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Palladium Nanoparticles Anchored on Thiol Functionalized Xylose Hydrochar Microspheres: An Efficient Heterogeneous Catalyst for Suzuki Cross-Coupling Reactions

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Abstract

Novel thiol functionalized xylose hydrochar microspheres supported palladium nanoparticles (C–SH–Pd) were synthesized by gentle heating of palladium (II) acetate and thiol functionalized xylose hydrochar (C–SH) in ethanol. The as-prepared C–SH–Pd exhibited high catalytic activity towards Suzuki reactions with a yield of high up to 100%. Moreover, it could be reused for at least five times without heavily loss of the catalytic activity. The amount of palladium entrapped on C-SH microspheres was measured by AAS and found to be 1.42 mmol/g. Leaching studies showed that the filtrate contained less than 0.2 ppm Pd. Due to the superior catalytic performance and stability of the C–SH–Pd catalyst, it can be exploited in other cross coupling reactions in the long run.

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Acknowledgements

We wish to thank for the National Natural Science Foundation of China (3197161, 31430092, 21736003), Guangdong Natural Science Funds for Distinguished Young Scholar (2016A030306027, 2017A030306029), Guangdong Natural Science Funds (2017A030313130), Guangzhou science and technology funds (201904010078), State Key Laboratory of Pulp and Paper Engineering and Fundamental Research Funds for the Central Universities.

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Authors and Affiliations

  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, 381 Wushan Road, Guangzhou, 510640, China

    Pingquan Huang, Xiaoyan Zeng, Fan Du, Lei Zhang & Xinwen Peng

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  1. Pingquan Huang
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  2. Xiaoyan Zeng
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  3. Fan Du
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  4. Lei Zhang
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  5. Xinwen Peng
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Correspondence to Xinwen Peng.

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Huang, P., Zeng, X., Du, F. et al. Palladium Nanoparticles Anchored on Thiol Functionalized Xylose Hydrochar Microspheres: An Efficient Heterogeneous Catalyst for Suzuki Cross-Coupling Reactions. Catal Lett 150, 1011–1019 (2020). https://doi.org/10.1007/s10562-019-02984-4

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