Skip to main content
SpringerLink
Log in

[Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2″-terpyridine) ruthenium (II)] (2+) Tetrafluoroborate: Photophysical Studies

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

The photophysical properties of the title compound have been studied by fs and ns transient absorption spectroscopy. The electronic absorption spectrum consists of three principle absorptions assigned to terpy 1LLCT at ~300 nm, ruthenium (II) t 62g to terpy 1MLCT at ~470 nm and Mo2 δ to terpycarboxylate at ~670 nm. The compound shows weak room temperature emission in THF solution at ~1,100 nm when excited into each of the aforementioned bands. This emission is assigned to the T1 state, 3MMδδ*. Transient absorption spectroscopy indicates a lifetime for T1 of 9.6 μs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Scheme 3
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. M. H. Chisholm and N. J. Patmore (2005). Chem. Rec. 5, 308.

    Article  CAS  Google Scholar 

  2. M. H. Chisholm and N. J. Patmore (2007). Acc. Chem. Res. 40, 19.

    Article  CAS  Google Scholar 

  3. M. V. Barybin, M. H. Chisholm, N. J. Patmore, R. E. Robinsona, and N. Singh (2007). Chem. Commun. 3652.

  4. M. H. Chisholm, P. T. Chou, Y. H. Chou, Y. Ghosh, T. L. Gustafson, and M. L. Ho (2008). Inorg. Chem. 47, 3415.

    Article  CAS  Google Scholar 

  5. M. H. Chisholm and N. J. Patmore (2006). Dalton Trans. 26, 3164.

    Article  Google Scholar 

  6. F. A. Cotton, L. M. Daniels, J. P. Donahue, C. Y. Liu, and C. A. Murillo (2002). Inorg. Chem. 41, 1354.

    Article  CAS  Google Scholar 

  7. D. J. Brown, M. H. Chisholm, and J. C. Galluci (2008). Dalton Trans. 12, 1615.

    Article  Google Scholar 

  8. F. A. Cotton, J. P. Donahue, C. Lin, and C. A. Murillo (2001). Inorg. Chem. 40, 1234.

    Article  CAS  Google Scholar 

  9. M. H. Chisholm, C. M. Hadad, K. Heinze, K. Hempel, N. Singh, and S. Vyas (2008). J. Cluster Sci. 19, 209.

    Article  CAS  Google Scholar 

  10. M. J. Byrnes, M. H. Chisholm, J. C. Gallucci, Y. A. Liu, R. Ramkrishna, and C. Turro (2005). J. Am. Chem. Soc. 127, 17343.

    Article  CAS  Google Scholar 

  11. G. Burdzinski, J. C. Hackett, J. Wang, T. L. Gustafson, C. M. Hadad, and M. S. Platz (2006). J. Am. Chem. Soc. 128, 13402.

    Article  CAS  Google Scholar 

  12. T. Nakayama, Y. Amijima, K. Ibuki, and K. Hamanoue (1997). Rev. Sci. Instrum. 68, 4364.

    Article  CAS  Google Scholar 

  13. S. Braterman, J. I. Song, and R. D. Peacock (1992). Inorg. Chem. 31, 555.

    Article  CAS  Google Scholar 

  14. G. T. Burdzinski, M. H. Chisholm, P. T. Chou, Y. H. Chou, F. Feil, J. C. Gallucci, Y. Ghosh, T. L. Gustafson, M. L. Ho, Y. A. Liu, R. Ramkrishna, and C. Turro (2008). Proc. Natl. Acad. Sci. USA 105, 15247.

    Article  CAS  Google Scholar 

  15. J. K. McCusker (2003). Acc. Chem. Res. 36, 876.

    Article  CAS  Google Scholar 

  16. M. W. Cooke, M.-P. Santoni, G. S. Hanan, F. Loiseau, A. Proust, and B. Hasenknopf (2008). Inorg. Chem. 47, 6112.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Columbus, OH, 43210-1185, USA

    Brian G. Alberding, Malcolm H. Chisholm, Terry L. Gustafson, Carly R. Reed, Namrata Singh & Claudia Turro

Authors
  1. Brian G. Alberding
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Malcolm H. Chisholm
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Terry L. Gustafson
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Carly R. Reed
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Namrata Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Claudia Turro
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Malcolm H. Chisholm.

Additional information

This paper is dedicated to Prof. C. N. R. Rao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alberding, B.G., Chisholm, M.H., Gustafson, T.L. et al. [Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2″-terpyridine) ruthenium (II)] (2+) Tetrafluoroborate: Photophysical Studies. J Clust Sci 20, 307–317 (2009). https://doi.org/10.1007/s10876-009-0232-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-009-0232-y

Keywords

Search

Navigation