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Synthesis and Heterogenization of Siloxane Functionalized Cobalt Complex: Potential Catalyst for Oxidation of Alcohols

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Abstract

Cobalticinium complex containing siloxane moiety on ligand center was first time synthesized, characterized and heterogenized on the surface of SBA-15 molecular sieves. FT-IR and 29Si-MAS-NMR spectrum evidence the successful grafting of the cobalt complex on the surface of SBA-15. N2 sorption isotherm of cobalticinium complex grafted sample showed the decrease in surface area, pore volume, further confirms the presence of complex inside the channel of mesoporous SBA-15. The heterogenized complex exhibited promising activity for oxidation of alcohols with good selectivity of ketone. Further the catalytic activity remains intact after two recycles.

Graphical Abstract

Cobalticinium complex possessing siloxane functionality was prepared first time and heterogenized on SBA-15 surface. The resultant materials showed as promising recyclable heterogeneous catalyst for oxidation of alcohols.

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Acknowledgments

The authors are thankful to CSIR (Project No: 01(2516)/11/EMR-II), University of Delhi for their financial support and to USIC, University of Delhi, for the support on instrumentation facility. The authors also wish to express their gratitude for the equipment grant by Humboldt Foundation on FT-IR.

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Authors and Affiliations

  1. Department of Chemistry, Inorganic Materials and Catalysis Laboratory, University of Delhi, New Delhi, India

    T. Baskaran, R. Kumaravel & A. Sakthivel

  2. R&D Centre, Indian Oil Corporation Ltd, Faridabad, 121007, India

    J. Christopher

  3. NMR Lab, CSIR-Central Electrochemical Research Institute, Karaikudi, 630 006, India

    S. Radhakrishnan

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  1. T. Baskaran
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  2. R. Kumaravel
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  3. J. Christopher
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  4. S. Radhakrishnan
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  5. A. Sakthivel
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Correspondence to A. Sakthivel.

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Baskaran, T., Kumaravel, R., Christopher, J. et al. Synthesis and Heterogenization of Siloxane Functionalized Cobalt Complex: Potential Catalyst for Oxidation of Alcohols. Catal Lett 145, 851–859 (2015). https://doi.org/10.1007/s10562-015-1492-9

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  • DOI: https://doi.org/10.1007/s10562-015-1492-9

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