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Transcrystallisation in PP/flax composites and its effect on interfacial and mechanical properties

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Abstract

The effect of flax fibre reinforcement on the crystallisation behaviour of polypropylene (PP) was investigated using a hot-stage polarising optical microscope. To follow the crystallisation kinetics, crystallisation temperature and time were varied. At crystallisation temperatures between 130 and 138 °C the most uniform and thickest transcrystalline layers were formed. The effect of transcrystallisation on the interfacial shear strength (IFSS) in micro-composites was studied by the fibre pull-out test method. It was found that the IFSS of the PP/flax system is slightly decreased with the presence of a transcrystalline interphase. Finally, the influence of the formation of a transcrystalline zone on the macromechanical properties of compression moulded PP/flax composites was studied.

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References

  1. Heijenrath R, Peijs T (1996) Adv Compos Lett 5(3):81

    Article  Google Scholar 

  2. Peijs T (2000) Mater Technol 15(4):281

    Article  CAS  Google Scholar 

  3. Singleton ACN, Baillie CA, Beaumont PWR, Peijs T (2003) Compos Part B-Eng 34(6):519

    Article  CAS  Google Scholar 

  4. Soykeabkaew N, Supaphol P, Rujiravanit R (2004) Carbohyd Polym 58:53

    Article  CAS  Google Scholar 

  5. Van Den Oever MJA, Bos HL, Van Kemenade MJJM (2000) Appl Compos Mater 7:387

    Article  Google Scholar 

  6. Garkhail SK, Heijenrath RWH, Peijs T (2000) Appl Compos Mater 7(5–6):351

    Article  CAS  Google Scholar 

  7. Peijs T, Garkhail S, Heijenrath R, van den Oever M, Bos H (1998) Macromol Symp 127:193

    Article  CAS  Google Scholar 

  8. Pott GT, Pilot RJ, van Hazendonk JM (1997) In: EUROMAT 97 - Proceedings of the 5th European conference on advanced materials and processes and applications: materials, functionality & design, vol 2, p 107

  9. Ruyter HP, Hortulanus A (1995) US Patent 5,451,361

  10. Stamboulis A, Baillie CA, Garkhail SK, Van Melick HGH, Peijs T (2000) Appl Compos Mater 7(5–6):273

    Article  CAS  Google Scholar 

  11. Stamboulis A, Baillie CA, Peijs T (2001) Compos Part A-Appl S 32(8):1105

    Article  Google Scholar 

  12. Thomason JL, van Rooyen AA (1992) J Mater Sci 27:889. doi:https://doi.org/10.1007/BF01197638

    Article  CAS  Google Scholar 

  13. Krautz FG (1971) SPE J 27:74

    CAS  Google Scholar 

  14. Young RJ, Heppenstall-Butler M (2008) Encyclopedia of materials: science and technology (polymer transcrystallinity in composites), p 7535

