. 245, 1 (2013)

    Article  CAS  Google Scholar 

  32. K.S. Cole, R.H. Cole, J. Chem. Phys. 9, 341 (1941)

    Article  CAS  Google Scholar 

  33. O. Kaygili, S.V. Dorozhkin, T. Ates, A.A. Al-Ghamdi, F. Yakuphanoglu, Ceram. Int. 40, 9395 (2014)

    Article  CAS  Google Scholar 

  34. N. Iqbal, M.R. AbdulKadir, N.A.N.N. Malek, N.H.B. Mahmood, M.R. Murali, T. Kamarul, Mat. Res. Bull. 48, 3172 (2013)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Omer Kaygili.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kaygili, O., Keser, S., Dorozhkin, S.V. et al. Structural and Dielectrical Properties of Ag- and Ba-Substituted Hydroxyapatites. J Inorg Organomet Polym 24, 1001–1008 (2014). https://doi.org/10.1007/s10904-014-0074-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0074-4

Keywords

Navigation