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Synthesis, Structure, Property of a Templated Borate [Hdmpip][B5O6(OH)4]

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Abstract

A templated borate [Hdmpip][B5O6(OH)4] (dmpip = 1,4-dimethylpiperazine) has been synthesized and characterized by single crystal X-ray analysis, element analysis, IR spectroscopy, PXRD, TG-DSC, EPR, luminescence spectroscopy, and quantum chemistry analysis. The title compound contains the [B5O6(OH)4]− anions that are connected together by O–H···H H-bonds to form a 3-D network with 1-D tunnels, in which [Hdmpip]+ cations were located in. The luminescence spectra of [C9H14N]·[B5O6(OH)4] showed tunable luminescence emission by means of annealing treatment from 150 to 360 °C.

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References

  1. C. L. Christ and J. R. Clark (1977). Phys. Chem. Miner. 2, 59.

    Article  CAS  Google Scholar 

  2. G. Heller (1986). Top. Curr. Chem. 131, 39.

    Article  CAS  Google Scholar 

  3. P. C. Burns, J. D. Grice, and F. C. Hawthorne (1995). Can. Mineral. 33, 1131.

    CAS  Google Scholar 

  4. P. C. Burns (1995). Can. Mineral. 33, 1167.

    CAS  Google Scholar 

  5. J. D. Grice, P. C. Burns, and F. C. Hawthorne (1999). Can. Mineral. 37, 731.

    CAS  Google Scholar 

  6. P. Becker (1998). Adv. Mater. 10, 979.

    Article  CAS  Google Scholar 

  7. C.-Y. Pan, G.-M. Wang, S.-T. Zheng, and G.-Y. Yang (2007). Z. Anorg. Allg. Chem. 633, 336.

    Article  CAS  Google Scholar 

  8. C.-Y. Pan, S. Hu, D.-G. Li, P. Ouyang, F.-H. Zhao, and Y.-Y. Zheng (2010). Dalton Trans. 39, 5772.

    Article  CAS  Google Scholar 

  9. M. Z. Visi, C. B. Knobler, J. J. Owen, M. I. Khan, and D. M. Schubert (2006). Cryst. Growth Des. 6, 538.

    Article  CAS  Google Scholar 

  10. Z. H. Liu, L. Q. Li, and W. J. Zhang (2006). Inorg. Chem. 45, 1430.

    Article  CAS  Google Scholar 

  11. D. M. Schubert, M. Z. Visi, and C. B. Knobler (2000). Inorg. Chem. 39, 2250.

    Article  CAS  Google Scholar 

  12. Y. Yang, J.-B. Sun, M. Cui, R.-B. Liu, Y. Wang, and C.-G. Meng (2011). J. Solid State Chem. 184, 1666.

    Article  CAS  Google Scholar 

  13. J. Liang, Y.-G. Wang, Y.-X. Wang, F.-H. Liao, and J.-H. Lin (2013). J. Solid State Chem. 200, 99.

    Article  CAS  Google Scholar 

  14. C.-Y. Pan, G.-M. Wang, S.-T. Zheng, and G.-Y. Yang (2007). J. Solid State Chem. 180, 553.

    Google Scholar 

  15. S. H. Yang, G. B. Li, S. J. Tian, F. H. Liao, M. Xiong, and J. H. Lin (2007). J. Solid. State. Chem. 180, 2225.

    Article  CAS  Google Scholar 

  16. G. Z. Liu, S. T. Zheng, and G. Y. Yang (2007). Inorg. Chem. Commun. 10, 84.

    Article  CAS  Google Scholar 

  17. M.-S. Wang, G.-C. Guo, W.-T. Chen, G. Xu, W.-W. Zhou, K.-J. Wu, and J.-S. Huang (2007). Angew. Chem. Int. Ed. 46, 3909.

