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Two New 2D and 1D Ni(II) Coordination Polymers Bridged by Vanadium-Substituted Keggin Polyoxotungstophosphates: Hydrothermal Synthesis and Crystal Structure

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Abstract

Two coordination polymers based on vanadium-substituted Keggin polyoxotungstophosphates as bridging ligands, {[Ni(4,4′-bipy)1.5(OH)(H2O)]2[H3PW10V2O40]}·4H2O (4,4′-bpy = 4,4′-bipyridine) 1 and {[Ni(dpa)2][Ni(dpa)(H2O)3]2[PW9V3O40]}·4H2O (dpa = 2,2′-dipyridylamine) 2, have been obtained by hydrothermal reactions and characterized by elemental analysis, IR, XRD, TGA and single-crystal X-ray Diffraction analysis. Compound 1 is a 2D layered structure built from 1D infinite zigzag {Ni2(4,4′-bipy)3(OH)2(H2O)2} 2+n chains bridged via [H3PW10V2O40]2− anions. Compound 2 exhibits a one-dimensional chain-like structure constructed from [Ni(dpa)2]2+ fragments bridged via bis-supported Keggin polyoxoanions [Ni(dpa)(H2O)3]2[PW9V3O40]2−. The two examples demonstrate that vanadium-substituted Keggin polyoxometalates have greater coordination capability.

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Acknowledgment

This work was financially supported by the National Natural Science Foundation of China (Grant No. 20773057).

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Authors and Affiliations

  1. Institute of Chemistry for Functionalized Materials, Liaoning Normal University, Dalian Liaoning, 116029, People’s Republic of China

    Xuemei Han, Wansheng You, Limei Dai, Lijun Qi, Yong Fang & Weiwei Li

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  1. Xuemei Han
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  2. Wansheng You
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  3. Limei Dai
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  4. Lijun Qi
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Correspondence to Wansheng You.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10876_2009_273_MOESM1_ESM.doc

IR spectra, TG, XRD, numbering scheme for substituted Keggin ions and selected bond distances and angles of compound 1 and 2 can be found in the supplementary materials. (DOC 2718 kb)

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Han, X., You, W., Dai, L. et al. Two New 2D and 1D Ni(II) Coordination Polymers Bridged by Vanadium-Substituted Keggin Polyoxotungstophosphates: Hydrothermal Synthesis and Crystal Structure. J Clust Sci 20, 707–716 (2009). https://doi.org/10.1007/s10876-009-0273-2

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  • DOI: https://doi.org/10.1007/s10876-009-0273-2

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