Abstract
In this work, the CO2 capture performance of polyamidoamine (PAMAM) dendrimer functionalized cellulose nanocrystals (CNCs) of different generations (CNC-G1 ~ G4) was evaluated under dry conditions at 25–45 °C by thermogravimetric analysis. Compared with bare CNCs and CNC-derivatives, including carboxylated CNCs (CNC-COOH) and aminated CNCs (CNC-NH2), the PAMAM dendrimer functionalized CNC-G1 ~ G4 showed higher CO2 capture capacity under different dry conditions, demonstrating the enhanced CO2 capture performance by the PAMAM dendrimer structure on the CNCs. The second generation of PAMAM functionalized CNCs (CNC-G2) exhibited a CO2 capture capacity of 13.31 ± 0.38 mg/g at 25 °C, 9.64 ± 0.60 mg/g at 35 °C, and 9.18 ± 1.27 mg/g at 45 °C, respectively, prevailing among all the samples. Both pseudo-first-order and pseudo-second-order kinetic models were used to fit the adsorption kinetics, while the latter gave better fitting to experimental data. The activation energy obtained from the pseudo-second-order kinetic model was 55.67 kJ/mol for CO2 capture on CNC-G2, indicating an adsorption mechanism of dominant physisorption with slight chemisorption for CO2 capture. The FTIR spectra of CNC-G2 before and after CO2 adsorption–desorption cycle at 45 °C evidenced the formation of ammonium carbamate during CO2 capture, contributing to the high tolerance of CO2 desorption under the subsequent drier conditions (95 °C in N2 gas flow).
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References
Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM (2008) High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science 319:939–943
Biliuta G, Coseri S (2019) Cellulose: a ubiquitous platform for ecofriendly metal nanoparticles preparation. Coord Chem Rev 383:155–173
Cinke M, Li J, Bauschlicher CW Jr, Ricca A, Meyyappan M (2003) CO2 adsorption in single-walled carbon nanotubes. Chem Phys Lett 376:761–766
Dassanayake RS, Gunathilake C, Abidi N, Jaroniec M (2018) Activated carbon derived from chitin aerogels: preparation and CO2 adsorption. Cellulose 25:1911–1920
Dassanayake RS, Gunathilake C, Dassanayake AC, Abidi N, Jaroniec M (2017) Amidoxime-functionalized nanocrystalline cellulose–mesoporous silica composites for carbon dioxide sorption at ambient and elevated temperatures. J Mater Chem A 5:7462–7473
Fadhel B, Hearn M, Chaffee A (2009) CO2 adsorption by PAMAM dendrimers: significant effect of impregnation into SBA-15. Micropor Mesopor Mat 123:140–149
Gebald C, Wurzbacher JA, Tingaut P, Zimmermann T, Steinfeld A (2011) Amine-based nanofibrillated cellulose as adsorbent for CO2 capture from air. Environ Sci Technol 45:9101–9108
Grishkewich N, Mohammed N, Tang J, Tam K (2017) Recent advances in the application of cellulose nanocrystals. Curr Opin Colloid Interface Sci 29:32–45
Gunathilake C, Jaroniec M (2014) Mesoporous organosilica with amidoxime groups for CO2 sorption. ACS Appl Mater Interfaces 6:13069–13078
Gunathilake C, Dassanayake RS, Abidi N, Jaroniec M (2016) Amidoxime-functionalized microcrystalline cellulose–mesoporous silica composites for carbon dioxide sorption at elevated temperatures. J Mater Chem A 4:4808–4819
Harlick PJ, Sayari A (2006) Applications of pore-expanded mesoporous silicas. 3. Triamine silane grafting for enhanced CO2 adsorption. Ind Eng Chem Res 45:3248–3255
Hsu SC, Lu C, Su F, Zeng W, Chen W (2010) Thermodynamics and regeneration studies of CO2 adsorption on multiwalled carbon nanotubes. Chem Eng Sci 65:1354–1361
Jiang F, Hu S, Hsieh Y (2018) Aqueous synthesis of compressible and thermally stable cellulose nanofibril-silica aerogel for CO2 adsorption. ACS Appl Nano Mater 1:6701–6710
Jing Y, Wei L, Wang Y, Yu Y (2014) Synthesis, characterization and CO2 capture of mesoporous SBA-15 adsorbents functionalized with melamine-based and acrylate-based amine derivatives. Micropor Mesopor Mat 183:124–133
Kaushik M, Moores A (2016) Review: nanocelluloses as versatile supports for metal nanoparticles and their applications in catalysis. Green Chem 18:622–637
Leal O, Bolívar C, Ovalles C, García JJ, Espidel Y (1995) Reversible adsorption of carbon dioxide on amine surface-bonded silica gel. Inorg Chim Acta 240:183–189