    Article  CAS  Google Scholar 

  18. M.-C. Liu, P. Zhou, H.-G. Yao, S.-H. Ji, R.-C. Zhang, M. Ji, and Y.-L. An (2007). Eur. J. Inorg. Chem. 2009, 4622.

    Article  Google Scholar 

  19. A. D. Becke (1993). J. Chem. Phys. 98, 5648.

    Article  CAS  Google Scholar 

  20. M. J. Frisch et al., GAUSSIAN 09 (Revision A.1), (Gaussian Inc., Wallingford, 2009).

  21. P. Ros and G. C. A. Schuit (1966). Theor. Chem. Acc. 4, 1.

    Article  CAS  Google Scholar 

  22. T. Lu and F. Chen (2012). J. Comput. Chem. 33, 580.

    Article  Google Scholar 

  23. G. M. Sheldrick SHELXS97 Program for Solution of Crystal Structures (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  24. G. M. Sheldrick SHELXL97 Program for the Refinement of Crystal Structures (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  25. R. A. Nyquist, C. A. Putzig Infrared and Raman Spectral Atlas of Inorganic Compounds and Organic Salts, vol. 1 (Academic Press, Boston, 1997), pp. 6–10, 39.

    Google Scholar 

  26. G. Socrates Infrared and Raman Characteristic Group Frequencies (Wiley, Chichester, 2001), pp. 247–252.

    Google Scholar 

  27. L. Jun, et al. (1995). Sectrochim. Acta Part A. 51, 519.

    Article  Google Scholar 

  28. G. Xion, et al. (1993). J. Raman Spectro. 24, 785.

    Article  Google Scholar 

  29. H. S. Bazzi, S. Y. AlQaradawi, A. Mostafa, and E.-M. Nour (2008). J. Mol. Struct. 879, 60.

    Article  CAS  Google Scholar 

  30. J. D. Jiang, K. Zhang, C. Y. Liu, and G. Z. Wu (2013). Acta Polym. Sinica 2, 255.

    Google Scholar 

  31. B. Nicolaï, I. B. Rietveld, M. Barrio, N. Mahé, J. Tamarit, R. Céolin, C. Guéchot, and J. Teulon (2013). Struct. Chem. 24, 279.

    Article  Google Scholar 

  32. S. Bhattacharya and B. K. Saha (2013). Cryst. Growth Design 13, 3299.

    Article  CAS  Google Scholar 

  33. Y. Hasegawa, T. Ohkubo, T. Nakanishi, A. Kobayashi, M. Kato, T. Seki, H. Ito, and K. Fushimi (2013). Eur. J. Inorg. Chem. 34, 5911.

    Article  Google Scholar 

  34. L. Li, J. Xin, L. J. He, L. Y. Dong, and L. F. Li (2005). Spectro. Spectral Anal. 25, 26.

    Google Scholar 

  35. L. J. Lai, H. C. Lu, H. K. Chen, B. M. Cheng, M. I. Lin, and T. C. Chu (2005). J. Electron. Spectro. Relat. Phenom. 865, 144.

    Google Scholar 

  36. C. Zhang, C. Li, J. Yang, Z. Cheng, Z. Hou, Y. Fan, and J. Lin (2009). Langmuir 25, 7078.

    Article  CAS  Google Scholar 

  37. Y.-C. Liao, C.-H. Lin, and S.-L. Wang (2005). J. Am. Chem. Soc. 127, 9986.

    Article  CAS  Google Scholar 

  38. Q. C. Gu, S. C. Lou, Q. P. Dai, and Q. J. Li Chemical Table, vol. 1 (Jiangsu Science and Technology Press, Nanjing, 1979).

    Google Scholar 

  39. T. Hayakawa, A. Hiramitsu, and M. Nogami (2003). Appl. Phys. Lett. 82, 2975.

    Article  CAS  Google Scholar 

  40. A. Pifferi, P. Taroni, A. Torricelli, G. Valentini, P. Mutti, G. Ghislotti, and L. Zanghieri (1997). Appl. Phys. Lett. 70, 348.

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Project of Coal to Ethylene glycole of Fjirsm of CAS, the National Natural Science Foundation of China (51002034).

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Authors and Affiliations

  1. School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou, 510006, Guangdong, China

    Chun-Yang Pan, Yuan-Zhang Luo, Da-Guang Li, Feng-Hua Zhao & Jing Lu

  2. College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, Fujian, China

    Cheng Rong

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  1. Chun-Yang Pan
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  2. Yuan-Zhang Luo
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  3. Da-Guang Li
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Correspondence to Chun-Yang Pan.

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Pan, CY., Luo, YZ., Li, DG. et al. Synthesis, Structure, Property of a Templated Borate [Hdmpip][B5O6(OH)4]. J Clust Sci 26, 1633–1644 (2015). https://doi.org/10.1007/s10876-015-0863-0

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  • DOI: https://doi.org/10.1007/s10876-015-0863-0

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