Skip to main content

Advertisement

SpringerLink
Log in

SiO2-CaO-K2O coatings on alumina and Ti6Al4V substrates for biomedical applications

  • Published:
Journal of Materials Science: Materials in Medicine Aims and scope Submit manuscript

Abstract

Alumina and Ti6Al4V alloys are widely used for orthopedics and dental applications due to their good mechanical properties and biocompatibility. Unfortunately they can not provide a satisfactory osteointegration when implanted. In fact, both alumina and Ti6Al4V are not bioactive and thus they can only guarantee a morphological fixation with the surrounding tissues without a suitable chemical anchorage. Aiming to impart bioactive properties to these materials a coating can be proposed. At this purpose, a bioactive glass belonging to the SiO2-CaO-K2O system was selected and prepared. This glass, named SCK, possess a thermal expansion coefficient matching with the alumina (8.5× 10− 6/ ∘C) and Ti6Al4V (9 × 10− 6/∘C) ones and thus is a good candidate to produce coatings on both of them. Simple and low-cost enameling and glazing techniques were used to realize the coatings. Structural, morphological and compositional characterizations of the coatings were carried out by means of X-ray diffraction, optical and scanning microscopy and compositional analyses. The in vitro properties of the coatings were investigated by soaking them in a simulated body fluid (SBF) in order to study the precipitation, on their surfaces, of a biologically active layer of hydroxylapatite (HAp).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. F. HULBERT, in “An Introduction to Bioceramics” edited by L. L. Hench and J. Wilson (World Scientific Pub, 1993) Vol. 1, p. 25.

  2. L.L. HENCH, J. Am. Ceram. Soc. 74 (1991) 1487.

    Article  Google Scholar 

  3. Idem., ibid. 81 (1998) 1705.

    Google Scholar 

  4. A. SCHROEDER, F. SUTTER and G. KREKELER, in “Oral Implantology” (New York, Thiem Medical, 1991) p. 37.

    Google Scholar 

  5. M. LONG and H. J. RACK, Biomat. 19 (1998) 1621.

    Article  Google Scholar 

  6. A. RAVAGLIOLI, A. KRAJEWSKI, A. PIANCASTELLI, G. BERGER, K. ADAM and R. GILDENHAAR, Interceram. 41 (1992) 41.

    Google Scholar 

  7. E. VERNÉ, C. VITALE BROVARONE, A. RAVAGLIOLI and A. KRAJEWSKI, in “Bioceramics” edited by H. Ohgushi, G. W. Hastings and T. Yoshikawa (World Scientific Publishing, 1999) Vol. 12, p. 491.

  8. E. VERNÉ, C. VITALE BROVARONE, C. MOISESCU, E. GHISOLFI and E. MARMO, Acta Materialia 48 (2000) 4667.

    Article  Google Scholar 

  9. C. VITALE BROVARONE, E. VERNÉ, F. LUPO, C. MOISESCU, L. ZANARDI, M. BOSETTI and M. CANNAS, in “Key Engineering Materials” (Trans. Tech. Publications Switzerland, 2001) Vols. 192–195, p. 123.

    Google Scholar 

  10. C. VITALE BROVARONE, E. VERNÉ, A. KRAJEWSKI and A. RAVAGLIOLI, J. Eur. Ceram. Soc.21 (2001) 2855.

    Article  Google Scholar 

  11. E. VERNÈ, M. BOSETTI, C. VITALE BROVARONE, C. MOISESCU, F. LUPO, S. SPRIANO and M. CANNAS, Biomat. 23 (2002) 3395.

    Article  Google Scholar 

  12. C. VITALE BROVARONE and E. VERNE’, in 7th meeting and Conference on Ceramics, Cells and Tissues, Biomimetic Engineering, a New Role for Ceramics, edited by A. Ravaglioli and A. Krajewski (ISTEC-CNR Faenza, 2002) p. 137.

  13. M. FERRARIS, P. RABAJOLI, F. BROSSA and L. PARACCHINI, J. Am. Ceram. Soc. 79 (1996) 1515.

    Google Scholar 

  14. E. VERNÉ, M. FERRARIS, A. VENTRELLA, L. PARACCHINI, A. KRAJEWSKI and A. RAVAGLIOLI, J. Eur. Ceram. Soc. 18 (1998) 363.

    Article  Google Scholar 

  15. E. VERNÉ, M. FERRARIS, C. JANA and L. BARACCHINI, ibid. 20 (2000) 473.

    Article  Google Scholar 

  16. M. FERRARIS, P. RABAJOLI, F. BROSSA and L. PARACCHINI, J. Am. Ceram. Soc. 79 (1996) 1515.

    Google Scholar 

  17. C. JANA, W. NISCH and G. GRIMM, in “Advances in Science and Technology,” edited by Vincenzini (Materials in Clinical Applications, Techna, Faenza, 1995) Vol. 12, p. 257.

