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The solid-state structures of the ethanol solvated complexes of para-sulphonato-calix[4]arene with magnesium and calcium ions

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Abstract

The structures ethanol solvated complexes of para-sulphonato-calix[4]arene with magnesium and calcium have been determined. Both show the classical bilayer structure of para-sulphonato-calix[4]arene. The cations are situated between the bilayers. In the case of the magnesium complex the cation is octahedrally coordinated by six water molecules, however for the calcium complex the cation is coordinated in two different geometries by water molecules, bridging oxygen atoms of the sulphonate anions and an oxygen of an ethanol molecule. Both complexes contain an ethanol molecule embedded in the macrocyclic cavity.

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Acknowledgments

Y.T. thanks the Unversité Lyon 1 for financial support.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland

    Kinga Suwinska

  2. Centre de diffractométrie Henri Longchambon, Unversité Lyon 1, 69622, Villeurbanne, France

    Erwann Janneau

  3. LMI, CNRS UMR 5615, Unversité Lyon 1, 69622, Villeurbanne, France

    Yannick Tauran & Anthony W. Coleman

Authors
  1. Kinga Suwinska
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  2. Erwann Janneau
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  3. Yannick Tauran
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  4. Anthony W. Coleman
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Correspondence to Anthony W. Coleman.

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Suwinska, K., Janneau, E., Tauran, Y. et al. The solid-state structures of the ethanol solvated complexes of para-sulphonato-calix[4]arene with magnesium and calcium ions. J Incl Phenom Macrocycl Chem 79, 177–183 (2014). https://doi.org/10.1007/s10847-013-0342-x

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  • DOI: https://doi.org/10.1007/s10847-013-0342-x

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