Skip to main content

Advertisement

Log in

Study of the ambient air metallic elements Cr, Cu, Zn, Cd and Pb at HAF sampling sites

  • Original Paper
  • Published:
Environmental Geochemistry and Health Aims and scope Submit manuscript

Abstract

This study characterized diurnal variations in the compositions of total suspended particulates (TSP) and dry deposits of particulates from ambient air, and the metallic elements that are contained in them at harbor, airport and farmland (HAF) sampling sites from August, 2013 to July, 2014. Two-way ANOVA of the amounts of metallic elements in the TSP and dry deposits was carried out in all four seasons at the HAF sampling sites. The metallic elements Cr and Cu originated in local emission sources at the airport. Metallic elements Zn and Pb originated in local emission sources at the harbor. Finally, metallic element Cd originated in local emissions form farmland. The following results were also obtained. (1) The metallic composition of the TSP differed significantly from that of the dry deposits in all four seasons at the harbor and farmland sampling sites, but not at the airport sampling site. (2) High correlations coefficients were found between the amounts of metallic elements Cr and Cu in the TSP and those in the dry deposits at the airport sampling site. (3) Pb was present in the TSP and the dry deposits at the harbor sampling site.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Arndt, R. L., Carmichael, G. R., & Roorda, J. M. (1998). Seasonal source–receptor relationships in Asia. Atmospheric Environment, 32(8), 1397–1406.

    Article  CAS  Google Scholar 

  • Bech, J., Tume, P., Sokolovska, M., Reverter, F., Sanchez, P., Longan, L., et al. (2008). Pedogeochemical mapping of Cr, Ni, and Cu in soils of the Barcelona Province (Catalonia, Spain): Relationships with soil physico-chemical characteristics. Journal of Geochemical Exploration, 96(2–3), 106–116.

    Article  CAS  Google Scholar 

  • Chen, T., Zheng, Y., Lei, M., Huang, Z., Wu, H., Chen, H., et al. (2005). Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China. Chemosphere, 60(4), 542–551.

    Article  CAS  Google Scholar 

  • Chu, C., Fang, G., Chen, J., & Lin, I. (2008). Ambient air dry deposition and ionic species analysis by using various deposition collectors in Shalu, central Taiwan. Atmospheric Research, 88(3–4), 212–223.

    Article  CAS  Google Scholar 

  • Fabretti, J. F., Sauret, N., Gal, J. F., Maria, P. C., Schärer, U. (2009). Elemental characterization and source identification of PM2.5 using Positive Matrix Factorization: The Malraux road tunnel, Nice, France. Atmospheric Research, 94, 320–329.

    Article  CAS  Google Scholar 

  • Fang, G. C., Chang, C. N., Wu, Y. S., Fu, P. P. C., Yang, I. L., & Chen, M. H. (2004). Characterization, identification of ambient air and road dustpolycyclic aromatic hydrocarbons in central Taiwan, Taichung. Science of the Total Environment, 327, 135–146.

    Article  CAS  Google Scholar 

  • Fang, G. C., Wu, Y. S., Fu, P. P. C., Chang, C. N., Chen, M. H., Ho, T. T., Huang, S. H., & Rau, J. Y. (2005). Metallic elements study of fine and coarse particulates using a versatile air pollutant system at a traffic sampling site. Atmospheric Research, 75(1), 1–14.

    Article  CAS  Google Scholar 

  • Fang, G. C., Huang, Y. L., Huang, J. H., & Liu, C. K. (2012). Dry deposition of Mn, Zn, Cr, Cu and Pb in particles of sizes of 3 m, 5.6 m and 10 m in central Taiwan. Journal of hazardous materials, 203, 158–168.

  • Fujikoshi, Y. (1993). Two-way ANOVA models with unbalanced data. Discrete Mathematics, 116(1–3), 315–334.

