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Silicon and Chlorine Substituted Unsaturated Polymers: ROMP of (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane via Mo-based catalyst

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Abstract

Ring opening metathesis polymerization (ROMP) of a norbornene derivative that contains silicon and chlorine, (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane, by using electrochemically produced active catalyst species (MoCl5–e−–Al–CH2Cl2) was investigated. Silicon and chlorine containing unsaturated polymer was characterized by 1H, 13C, and 29Si-NMR and FTIR spectroscopy. The thermal behavior of the polymer was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

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Acknowledgments

We gratefully acknowledge the Hacettepe University Research Fund (08A601002) and Scientific and Technological Research Council of Turkey (TUBITAK, TBAG 108T087) for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hacettepe University, Beytepe, Ankara, 06800, Turkey

    Solmaz Karabulut, Volkan Şahin, Bengi Ö. Öztürk & Yavuz İmamoğlu

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  1. Solmaz Karabulut
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  2. Volkan Şahin
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  3. Bengi Ö. Öztürk
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  4. Yavuz İmamoğlu
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Correspondence to Solmaz Karabulut or Yavuz İmamoğlu.

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Karabulut, S., Şahin, V., Öztürk, B.Ö. et al. Silicon and Chlorine Substituted Unsaturated Polymers: ROMP of (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane via Mo-based catalyst. J Inorg Organomet Polym 19, 570–574 (2009). https://doi.org/10.1007/s10904-009-9302-8

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