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Synthesis and Crystal Structures of Spiro[1,3-Dihydroperimidine-2,9′-Fluorene] and its Co-Crystal with 9-Fluorenone

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Abstract

The crystal structures of the new compounds spiro[1,3-dihydroperimidine-2,9′-fluorene] (1), and co-crystal (2) consists of 1 and 9-fluorenone were obtained by single crystal X-ray diffraction. Compound 1 crystallizes in the orthorhombic space group Pbca, with lattice parameters: a = 14.914(9) Å, b = 16.2126(8) Å, c = 26.4850(14) Å and Z = 16. Co-crystal 2 crystallizes in the orthorhombic space group Pca2(1), with lattice parameters: a = 18.0732(9) Å, b = 7.7216(4) Å, c = 17.8262(9) Å and Z = 4. Details of the synthesis, structures, thermal and spectroscopic properties of the new compounds are discussed.

Graphical Abstract

The crystal structures of the new compounds spiro[1,3-dihydroperimidine-2,9′-fluorene] (1), and co-crystal (2) consists of 1 and 9-fluorenone were obtained by single crystal X-ray diffraction. Details of the synthesis, structures, thermal and spectroscopic properties of the new compounds are discussed.

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Acknowledgments

Financial support from the State Key Development Program for Basic Research of China (2009CB930604) and the Natural Science Foundation of Guangdong Province, China (8151064101000111) is gratefully acknowledged.

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  1. College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, People’s Republic of China

    Zhuomin Li & Wenli Deng

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  1. Zhuomin Li
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  2. Wenli Deng
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Correspondence to Wenli Deng.

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Li, Z., Deng, W. Synthesis and Crystal Structures of Spiro[1,3-Dihydroperimidine-2,9′-Fluorene] and its Co-Crystal with 9-Fluorenone. J Chem Crystallogr 41, 1534–1538 (2011). https://doi.org/10.1007/s10870-011-0136-1

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  • DOI: https://doi.org/10.1007/s10870-011-0136-1

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