    Article  Google Scholar 

  • Galán, E., Fernández-Caliani, J. C., González, I., Aparicio, P., & Romero, A. (2008). Influence of geological setting on geochemical baselines of trace elements in soils. Application to soils of South-West Spain. Journal of Geochemical Exploration, 98(3), 89–106.

    Article  Google Scholar 

  • Giorio, C., Tapparo, A., Scapellato, M. L., Carrieri, M., Apostoli, P., & Bartolucci, G. B. (2013). Field comparison of a personal cascade impactor sampler, an optical particle counter and CEN-EU standard methods for PM10, PM2.5 and PM1 measurement in urban environment. Journal of Aerosol Science, 65, 111–120.

    Article  CAS  Google Scholar 

  • Gray, C. W., McLaren, R. G., & Roberts, A. H. C. (2003). Atmospheric accessions of heavy metals to some New Zealand pastoral soils. Science of the Total Environment, 305(1–3), 105–115.

    Article  CAS  Google Scholar 

  • He, S., Wu, Q., & He, Z. (2014). Synergetic effects of DA-6/GA3 with EDTA on plant growth, extraction and detoxification of Cd by Lolium perenne. Chemosphere, 117, 132–138.

    Article  CAS  Google Scholar 

  • Ho, K. F., Lee, S. C., Cao, J. J., Li, Y. S., Chow, J. C., Watson, J. G., et al. (2006a). Variability of organic and elemental carbon, water soluble organic carbon and isotopes in Hong Kong. Atmospheric Chemistry and Physics, 6(12), 4569–4576.

    Article  CAS  Google Scholar 

  • Ho, K. F., Lee, S. C., & Tsai, W. Y. (2006b). Carbonyl compounds in the roadside environment of Hong Kong. Journal of Hazardous Materials, 133(1–3), 24–29.

    Article  CAS  Google Scholar 

  • Hovmand, M. F., Kemp, K., Kystol, J., Johnsen, I., Riis-Nielsen, T., & Pacyna, J. M. (2008). Atmospheric heavy metal deposition accumulated in rural forest soils of southern Scandinavia. Environmental Pollution, 155(3), 537–541.

    Article  CAS  Google Scholar 

  • Kang, C., Kim, W., Ko, H., & Hong, S. (2009). Asian dust effects on total suspended particulate (TSP) compositions at Gosan in Jeju Island, Korea. Atmospheric Research, 94(2), 345–355.

    Article  CAS  Google Scholar 

  • Kavuri, N. C., Paul, K. K., & Roy, N. (2015). TSP aerosol source apportionment in the urban region of the Indian steel city, Rourkela. Particuology, 20, 124–133.

    Article  Google Scholar 

  • Krishnamoorthy, K., Lu, F., & Mathew, T. (2007). A parametric bootstrap approach for ANOVA with unequal variances: Fixed and random models. Computational Statistics & Data Analysis, 51(12), 5731–5742.

    Article  Google Scholar 

  • Kong, S., Han, B., Bai, Z., Chen, L., Shi, J., & Xu, Z. (2010). Receptor modeling of PM2.5, PM10 and TSP in different seasons and long-range transport analysis at a coastal site of Tianjin, China. Science of the Total Environment, 408, 4681–4694.

    Article  CAS  Google Scholar 

  • Lee, C., Yuan, C., Chang, J., & Yuan, C. (2005). Effects of aerosol species on atmospheric visibility in Kaohsiung City, Taiwan. Journal of the Air and Waste Management Association, 55(7), 1031–1041.

    Article  CAS  Google Scholar 

  • Mage, D. T., Muir, D., Laxen, D. P. H., & Horvath, H. (1996). Discussion. Black smoke as a surrogate for PM10 in health studies. Atmospheric Environment, 30(14), 2647–2650.

    Article  CAS  Google Scholar 

  • Qu, W., Zhang, X., Arimoto, R., Wang, Y., Wang, D., Sheng, L., et al. (2009). Aerosol background at two remote CAWNET sites in western China. Science of the Total Environment, 407(11), 3518–3529.

