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Preparation, Structure and Near-infrared Luminescent Property of Yb(III) Complex with 2,4,6-Pyridinetricarboxylic Acid

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Abstract

A rare earth ytterbium complex with 2,4,6-pyridinetricarboxylic acid (H3pta) has been synthesized by hydrothermal method, the formula is {[Yb2(pta)2(H2O)3]·H2O}n. The complex crystallized in monoclinic system, P21/c space group with lattice parameters a = 11.6556(19)Å, b = 7.8364(12), c = 22.020(4), α = γ = 90º, β = 92.120(3), Z = 4, GOF = 1.026, R1 = 0.0334, wR2 = 0.0660. The pta anions connect four rare earth Yb(III) ions with two different coordination modes. The complex exhibit intense characteristic near-infrared luminescence of Yb(III) ions at 990 nm with excitation of UV-rays.

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Acknowledgements

This work was supported by Scientific Research Foundation of the Education Department of Henan Province (No. 2009B150026) and project of Xuchang Science and technology plans (No. 1101069).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan, 461000, People’s Republic of China

    Hong-Sheng Wang & Gong-Chun Li

  2. Department of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Hong-Sheng Wang, Jun Xia, Bin Zhai & Ming-Li Liu

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  2. Gong-Chun Li
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Correspondence to Hong-Sheng Wang.

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Wang, HS., Li, GC., Xia, J. et al. Preparation, Structure and Near-infrared Luminescent Property of Yb(III) Complex with 2,4,6-Pyridinetricarboxylic Acid. J Fluoresc 23, 7–12 (2013). https://doi.org/10.1007/s10895-012-1122-5

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