Abstract
New experimental data for the viscosity of molten lithium nitrate from its melting point up to about 700 K are reported. The measurements were taken, for the first time, with an oscillating-cup viscometer with an estimated uncertainty of 3 %. The obtained data were compared with previous works. It was concluded that there are still large discrepancies between different sets of data. Our data follow the Arrhenius behavior with an activation energy for viscous flow of \(E_{\eta } \hbox {= 19.3}\) \(\hbox {kJ}{\cdot }\hbox {mol}^{-1}\), slightly higher than previous recommendations.
Similar content being viewed by others
References
J.G. Cordaro, N.C. Rubin, R.W. Bradshaw, J. Sol. Energy Eng. 133, 011014 (2011)
R.W. Bradshaw, Sandia Report, SAND2010-1129 (2010)
T. Wang, D. Mantha, R.G. Reddy, Appl. Energy 102, 1422 (2013)
A.G. Fernandez, S. Ushak, H. Galleguillos, F.J. Pérez, Appl. Energy 119, 131 (2014)
V.M.B. Nunes, M.J.V. Lourenço, F.J.V. Santos, C.A. Nieto de Castro, Int. J. Thermophys. 27, 1638 (2006)
V.M.B. Nunes, M.J.V. Lourenço, F.J.V. Santos, C.A.Nieto de Castro, Viscosity of molten lithium nitrate in Euchem Conference on Molten Salts and ionic Liquids, Hammamet, Tunísia (2006)
C.A. Nieto de Castro, F.J.V. Santos, Chim. Oggi Chem. Today 25, 20 (2007)
G.J. Janz, F.W. Dampier, G.R. Lakshiminarayanan, P.K. Lorenz, R.P.T. Tomkins, Natl. Stand. Ref. Data Ser., Natl. Bur. Stand. 15, 25 (1968)
R.S. Dantuma, Z. Anorg. Chem. 175, 1 (1928)
G.J. Janz, S.W. Lurie, G.L. Gardner, J. Chem. Eng. Data 23, 14 (1978)
G.J. Janz, NIST Standard Reference Database, vol 27, (Gaithersburg, MD, 1991)
I.G. Murgulescu, S. Zuca, Electrochim. Acta 11, 1383 (1966)
S. Zuca, Rev. Roum. Chim. 15, 1277 (1970)
P.I. Protsenko, O.N. Razumovskaya, Zhur. Prikl. Khim. 38, 2355 (1965)
V.M.B. Nunes, F.J.V. Santos, Nieto de Castro, C. A. Int. J. Thermophys. 19, 427 (1998)
K.H. Stern, J. Phys. Chem. Ref. Data 1, 747 (1972)
I. Brovkina, A. Farmakovskaya, V. Khokhlov, Electrochem. Molten Solid Electrolytes 21, 4 (1974)
V.G. Smotrakov, N.P. Popovskaya, V.A. Tereshenko, Zhur. Prikl. Khim 45, 2627 (1972)
V.M.B. Nunes, M.J.V. Lourenço, P. Panandiker, F.J.V. Santos, C.A. Nieto de Castro, in Proceedings of the 7th International Symposium on Molten Salts Chemistry and Technology, ed. by P. Taxil et al., vol. 2 (Toulouse, France, 2005), pp. 783–786
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Nunes, V.M.B., Lourenço, M.J.V., Santos, F.J.V. et al. Measurements of the Viscosity of Molten Lithium Nitrate by the Oscillating-cup Method. Int J Thermophys 38, 13 (2017). https://doi.org/10.1007/s10765-016-2150-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10765-016-2150-1