  18. J. M. GOMEZ VEGA, E. SAIZ, A. P. TOMSIA, G. W. MARSHALL and S. J. MARSHALL, Biomat. 21 (2000) 105.

    Article  Google Scholar 

  19. A. PAZO, E. SAIZ and A.P. TOMSIA, Acta Mater. 46 (1998) 2551.

    Article  Google Scholar 

  20. J. M. GOMEZ-VEGA, E. SAIZ and A. P. TOMSIA, J. Biomed. Mater. Res. 46 (1999) 549.

    Article  PubMed  Google Scholar 

  21. T. SOHMURA, H. TAMASAKI, T. OHARA and J. TAKAHASHI, J. Biomed Mater Res (Appl Biomater) 58 (2001) 478.

    Article  Google Scholar 

  22. L. L. HENCH, in “An Introduction to Bioceramics,” edited by L. L. Hench and J. Wilson (World Scientific Publ., 1993) Vol. 1, p. 41.

  23. C. KIM and S. JEE, J. Eur. Cer. Soc. 23 (2003) 1803.

    Article  Google Scholar 

  24. T. KOKUBO, H. KUSHITAI, C. OHTSUKI, S. SAKKA and T. YAMAMURO, J. Mater. Sci.: Mater. Med. 3 (1992) 79.

    Article  Google Scholar 

  25. O. PEITL, E. ZANOTTO and L.L. HENCH, J. Non. Cryst. Sol. 292 (2001) 115.

    Article  Google Scholar 

  26. T. KOKUBO, M. SHIGEMATSU, Y. NAGASHIMA, M. TASHIRO, T. NAKAMURA, T. YAMAMURO and S. HIGASHI, Bull. Inst. Chem. Res. Kyoto. Univ. 60 (1982) 260.

    Google Scholar 

  27. T. KOKUBO, J. Non Cryst. Solids 120 (1990) 138.

    Article  Google Scholar 

  28. T. KOKUBO, H. KIM and M. KAWASHITA, Biomat. 24 (2003) 2161.

    Article  Google Scholar 

  29. L. L. HENCH and O. ANDERSSON, in “Introduction to Bioceramics,” edited by L. L. Hench and J. Wilson (World Scientific Pub., 1993) Vol. 1, p. 261.

  30. S. W. K. KWEH, K. A. KHOR and P. CHEANG, Biomat. 21 (2000) 1223.

    Article  Google Scholar 

  31. E. S. THAIN, K. A. KHOR, N. H. LOH and S. B. TOR, ibid. 22 (2001) 1225.

    Article  Google Scholar 

  32. K. YAMASHITA, K. E. YONEHARA, X. DING, M. NAGAI and T. UMEGAKI, J. Biomed. Mater. Res. (Appl Biomater) 43 (1998) 46.

    Article  Google Scholar 

  33. C. C. MARDARE, A. I. MARDARE, J. F. R. FERANDES, E. JOANNI, S. C. A. PINA, FERNANDES and R. N. CORREIRA, J. Eur. Cer. Soc. 23 (2003) 1027.

    Article  Google Scholar 

  34. X. NIE, A. LEYLAND and A. MATTHEWS, Surf. Coat. Techn. 125 (2000) 407.

    Article  Google Scholar 

  35. F. BRANDA, F. ARCOBELLO-VARLESE, A. COSTANTINI and G. LUCIANI, Biomater. 23 (2002) 711.

    Article  Google Scholar 

  36. M. FERRARIS, E. VERNÉ, C. MOISESCU, A. RAVAGLIOLI and A. KRAJEWSKI, in “Bioceramic Coatings for Guided Bone Growth,” edited by A. Ravaglioli and A. Krajewski (Gruppo Editoriale Faenza Editrice, 1996) p. 31

  37. K. OHURA, T. NAKAMURA, T. YAMAMURO, Y. EBISAWA, T. KOKUBO, Y. KOTOURA and M. OKA, J. Mater. Sci: Mater. Med. 3 (1992) 95.

    Article  Google Scholar 

  38. H. M. KIM, F. MIYAJI, T. KOKUBO, C. OHTSUKI and T. NAKAMURA, J. Am. Ceram. Soc. 78 (1995) 2405.

    Article  Google Scholar 

  39. G. W. MOREY, F. C. KRACEK and N. L. BOWEN, J. Soc. Glass. Technol. 14 (1930) 158.

    Google Scholar 

  40. I. W. DONALD, J. Mat. Sci. 28 (1993) 2841.

    Article  Google Scholar 

  41. C. OHTSUKI, Y. AOKI, T. KOKUBO, Y. BANDO, M. NEO and T. NAKAMURA, J. Ceram. Soc. Jpn. 103 (1995) 449.

    Google Scholar 

  42. P. W. MCMILLAN, in “The Properties of Glass-Ceramics,” edited by J.P. Roberts and P. Popper (Academic Press Inc., London, 1979) p. 225.

    Google Scholar 

  43. S. FUJIBAYASHI, M. NEO, H. KIM, T. KOKUBO and T. NAKAMURA, Biomat. 24 (2003) 1349.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Materials Science and Chemical Engineering Department, Polytechnic of Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy

    C. Vitale-Brovarone & E. Verné

Authors
  1. C. Vitale-Brovarone
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Verné
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to C. Vitale-Brovarone.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vitale-Brovarone, C., Verné, E. SiO2-CaO-K2O coatings on alumina and Ti6Al4V substrates for biomedical applications. J Mater Sci: Mater Med 16, 863–871 (2005). https://doi.org/10.1007/s10856-005-3583-4

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10856-005-3583-4

Keywords

Search

Navigation