    Chapter  Google Scholar 

  15. Arbelaiz A, Fernandez B, Ramos JA, Mondragon I (2006) Thermochim Acta 440:111

    Article  CAS  Google Scholar 

  16. Barber AH, Wiesel E, Wagner HD (2002) Comp Sci Technol 62(15):1957

    Article  CAS  Google Scholar 

  17. Cai Y, Petermann J, Wittich H (1997) J Appl Polym Sci 65:67

    Article  CAS  Google Scholar 

  18. Chen EJH, Hsiao BS (1992) Polym Eng Sci 32:280

    Article  CAS  Google Scholar 

  19. Gray DG (1974) Polym Lett Ed 12:645

    Article  CAS  Google Scholar 

  20. Huang Y, Petermann J (1995) J Appl Polym Sci 55:981

    Article  CAS  Google Scholar 

  21. Mathew AP, Oksman K, Sain M (2006) J Appl Polym Sci 101:300

    Article  CAS  Google Scholar 

  22. Moon C-K (1998) J Appl Polym Sci 67:1191

    Article  CAS  Google Scholar 

  23. Son S-J, Lee Y-M, Im S-S (2000) J Mater Sci 35:5767. doi:https://doi.org/10.1023/A:1004827128747

    Article  CAS  Google Scholar 

  24. Thomason JL, van Rooyen AA (1992) J Mater Sci 27:897. doi:https://doi.org/10.1007/BF01197639

    Article  CAS  Google Scholar 

  25. Wang C, Hwang LM (1996) J Polym Sci Pol Phys 34:47

    Article  CAS  Google Scholar 

  26. Wang C, Liu CR (1999) Polymer 40:289

    Article  Google Scholar 

  27. Wang K, Guo M, Zhao D, Zhang Q, Du R, Fu Q, Dong X, Han CC (2006) Polymer 47:8374

    Article  CAS  Google Scholar 

  28. Zafeiropoulos NE, Baillie CA, Matthews FL (2001) Compos Part A-Appl S 32:525

    Article  Google Scholar 

  29. Zafeiropoulos NE, Baillie CA, Matthews FL (2001) Adv Compos Lett 10(5):293

    Article  Google Scholar 

  30. Zafeiropoulos NE, Baillie CA, Matthews FL (2001) Adv Compos Lett 10(6):229

    Article  Google Scholar 

  31. Wagner HD, Lustiger A, Marzinsky CN, Mueller RR (1993) Compos Sci Technol 48:181

    Article  CAS  Google Scholar 

  32. Clark RL, Kander RG (1996) J Eng Appl Sci 2:2568

    Google Scholar 

  33. Heppenstall-Butler M, Bannister DJ, Young RJ (1996) Compos Part A-Appl S 27(9):833

    Article  Google Scholar 

  34. Gati A, Wagner HD (1997) Macromolecules 30:3933

    Article  CAS  Google Scholar 

  35. Wood JR, Marom G (1997) Appl Compos Mater 4(4):197

    CAS  Google Scholar 

  36. Pompe G, Mader E (2000) Compos Sci Technol 60:2159

    Article  CAS  Google Scholar 

  37. Folkes MJ, Hardwick ST (1987) J Mater Sci Lett 6:656

    Article  CAS  Google Scholar 

  38. Folkes MJ, Hardwick ST (1990) J Mater Sci 25:2598. doi:https://doi.org/10.1007/BF00638065

    Article  CAS  Google Scholar 

  39. Zhang M, Xu J, Zhang Z, Zeng H, Xiong X (1996) Polymer 37:5151

    Article  CAS  Google Scholar 

  40. van den Heuvel PWJ, Hogeweg B, Peijs T (1997) Compos Part A-Appl S 28(3):237

    Article  Google Scholar 

  41. Zhandarov SF, Pisanovab EV (1997) Compos Sci Technol 57:957

    Article  CAS  Google Scholar 

  42. Bannister DJ, Angrews MC, Cervenka AJ, Young RJ (1995) Compos Sci Technol 53(4):411

    Article  CAS  Google Scholar 

  43. Piggott MR (1997) Compos Sci Technol 57(8):965

    Article  CAS  Google Scholar 

  44. Mäder E, Pisanova E (2000) Polym Compos 21(3):361

    Article  Google Scholar 

  45. Loos J, Schimanski T, Hofman J, Peijs T, Lemstra PJ (2001) Polymer 42:3827

    Article  CAS  Google Scholar 

  46. Assouline E, Pohl S, Fulchiron R, Gerard J-F, Lustiger A, Wagner HD, Marom G (2000) Polymer 41:7843

    Article  CAS  Google Scholar 

  47. Assouline E, Wachtel E, Grigull S, Lustiger A, Wagner HD, Marom G (2001) Polymer 42:6237

    Article  Google Scholar 

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Correspondence to Ton Peijs.

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Garkhail, S., Wieland, B., George, J. et al. Transcrystallisation in PP/flax composites and its effect on interfacial and mechanical properties. J Mater Sci 44, 510–519 (2009). https://doi.org/10.1007/s10853-008-3089-9

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  • DOI: https://doi.org/10.1007/s10853-008-3089-9

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