Skip to main content
Log in

Capture and reversible storage of volatile iodine by porous carbon with high capacity

  • Original Paper
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The capture of iodine using porous materials has attracted considerable interest. In this work, porous carbon with a special surface area of 1973 m2 g−1 was prepared by simple activation method. As an adsorbent, the adsorption capacity of the resulting porous carbon could reach up to 376 wt% for iodine vapor and 460 mg g−1 for iodine uptake in cyclohexane, which both are among the highest values reported up to now. Taking advantages of its high special surface area, easy preparation, low cost, as well as good regeneration, the resulting porous carbon shows great potential in the removal of radioactive iodine at different states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Ewing RC, von Hippel FN (2009) Nuclear waste management in the United States—starting over. Science 325:151–152

    Article  Google Scholar 

  2. Sigen A, Zhang Y, Li Z, Xia H, Xue M, Liu X, Mu Y (2014) Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer. Chem Commun 50:8495–8498

    Article  Google Scholar 

  3. Sava DF, Rodriguez MA, Chapman KW, Chupas PJ, Greathouse JA, Crozier PS, Nenoff TM (2011) Capture of volatile iodine, a gaseous fission product, by zeolitic imidazolate framework-8. J Am Chem Soc 133:12398–12401

    Article  Google Scholar 

  4. Riley BJ, Chun J, Ryan JV, Matyáš J, Li XS, Matson DW, Sundaram SK, Strachan DM, Vienna JD (2011) Chalcogen-based aerogels as a multifunctional platform for remediation of radioactive iodine. RSC Adv 1:1704–1715

    Article  Google Scholar 

  5. Chapman KW, Chupas PJ, Nenoff TM (2010) Radioactive iodine capture in silver-containing mordenites through nanoscale silver iodide formation. J Am Chem Soc 132:8897–8899

    Article  Google Scholar 

  6. Liu Q, Ma J, Dong Y (2011) Highly efficient iodine species enriching and guest-driven tunable luminescent properties based on a cadmium(II)-triazole MOF. Chem Commun 47:7185–7187

    Article  Google Scholar 

  7. Huang P, Kuo C, Hsieh C, Horng Y (2012) Selective capture of volatile iodine using amorphous molecular organic solids. Chem Commun 48:3227–3229

    Article  Google Scholar 

  8. Zeng M, Wang Q, Tan Y, Hu S, Zhao H, Long L, Kurmoo M (2010) Rigid pillars and double walls in a porous metal-organic framework: single-crystal to single-crystal, controlled uptake and release of iodine and electrical conductivity. J Am Chem Soc 132:2561–2563

    Article  Google Scholar 

  9. Yin Z, Wang Q, Zeng M (2012) Iodine release and recovery, influence of polyiodide anions on electrical conductivity and nonlinear optical activity in an interdigitated and interpenetrated bipillared-bilayer metal-organic framework. J Am Chem Soc 134:4857–4863

    Article  Google Scholar 

  10. Yu F, Li D, Cheng L, Yin Z, Zeng M, Kurmoo M (2015) Porous supramolecular networks constructed of one-dimensional metal-organic chains: carbon dioxide and iodine capture. Inorg Chem 54:1655–1660

    Article  Google Scholar 

  11. Sun F, Yin Z, Wang Q, Sun D, Zeng M, Kurmoo M (2013) Tandem postsynthetic modification of a metal-organic framework by thermal elimination and subsequent bromination: effects on absorption properties and photoluminescence. Angew Chem Int Ed 52:4538–4543

    Article  Google Scholar 

  12. Tom H, Schmidtmann M, Cooper AI (2011) Molecular doping of porous organic cages. J Am Chem Soc 133:14920–14923

    Article  Google Scholar 

  13. Chen Y, Sun H, Yang R, Wang T, Pei C, Xiang Z, Zhu Z, Liang W, Li A, Deng W (2015) Synthesis of conjugated microporous polymer nanotubes with large surface areas as absorbents for iodine and CO2 uptake. J Mater Chem A 3:87–91

    Article  Google Scholar 

  14. Chien C-C, Huang Y-P, Wang W-C, Chao J-H, Wei Y-Y (2011) Efficiency of moso bamboo charcoal and activated carbon for adsorbing radioactive iodine. Clean Soil Air Water 39:103–108

    Article  Google Scholar 

  15. Zhou J, Hao S, Gao L, Zhang Y (2014) Study on adsorption performance of coal based activated carbon to radioactive iodine and stable iodine. Ann Nucl Energy 72:237–241

    Article  Google Scholar 

  16. Mianowski A, Owczarek M, Marecka A (2007) Surface area of activated carbon determined by the iodine adsorption number. Energy Sources Part A 29:839–850

