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The Discontinuity in the First Derivative of the ITS-90 at the Triple Point of Water

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Abstract

This paper investigates the discontinuity in the derivative [dW/dT 90]TPW of the ITS-90 at the triple point of water, using data for over 40 calibrated standard platinum resistance thermometers (SPRTs). It finds that the discontinuity is in most cases somewhere between 0 and −6 parts in 105, in relative terms, but that the higher numerical values are obtained for ‘less ideal’ SPRTs (those with lower temperature coefficients of resistance), and also for sub-ranges not extending beyond the indium point. These results are investigated vis-à-vis the long-standing observation that the ITS-90 reference values W r(Ga) and W r(Hg) are not completely consistent with data for W(Ga) and W(Hg) for real SPRTs. It discusses what may be done in a future scale to ensure continuity in the first derivative, and it concludes with a comment about the acceptance criteria for SPRTs in the scale.

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Correspondence to R. L. Rusby.

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Rusby, R.L. The Discontinuity in the First Derivative of the ITS-90 at the Triple Point of Water. Int J Thermophys 31, 1567–1572 (2010). https://doi.org/10.1007/s10765-010-0794-9

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  • DOI: https://doi.org/10.1007/s10765-010-0794-9

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