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A 3D Porous Coordination Polymer from Tetrazole Ligand and Cd(II): Crystal Structure, Luminescent Property and Adsorption of Methanol and Water

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Abstract

An unusual tetrazole-based Cd(II) coordination polymer, [Cd(4-tzba)(H2O)]n (tzba = 4-(tetrazolyl)benzenecarboxylic acid) (1), was synthesized by hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The structure of 1 contains distorted octahedral cadmium centers coordinated by four different tzba2− ligands and a water molecule. All the tzba2− ligands display coordination of type, μ4-κN1:κN3:κN4:κO1, O2, which connects four Cd(II) atoms to form an intricate 3-D network. There are three kinds of apertures in the structure of 1; two helical channels and a hexagonal aperture are observed along different axes. Polymer 1 exhibits selective gas adsorption behavior for methanol, ethanol and water. In addition, 1 shows blue photoluminescence mainly arising from intraligand transitions of the aromatic rings in the tbza2− ligand.

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (Grants Nos. 21271056 and 21371042), the Ministry of Education and Specialized Research Fund for the Doctoral Program of Higher Education (20122329110001), the Natural Science Foundation of Heilongjiang Province (B201216), Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, Doctoral initiation Foundation of Harbin Normal University (No. KGB201214).

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Authors and Affiliations

  1. Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, 150025, People’s Republic of China

    Bo Li, Kai Yu, Chunmei Wang, Zhanhua Su, Chunxiao Wang & Baibin Zhou

  2. Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, 150025, People’s Republic of China

    Kai Yu, Chunmei Wang, Zhanhua Su, Chunxiao Wang & Baibin Zhou

  3. Department of Chemistry, Heihe College, Heihe, 164300, People’s Republic of China

    Bo Li

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  1. Bo Li
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  2. Kai Yu
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Correspondence to Kai Yu or Baibin Zhou.

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Li, B., Yu, K., Wang, C. et al. A 3D Porous Coordination Polymer from Tetrazole Ligand and Cd(II): Crystal Structure, Luminescent Property and Adsorption of Methanol and Water. J Inorg Organomet Polym 24, 525–530 (2014). https://doi.org/10.1007/s10904-013-0015-7

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  • DOI: https://doi.org/10.1007/s10904-013-0015-7

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