Skip to main content
SpringerLink
Log in

Synthesis of TiO2 Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. C. Sulitzky, B. Ruckert, A.J. Hall, F. Lanza, K. Unger, B. Sellergren, Macromolecules 35, 3314 (2002)

    Article  CAS  Google Scholar 

  2. M. Jakusch, M. Janotta, B. Mizaikoff, K. Mosbach, K. Haupt, Anal. Chem. 71, 4786 (1999)

    Article  CAS  Google Scholar 

  3. R. Simon, E. Collins, D.A. Spivak, Anal. Chem. Acta 591, 7 (2007)

    Article  CAS  Google Scholar 

  4. X. Huang, S.J. Li, J. Inorg. Organomet. Polym. 18, 277 (2008)

    Article  CAS  Google Scholar 

  5. E.C. Hagberg, M.W. Hart, L. Cong, C.W. Allen, K.R. Carter, J. Inorg. Organomet. Polym. 17, 377 (2007)

    Article  CAS  Google Scholar 

  6. K. Haupt, Ann. Chem. A 75, 377 (2003)

    Google Scholar 

  7. T. Gotoh, Y. Nakatani, S. Sakohara, J. Appl. Polym. Sci. 69, 895 (1998)

    Article  CAS  Google Scholar 

  8. L. Feng, Y.J. Liu, J.M. Hu, Langmuir 20, 1786 (2004)

    Article  CAS  Google Scholar 

  9. K.J. Shea, D.A. Loy, Chem. Mater. 13, 3306 (2001)

    Article  CAS  Google Scholar 

  10. J.P. Corriu, Angew. Chem. Int. Ed. Engl. 39, 1376 (2000)

    Article  CAS  Google Scholar 

  11. L. Hench, J. West. Chem. Rev. 90, 33 (1990)

    Article  CAS  Google Scholar 

  12. A.G. Mayes, M.J. Whitcombe, Adv. Drug Delivery Rev. 57, 1742 (2005)

    Article  CAS  Google Scholar 

  13. R.G. Wilson, Weed. Technol. 13, 25 (1999)

    CAS  Google Scholar 

  14. K.O. Abulnaja, C.R. Tighe, J.L. Harwood, Phytochemistry 34, 1155 (1992)

    Article  Google Scholar 

  15. H. Kawahigashi, S. Hirose, E. Hayashi, Pestic. Biochem. Physiol. 74, 139 (2002)

    Article  CAS  Google Scholar 

  16. L.Q. Jing, H.G. Fu, B.Q. Wang, D.J. Wang, B.F. Xin, J.Z. Sun, Appl. Catal. B 62, 282 (2006)

    Article  CAS  Google Scholar 

  17. B. Xin, L. Jing, Z. Ren, B. Wang, H. Fu, J. Phys. Chem. B 109, 2805 (2005)

    Article  CAS  Google Scholar 

  18. E.B. Lami, J. Lang, J. Colloid Interface Sci. 197, 293 (1998)

    Article  Google Scholar 

  19. L.H. Lee, W.C. Chen, Chem. Mater. 13, 1137 (2003)

    Article  Google Scholar 

  20. Z.J. Bo, P. Zhan, L. Tao, G.M. Chu, Chin. J. Catal. 27, 1045 (2006)

    Google Scholar 

  21. K.S. Suslick, S.B. Choe, A.A. Cichowlas, M.W. Grinstaff, Nature 353, 414 (1991)

    Article  CAS  Google Scholar 

  22. A.E. Alegria, Y. Lion, T. Kondo, P. Riesz, J. Phys. Chem. 93, 4908 (1989)

    Article  CAS  Google Scholar 

  23. L. Zhao, D.X. Wang, J.S. Gao, C.M. Xu, Chin. J. Catal. 26, 15 (2005)

    CAS  Google Scholar 

  24. A. Gedanken, Ultrason. Sonochem. 11, 47 (2004)

    Article  CAS  Google Scholar 

  25. K. Haupt, Analyt. 126, 747 (2001)

    Article  CAS  Google Scholar 

  26. J. Mahony, S.T. Wei, B. Mizaikoff, Anal. Chem. 78, 6187 (2006)

    Article  Google Scholar 

  27. M. Zhang, C.Y. LU, Chem. J. Chinese Universities 28, 422 (2007)

    Google Scholar 

  28. G.P. Gonz´alez, P.F. Hernando, J.S. Durand Alegr´ıa, Anal. Chim. Acta 557, 179 (2006)

    Article  CAS  Google Scholar 

  29. G.Q. Fu, H.Y. Li, H.F. Yu, L. Liu, Z. Yuan, B.L. He, React. Funct. Polym. 67, 442 (2007)

    Article  CAS  Google Scholar 

  30. K. Haupt, K. Mosbach, Chem. Rev. 100, 2495 (2000)

    Article  CAS  Google Scholar 

  31. J.A. Garc′ıa-Calz′on, M.E. D′ıaz-Garc′ıa, Sens. Actuators B 123, 1180 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the National Nature Science Foundation of China (50873026) and "Six Talents Pinnacle Program" of Jiangsu Province of China (06-A-033) for financial supports.

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Qingzhao Yao, Yuming Zhou, Yanqing Sun & Xiaoyun Ye

Authors
  1. Qingzhao Yao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuming Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yanqing Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaoyun Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yuming Zhou.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yao, Q., Zhou, Y., Sun, Y. et al. Synthesis of TiO2 Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent. J Inorg Organomet Polym 18, 477–484 (2008). https://doi.org/10.1007/s10904-008-9227-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-008-9227-7

Keywords

Search

Navigation