The path of movement of the state of a polymer solution in gelation from the point of the initial position to the binodal on the phase separation diagram of the polymer—solvent—precipitator system was calculated. The gelation rate was estimated for trajectories corresponding to diffusion, thermotropic, and mechanotropic mechanisms.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. P. Papkov, Physicochemical Principles of Processing of Polymer Solutions [in Russian], Khimiya, Moscow (1971).
S. A. Vshivkov et al., Vysokomolek. Soedin., 38, No. 5, 844-848 (1996).
A. E. Chalykh, V. K. Gerasimov, and Yu. M. Mikhailov, Phase Diagrams of Polymer Systems [in Russian], Yanus-K, Moscow (1998).
A. L. Kalabin and E. A. Pakshver, Khim. Volokna, No. 2, 27-29 (2000).
A. L. Kalabin and E. A. Pakshver, Teor. Osn. Khim. Tekhnol., 31, No. 6, 574-579 (1997).
A. L. Kalabin, A. V. Kernitskii, and E. A. Pakshver, Khim. Volokna, No. 4, 34-38 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimicheskie Volokna, No. 1, pp. 10-12, January-February, 2010.
Rights and permissions
About this article
Cite this article
Kalabin, A.L., Pakshver, E.A. & Salakhov, M.A. Gelation in the phase space in spinning chemical fibres from polymer solutions. Fibre Chem 42, 10–12 (2010). https://doi.org/10.1007/s10692-010-9215-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10692-010-9215-x