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Maximum availability and mineralogical control of chromium released from AOD slag

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Abstract

AOD (argon oxygen decarburization) slag is the by-product in the stainless steel refining process. Chromium existing in AOD slag can leach out and probably poses a serious threat to the environment. To assess the leaching toxicity of chromium released from AOD slag, the temperature-dependent maximum availability leaching test was performed. To determine the controlling mineralogical phases of chromium released from AOD slag, a Visual MINTEQ simulation was established based on Vminteq30 and the FactSage 7.0 database. The leaching tests indicated that the leaching availability of chromium was slight and mainly consisted of trivalent chromium. Aging of AOD slag under the atmosphere can oxidize trivalent chromium to hexavalent chromium, which could be leached out by rainwater. According to the simulation, the chromium concentration in leachates was controlled by the freely soluble pseudo-binary phases in the pH = 7.0 leaching process and controlled by the Cr2O3 phase in the pH = 4.0 leaching process. Chromium concentrations were underestimated when the controlling phases were determined to be FeCr2O4 and MgCr2O4. Facilitating the generation of the insoluble spinel-like phases during the cooling and disposal process of the molten slag could be an effective approach to decreasing the leaching concentration of chromium and its environmental risk.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (51274085, 51574108) and the State Key Laboratory of Solid Waste Reuse for Building Materials (SWR-2013-010).

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Authors and Affiliations

  1. College of Metallurgy and Energy, North China University of Science and Technology, Tangshan, 063009, People’s Republic of China

    Junguo Li, Bao Liu, Yanan Zeng, Ziming Wang & Zhiyuan Gao

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  1. Junguo Li
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  2. Bao Liu
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  3. Yanan Zeng
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  4. Ziming Wang
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  5. Zhiyuan Gao
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Correspondence to Junguo Li.

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Li, J., Liu, B., Zeng, Y. et al. Maximum availability and mineralogical control of chromium released from AOD slag. Environ Monit Assess 189, 113 (2017). https://doi.org/10.1007/s10661-017-5843-4

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  • DOI: https://doi.org/10.1007/s10661-017-5843-4

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