Li D, Furukawa H, Deng H, Liu C, Yaghi OM, Eisenber DS (2014) Designed amyloid fibers as materials for selective carbon dioxide capture. Proc Natl Acad Sci 111:191–196
Liang Z, Fadhel B, Schneider CJ, Chaffee AL (2008) Stepwise growth of melamine-based dendrimers into mesopores and their CO2 adsorption properties. Micropor Mesopor Mat 111:536–543
Liu S, Zhang Y, Jiang H, Wang X, Zhang T, Yao Y (2018) High CO2 adsorption by amino-modified bio-spherical cellulose nanofibres aerogels. Environ Chem Lett 16:605–614
Mahfoudhi N, Boufi S (2017) Nanocellulose as a novel nanostructured adsorbent for environmental remediation: a review. Cellulose 24:1171–1197
Mohamed MA, Salleh W, Jaafar J, Ismail AF, Mutalib MA, Mohamad AB, Zain M, Awang NA, Hir Z (2017) Physicochemical characterization of cellulose nanocrystals and nanoporous self-assembled CNC membrane derived from Ceiba pentandra. Carbohydr Polym 157:1892–1902
Paulo P, Lopes S, Costa J (2007) Molecular Dynamics simulations of charged dendrimers: low-to-intermediate half-generation PAMAMs. J Phys Chem B 111:10651–10664
Quang DV, Dindi A, Abu-Zahra MR (2017) One-step process using CO2 for the preparation of amino-functionalized mesoporous silica for CO2 capture application. ACS Sustain Chem Eng 5:3170–3178
Rackley SA (2017) Carbon capture and storage. Butterworth-Heinemann, Oxford
Sajid M, Nazal M, Ihsanullah BN, Osman A (2018) Removal of heavy metals and organic pollutants from water using dendritic polymers based adsorbents: a critical review. Sep Purif Technol 191:400–423
Sevilla M, Fuertes AB (2011) Sustainable porous carbons with a superior performance for CO2 capture. Energy Environ Sci 4:1765–1771
Shah KJ, Imae T, Shukla A (2015) Selective capture of CO2 by poly(amidoamine)dendrimer-loaded organoclays. RSC Adv 5:35985–35992
Shah KJ, Imae T (2017) Photoinduced enzymatic conversion of CO2 gas to solar fuel on functionalized cellulose nanofiber films. J Mater Chem A 5:9691–9701
Shojaeiarani J, Bajwa D, Shirzadifar A (2019) A review on cellulose nanocrystals as promising biocompounds for the synthesis of nanocomposite hydrogels. Carbohydr Polym 216:247–259
Sim K, Lee N, Kim J, Cho EB, Gunathilake C, Jaroniec M (2015) CO2 adsorption on amine-functionalized periodic mesoporous benzenesilicas. ACS Appl Mater Interfaces 7:6792–6802
Sun J, Liang C, Tong X, Guo Y, Li W, Zhao C, Zhang J, Lu P (2019) Evaluation of high-temperature CO2 capture performance of cellulose-templated CaO-based pellets. Fuel 239:1046–1054
Steger E, Macovei TA (1963) Untersuchungen zum infrarotspektrum der dl-α-aminobuttersäure. Spectrochim Acta 19:293–300
Teng Y, Liu Z, Xu G, Zhang K (2017) Desorption kinetics and mechanisms of CO2 on amine-based mesoporous silica materials. Energies 10:115
Thomas B, RajJoy MCJ, Moores A, Drisko GI, Sanchez C (2018) Nanocellulose, a versatile green platform: from biosources to materials and their applications. Chem Rev 118:11575–11625
Wang D (2018) A critical review of cellulose-based nanomaterials for water purification in industrial processes. Cellulose 26:687–701
Wang Q, Luo J, Zhong Z, Borgna A (2011) CO2 capture by solid adsorbents and their applications: current status and new trends. Energy Environ Sci 4:42–55
Wang Y, Lu Q (2020) Dendrimer functionalized nanocrystalline cellulose for Cu(II) removal. Cellulose 27:2173–2187
Zhang T, Zhang Y, Jiang H, Wang X (2019) Aminosilane-grafted spherical cellulose nanocrystal aerogel with high CO2 adsorption capacity. Environ Sci Pollut Res 26:16716–16726
Funding
The authors acknowledge the Discovery Grant from the Natural Sciences and Engineering Research Council of Canada (NSERC), the Start-up Fund from the University of Calgary, the Canada First Research Excellence Fund (CFREF) for its Global Research Initiative in Sustainable Low Carbon Unconventional Resources, and Canada Foundation of Innovation (CFI) for the support of the work.
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Wang, Y., He, X. & Lu, Q. Polyamidoamine dendrimer functionalized cellulose nanocrystals for CO2 capture. Cellulose 28, 4241–4251 (2021). https://doi.org/10.1007/s10570-021-03787-w
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DOI: https://doi.org/10.1007/s10570-021-03787-w