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A Perspective on the Science of Clusters

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Abstract

In this article, the interdisciplinary science of clusters is discussed in general terms. Different types of clusters across vast scales of matter, energy, space, and time in the physical world are discussed. Specific examples of clusters in chemistry and physics are used to illustrate various principles or models of clustering processes of atoms and molecules as well as to demonstrate the exquisite beauty and pattern of clusters and the clustering phenomena so ubiquitous in nature. Nowadays, “designer clusters” can be made with tailorable properties and used as “building blocks” to form supermolecules, or to construct large cluster-based hierarchical materials with tunable properties, or to fabricate cluster-based devices with specific functions, etc., thereby providing a materials base for nanotechnology. Clustering is a spontaneous self-assembly process and the similarity across scales reflects the intrinsic self-organization and self-similarity principle of the physical world. Geometry and symmetry transcend all clustering processes, in ordered as well as in disordered systems.

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Acknowledgments

I would like to dedicate this review to Professors Larry and June Dahl of University of Wisconsin (Madison) in appreciation of their guidance and friendship over the years. I thank Ken Howell for suggesting the title and scope of this perspective review on the science of clusters. I am particularly grateful for his careful reading of, and helpful comments on, the manuscript. Partial financial support of iCHEM, Xiamen University, is gratefully acknowledged.

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  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, Fujian, China

    Boon K. Teo

  2. College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China

    Boon K. Teo

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Teo, B.K. A Perspective on the Science of Clusters. J Clust Sci 25, 5–28 (2014). https://doi.org/10.1007/s10876-013-0678-9

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