    Article  Google Scholar 

  17. Raipur B, Bansal RC (1965) Iodine adsorption method for measuring surface area of carbon blacks. Carbon 3:227–300

    Article  Google Scholar 

  18. González-García CM, González JF, Román S (2011) Removal efficiency of radioactive methyl iodide on TEDA-impregnated activated carbons. Fuel Process Technol 92:247–252

    Article  Google Scholar 

  19. Wang H, Gao Q, Hu J (2009) High hydrogen storage capacity of porous carbons prepared by using activated carbon. J Am Chem Soc 131:7016–7022

    Article  Google Scholar 

  20. Wang R, Wang P, Yan X, Lang J, Peng C, Xue Q (2012) Promising porous carbon derived from celtuce leaves with outstanding supercapacitance and CO2 capture performance. ACS Appl Mater Interfaces 4:5800–5806

    Article  Google Scholar 

  21. Sun H, Li A, Zhu Z, Liang W, Zhao X, La P, Deng W (2013) Superhydrophobic activated carbon-coated sponges for separation and absorption. ChemSusChem 6:1057–1062

    Article  Google Scholar 

  22. Liu Y, Xue JS, Zheng T, Dahn JR (1996) Mechanism of lithium insertion in hard carbons prepared by pyrolysis of epoxy resins. Carbon 34:193–200

    Article  Google Scholar 

  23. Cuesta A, Dhamelincourt P, Laureyns J, Martinez-Alonso A, Tascon JMD (1994) Raman microprobe studies on carbon materials. Carbon 32:1523–1532

    Article  Google Scholar 

  24. Pimenta MA, Dresselhaus G, Dresselhaus MS, Cancado LG, Jorio A, Saito R (2007) Studying disorder in graphite-based systems by Raman spectroscopy. Phys Chem Chem Phys 9:1276–1291

    Article  Google Scholar 

  25. Dresselhaus MS, Jorio A, Hofmann M, Dresselhaus G, Saito R (2010) Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett 10:751–758

    Article  Google Scholar 

  26. Li M, Liu C, Cao H, Zhao H, Zhang Y, Fan Z (2014) KOH self-templating synthesis of three-dimensional hierarchical porous carbon materials for high performance supercapacitors. J Mater Chem A 2:14844–14851

    Article  Google Scholar 

  27. Qu D (2008) Investigation of hydrogen physisorption active sites on the surface of porous carbonaceous materials. Chem Eur J 14:1040–1046

    Article  Google Scholar 

  28. Yu J, Gu M, Bian C, Xu X, Tang TB (2013) An impedance spectroscopy study of the rotation and reorientation of water molecules in hydrated graphite. Carbon 61:367–372

    Article  Google Scholar 

  29. Qin H, Gao P, Wang F, Zhao L, Zhu J, Wang A, Zhang T, Wu R, Zou H (2011) Highly efficient extraction of serum peptides by ordered mesoporous carbon. Angew Chem Int Ed 50:12218–12221

    Article  Google Scholar 

  30. Choi M, Ryoo R (2007) Mesoporous carbons with KOH activated framework and their hydrogen adsorption. J Mater Chem 17:4204–4209

    Article  Google Scholar 

  31. Zhu Y, Murali S, Stoller MD, Ganesh KJ, Cai W, Ferreira PJ, Pirkle A, Wallace RM, Cychosz KA, Thommes M, Su D, Stach EA, Ruoff RS (2011) Carbon-based supercapacitors produced by activation of graphene. Science 332:1537–1541

    Article  Google Scholar 

  32. Raymundo-Piñeroa E, Azaïs P, Cacciaguerra T, Cazorla-Amorós D, Linares-Solano A, Béguin F (2005) KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organization. Carbon 43:786–795

    Article  Google Scholar 

  33. Portet C, Lillo-Ródenas MÁ, Linares-Solano A, Gogotsi Y (2009) Capacitance of KOH activated carbide-derived carbons. Phys Chem Chem Phys 11:4943–4945

    Article  Google Scholar 

Download references

Acknowledgements

The authors are grateful to the National Natural Science Foundation of China (Grant Nos. 51263012, 51262019, 51462021 and 51403092), Gansu Provincial Science Fund for Distinguished Young Scholars (Grant No. 1308RJDA012), Support Program for Hongliu Young Teachers (Q201411), Hongliu Elitist Scholars of LUT (J201401), Support Program for Longyuan Youth, and Fundamental Research Funds for the Universities of Gansu Province.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to An Li.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 1524 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sun, H., La, P., Zhu, Z. et al. Capture and reversible storage of volatile iodine by porous carbon with high capacity. J Mater Sci 50, 7326–7332 (2015). https://doi.org/10.1007/s10853-015-9289-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-015-9289-1

Keywords

Navigation