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Corrosion inhibition of aluminum by novel phthalocyanines in hydrochloric acid solution

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Abstract

The corrosion inhibition characteristics of quaternized 1,(4)-tetrakis[(2-mercapto)pyridine]phthalocyanine (I) and 2,3-octakis[(2-mercapto)pyridine] phthalocyanine (II) on aluminum in 0.1 M HCl solution has been studied by means of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The maximum inhibition efficiency was obtained for compound I with two-electrochemical techniques applied. Langmuir isotherm fits well the experimental data. The inhibition efficiency increases with increase in the phthalocyanine concentration, but decreases with an increase in temperature. The phthalocyanines act predominately as cathodic inhibitor.

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Acknowledgement

Thanks to author Devrim Atilla and Mahmut Durmuş for synthesizing phthalocyanines. This project was supported by TÜBITAK (project no. MAG107M476).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Gebze Institute of Technology, 41400, Gebze, Kocaeli, Turkey

    O. K. Özdemir & A. Aytaç

  2. Department of Chemistry, Faculty of Science, Gazi University, Teknikokullar, 06500, Ankara, Turkey

    A. Aytaç

  3. Department of Chemistry, Gebze Institute of Technology, 41400, Gebze, Kocaeli, Turkey

    D. Atilla & M. Durmuş

Authors
  1. O. K. Özdemir
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  2. A. Aytaç
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  3. D. Atilla
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  4. M. Durmuş
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Correspondence to A. Aytaç.

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Özdemir, O.K., Aytaç, A., Atilla, D. et al. Corrosion inhibition of aluminum by novel phthalocyanines in hydrochloric acid solution. J Mater Sci 46, 752–758 (2011). https://doi.org/10.1007/s10853-010-4808-6

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  • DOI: https://doi.org/10.1007/s10853-010-4808-6

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