    Article  CAS  Google Scholar 

  • Schichtel, B. A., Husar, R. B., Falke, S. R., & Wilson, W. E. (2001). Haze trends over the United States, 1980–1995. Atmospheric Environment, 35(30), 5205–5210.

    Article  CAS  Google Scholar 

  • Shen, Z., Cao, J., Arimoto, R., Han, Z., Zhang, R., Han, Y., et al. (2009). Ionic composition of TSP and PM2.5 during dust storms and air pollution episodes at Xi’an, China. Atmospheric Environment, 43(18), 2911–2918.

    Article  CAS  Google Scholar 

  • Tsai, Y. I., & Cheng, M. T. (1999). Visibility and aerosol chemical compositions near the coastal area in Central Taiwan. Science of the Total Environment, 231(1), 37–51.

    Article  CAS  Google Scholar 

  • Tsai, Y. I., Lin, Y. H., & Lee, S. Z. (2003). Visibility variation with air qualities in the metropolitan area in southern Taiwan. Water, Air, and Soil Pollution, 144(1–4), 19–40.

    Article  CAS  Google Scholar 

  • Vicente, A. B., Pardo, F., Sanfeliu, T., Casalta, S., & Bech, J. (2014). Assessment of PM10 and heavy metal concentration in a ceramic cluster (NE Spain) and the influence on nearby soils. Journal of Geochemical Exploration, 144(Part B), 320–327.

    Article  CAS  Google Scholar 

  • Wang, X., Sato, T., Xing, B., Tamamura, S., & Tao, S. (2005). Source identification, size distribution and indicator screening of airborne trace metals in Kanazawa, Japan. Journal of Aerosol Science, 36, 197–210.

    Article  CAS  Google Scholar 

  • Xu, L., Yang, F., Abula, A., & Qin, S. (2013). A parametric bootstrap approach f or two-way ANOVA in presence of possible interactions with unequal variances. Journal of Multivariate Analysis, 115, 172–180.

    Article  Google Scholar 

  • Yadav, A. K., Kumar, K., Bin Hj Awg Kasim, A. M., Singh, M. P., Parida, S. K., & Sharan, M. (2003). Visibility and incidence of respiratory diseases during the 1998 haze episode in Brunei Darussalam. Pure and Applied Geophysics, 160(1–2), 265–277.

    Article  Google Scholar 

  • Yuan, C., Lee, C., Liu, S., Chang, J., Yuan, C., & Yang, H. (2006). Correlation of atmospheric visibility with chemical composition of Kaohsiung aerosols. Atmospheric Research, 82(3–4), 663–679.

    Article  CAS  Google Scholar 

  • Yuan, C., Sau, C., Chen, M., Huang, M., Chang, S., Lin, Y., et al. (2004). Mass concentration and size-resolved chemical composition of atmospheric aerosols sampled at the Pescadores Islands during Asian dust storm periods in the years of 2001 and 2002. Terrestrial, Atmospheric and Oceanic Sciences, 15(5), 857–879.

    Article  Google Scholar 

  • Zhang, J. (2012). An approximate degrees of freedom test for heteroscedastic two-way ANOVA. Journal of Statistical Planning and Inference, 142(1), 336–346.

    Article  Google Scholar 

  • Zhang, N., Cao, J., Liu, S., Zhao, Z., Xu, H., & Xiao, S. (2014). Chemical composition and sources of PM2.5 and TSP collected at Qinghai Lake during summertime. Atmospheric Research, 138, 213–222.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the National Science Council of the ROC (Taiwan) for financial support under Project No. NSC 103-2221-E-241-004-MY3.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guor-Cheng Fang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fang, GC., Kuo, YC., Zhuang, YJ. et al. Study of the ambient air metallic elements Cr, Cu, Zn, Cd and Pb at HAF sampling sites. Environ Geochem Health 39, 879–887 (2017). https://doi.org/10.1007/s10653-016-9858-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10653-016-9858-5

Keywords

Navigation