Abstract
In order to develop the new anode materials for Al/air batteries, electrochemical properties of pure aluminium (99.999 %), technical grade aluminium (99.8 %) and the alloys with indium and tin, i.e. Al—0.1 % In, Al—0.2 % Sn and Al—0.1 % In—0.2 % Sn have been investigated in 2 mol dm−3 NaCl solution. The aluminium materials were polarized anodically in the range 20–100 mA cm−2 for a 30 min period. During the anodic polarization variation in potential was recorded as a function of time and the simultaneous hydrogen evolution was measured. The rate of hydrogen evolution reaction was found to increase with increasing anodic polarization which is characteristic of the negative difference effect. The additional information concerning the corrosion behaviour of the tested materials was provided by light microscope imaging. The results show that the examined technical grade aluminium alloys could serve as suitable anodes for Al/air batteries containing sodium chloride electrolyte; with Al–In exhibiting the most remarkable characteristics. The addition of In as alloying component to aluminium reduces electrode polarization, decreases hydrogen evolution rate and increases the anode efficiency.
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Downing BW (2012) In: Zhang L, Sun X, Liu H, Zhang J, Liu R-S (eds) Electrochemical technologies for energy storage and conversion. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 239–277
Macdonald DD, Real S, Urquidi-Macdonald M (1988) J Electrochem Soc 135:2397
Vargel C (2004) Corrosion of aluminium. Elsevier, Oxford
Li Q, Bjerrum NJ (2002) J Power Sources 110:1
Despić AR, Dražić DM, Perunović MM, Ciković N (1976) J Appl Electrochem 6:527
Mance A, Cerović D, Mihajlović A (1984) J Appl Electrochem 14:459
Hori Y, Takao J, Shomon H (1985) Electrochim Acta 30:1121
Tuck CDS, Hunter JA, Scamans GM (1987) J Electrochem Soc 134:2970
Real S, Urquidi-Macdonald M, Macdonald DD (1988) J Electrochem Soc 135:1633
El Shayeb HA, Abd El Wahab FM, Zein El Abedin S (1999) J Appl Electrochem 29:473
Dražić DM, Popić JP (1999) J Appl Electrochem 29:43
Mathiyarasu J, Nehru LC, Subramanian P, Palaniswamy N, Rengaswamy NS (2001) Anti Corros Methods Mater 48:324
Zein El Abedin S, Saleh AO (2004) J Appl Electrochem 34:331
Zein El Abedin S, Endres F (2004) J Appl Electrochem 34:1071
Nestoridi M, Pletcher D, Wood RJK, Wang S, Jones RL, Stokes KR, Wilcock I (2008) J Power Sources 178:445
Gudić S, Smoljko I, Kliškić M (2010) J Alloys Compd 505:54
Gudić S, Smoljko I, Kliškić M (2010) Mater Chem Phys 121:561
Zhuk AZ, Sheindlin AE, Kleymenov BV, Shkolnikov EI, Lopatin MY (2006) J Power Sources 157:921
McCafferty E (2003) Corros Sci 45:302
James WJ (1974) In: Fontana MG, Staehle RW (eds) Advances in corrosion science and technology, vol 4. Plenum Press, New York, p 85
Straumanis ME (1961) J Electrochem Soc 108:1087
Wang HZ, Leung DYC, Leung MKH, Ni M (2009) Renew Sustain Energy Rev 13:845
Franzoni F, Milani M, Montorsi L, Golovitchev V (2010) Int J Hydrogen Energy 35:1548
Stevanović RM, Despić AR, Dražić DM (1988) Electrochim Acta 33:397
Despić A, Parkhutik VP (1989) In: White RE, Conwas BE, Bockris JO’M (eds) Modern aspects of electrochemistry. Plenum Press, New York, pp 401–495
Muñoz AG, Saidman SB, Bessone JB (2002) Corros Sci 44:2171
Dražić DM, Zečević SK, Atanasoski RT, Despić AR (1983) Electrochim Acta 28:751
Kaesche H (2003) Corrosion of metals: physicochemical principles and current problems. Springer, Berlin\Heidelberg
John K (2010) In: Schütze M, Wieser D, Bender R (eds) Corrosion resistance of aluminium and aluminium alloys. Wiley-VCH, Weinheim, pp 139–142
Bargeron CB, Benson RC (1980) J Electrochem Soc 127:2528
Baumgärtner M, Kaesche H (1990) Corros Sci 31:231
Balázs L, Gouyet J-F (1995) Phys A 217:319
Despić AR, Dražić DM, Zečević SK, Atanasoski RT (1981) Electrochim Acta 26:173
Ambat R, Davenport AJ, Scamans GM, Afseth A (2006) Corros Sci 48:3455
Buchheit RG (1995) J Electrochem Soc 142:3994
Szklarska-Smialowska Z (1999) Corros Sci 41:1743
Birbilis N, Buchheit RG (2005) J Electrochem Soc 152:B140
Carroll WM, Breslin CB (1992) Corros Sci 33:1161
Gundersen JTB, Aytaç A, Nordlien JH, Nisancioglu K (2004) Corros Sci 46:697
Graver B, van Helvoort A, Walmsley JC, Nisancioglu K (2006) Mater Sci Forum 519–521:673
Graver B, Pedersen AM, Nisancioglu K (2009) ECS Trans 16:55
Saidman SB, Bessone JB (1997) Electrochim Acta 42:413
Trasatti S (1972) J Electroanal Chem 39:163
Nestoridi M, Pletcher D, Wharton JA, Wood RJ (2009) J Power Sources 193:895
Birkin PR, Nestoridi M, Pletcher D (2009) Electrochim Acta 54:6668
Breslin CB, Carroll WM (1993) Corros Sci 34:1099
Iudice de Souza JP, Vielstich W (2010) Seawater aluminum/air cells. Handbook of fuel cells
Nestoridi M (2009) The study of aluminium anodes for high power density Al-air batteries with brine electrolytes. Dissertation, University of Southampton
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Smoljko, I., Gudić, S., Kuzmanić, N. et al. Electrochemical properties of aluminium anodes for Al/air batteries with aqueous sodium chloride electrolyte. J Appl Electrochem 42, 969–977 (2012). https://doi.org/10.1007/s10800-012-0465-6
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DOI: https://doi.org/10.1007/s10800-012-0465-6