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Decorated Dawson Anion by Two Different Complex Fragments of Phenanthroline and Isonicotinic Acid: Synthesis and Properties

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Abstract

An unreported inorganic–organic hybrid compound [{Cu2(phen)2(ina)2(H2O)}{Cu(phen)2}(H2P2W18O62)]·10H2O(1) (phen = 1,10-phenanthroline, ina = isonicotinate anion) was hydrothermally synthesized and characterized with elemental analysis, IR spectroscopy, thermal analysis, luminescent spectroscopy, UV/Vis diffuse reflection spectroscopy, magnetic measurement. The crystal structure was determined with X-ray single-crystal diffraction. [Cu(phen)2]2+and [Cu2(phen)2(ina)2(H2O)]2+ units are grafted on the Dawson anion [P2W18O62]6− via the terminal oxygen atoms of two WO6 octahedra. In [Cu2(phen)2(ina)2(H2O)]2+ unit Cu2+ ions displays a square-pyramidal geometry, and in [Cu(phen)2]2+ unit the geometry of Cu2+ ion is more close to triangle bipyramidal geometry including a terminal oxygen atom. Hydrogen bonds exist between the decorated Dawson anions and water molecules. The compound 1 has a narrow band gap of 2.05 eV and strong emission at 437 nm. Variable-temperature magnetic measurement of 1 shows a typical antiferromagnetic interaction in the 2–300 K temperature range.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Hong-Ye Wang, Tian Shi, Ya-Guang Chen & Xiao-Yan Ren

  2. Department of Pharmaceutics, Changchun Medical College, Changchun, 130031, People’s Republic of China

    Hong-Bo Liu

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  1. Hong-Ye Wang
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  2. Hong-Bo Liu
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  3. Tian Shi
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  4. Ya-Guang Chen
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  5. Xiao-Yan Ren
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Correspondence to Ya-Guang Chen.

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Wang, HY., Liu, HB., Shi, T. et al. Decorated Dawson Anion by Two Different Complex Fragments of Phenanthroline and Isonicotinic Acid: Synthesis and Properties. J Clust Sci 28, 1041–1049 (2017). https://doi.org/10.1007/s10876-016-1094-8

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  • DOI: https://doi.org/10.1007/s10876-016-1094-8

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