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Photocharacterization of Novel Ruthenium Dyes and Their Utilities as Oxygen Sensing Materials in Presence of Perfluorochemicals

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Abstract

Photophysical constants of three novel ruthenium dyes derived from tridentate pyridinediimine (pydim) ligands has been declared and their photoluminescent properties were investigated in solvents of dichloromethane (DCM), tetrahydrofuran (THF) and ethanol (EtOH) by UV-Visible absorption, emission and excitation spectra. The quantum yield, fluorescence decay time, molar extinction coefficient and Stoke’s shift values of the novel ruthenium complexes were determined. The perfluoro compound (PFC) nonadecafluorodecanoic acid which is also known as medical gas carrier has been used for the first time together with newly synthesized Ruthenium complexes in ethyl alcohol. The utilities of oxygen sensing materials were investigated in EtOH in presence of chemically and biochemically inert PFC.

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Acknowledgements

We thank Prof. Dr. Jean-Marie Salmon and Dr. Anne-Cecile Ribou for allowing time resolved based studies in their laboratory. Funding for this research was provided by the TUBITAK and Scientific Research Funds of Dokuz Eylul University (Project No.: 04.kb.fen.105).

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Authors and Affiliations

  1. Faculty of Arts and Sciences, Department of Chemistry, University of Dokuz Eylul, Tinaztepe, 35160, Izmir, Turkey

    Ozlem Oter & Kadriye Ertekin

  2. Faculty of Science, Department of Chemistry, University of Ege, Bornova, 35100, Izmir, Turkey

    Osman Dayan & Bekir Cetinkaya

  3. Dokuz Eylul Universitesi Fen-Edebiyat Fakultesi Kimya Bolumu, Tinaztepe Buca, 35160, Izmir, Turkey

    Kadriye Ertekin

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  1. Ozlem Oter
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  2. Kadriye Ertekin
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  4. Bekir Cetinkaya
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Correspondence to Kadriye Ertekin.

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Oter, O., Ertekin, K., Dayan, O. et al. Photocharacterization of Novel Ruthenium Dyes and Their Utilities as Oxygen Sensing Materials in Presence of Perfluorochemicals. J Fluoresc 18, 269–276 (2008). https://doi.org/10.1007/s10895-007-0258-1

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  • DOI: https://doi.org/10.1007/s10895-007-0258-1

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