Abstract
This study aimed to remove phenolic and lignin compounds from paper mill industry (4500 m3/h) wastewaters, which is discharged to sea from a plant located in the western Turkey. As adsorbent, fly ash, raw sepiolite and heat-activated sepiolite were used. The effect of factors such as, particle size, temperature and pH on adsorption process was investigated. From kinetic studies, equilibrium time was found as 1 h for both. The kinetic data supports pseudo-second order model but shows very poor fit for pseudo-first order model. Intraparticle model also shows that there are two separate stages in sorption process, namely, external diffusion and pore diffusion. Adsorption isotherms for fly ash and activated sepiolite were obtained at two different temperatures. From experiments carried out at different pHs, it was observed that pH plays an important role in the adsorption process in removing of both lignin and phenolic compounds, providing both ionizating the compounds and modifying sorbent surfaces. It was also observed that heat-activated sepiolite is more effective than raw sepiolite and fly ash to remove these compounds. Adsorption of lignin and phenolic compounds increases with decreasing particle size. In addition, the efficiency of adsorption decreases with increasing adsorption temperature for both fly ash and untreated sepiolite.
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Al-Asheh, S., F. Banat, and L.A. Aitah, “Adsorption of Phenol Using Different Types of Activated Bentonites,” Separation and Purification Technology, 33, 1–10 (2003).
Ali, M. and T.R. Sreekrishnan, “Aquatic Toxicity from Pulp and Paper Mill Effluents: A Review,” Advances in Environmental Research, 5, 175–196 (2001).
APHA, AWWA, WPCF, Standard Methods for the Examination of Water and Wastewater for Lignin and Phenol, 15th Ed., USA, vol. 5, pp. 54–67 (1980).
Bailey, S.E., J.T. Olin, R.M. Bricka, and D.D. Adrian, “A Review of Potentially Low-Cost Sorbents for Heavy Metals,” WaterResearch, 33(1), 2469–2479 (1999).
Bajpai, P. and P.K. Bajpai, “Mini Review: Biological Color Removal of Pulp and Paper Mill Wastewaters,” J. Biotechnol, 33, 211–220 (1994).
Balci, S. and Y. Dinçel, “Ammonium Ion Adsorption with Sepiolite: Use of Transient Uptake Method,” Chem. Eng. Process, 4179–4185 (2002).
Banerjee, K., P.N. Cheremisinoff, and S.L. Cheng, “Adsorption Kinetics of O-Xylene by Fly Ash,” Water Research, 31(2), 249–261 (1997).
Basibuyuk, M. and C.F. Forster, “An Examination of the Adsorption Characteristics of a Basic Dye (Maxilon Red BL-N) on to Live Activated Sludge System,” Process Biochemistry, 38 (9), 1–6 (2003).
Brauner, K. and A. Preisenger, “Structur und Entstehung Des Sepioliths,” Tschermaks Miner Petrogr Min, 6, 40–120 (1956).
Bruce, W., M.E. Meek, and A. Newhook, “Phenol: Hazard Characterization and Exposure-Response Analysis,” Environ. Carcino. & Ecotox. Revs, C19(1), 305–324 (2001).
Carlberg, G.E. and T.R., Stuthridge, “Environmental Fate and Distribution of Substances,” Lucie Press ccc, 169–177 (1996).
Chiou, M.S. and H.Y. Li, “Adsorption Behavior of Reactive Dye in Aqueous Solution on Chemical Cross-Linked Chitosan Beads,” Chemosphere, 50, 1095–1105 (2003).
Diez, M.C., M.L. Mora, and S. Videala, “Adsorption of Phenolic Compounds and Colour from Bleached Kraft Mill Effluent Using Allophonic Compounds” Water Research, 33(1), 125–130 (1999).
Gündoğan, R., B. Acemioğlu, and MH. Alma, “Copper (II) Adsorption from Aqueous Solution by Herbaceous Peat,” Journal of Colloid and Interface Science, 269(2), 303–309, (2004).
Gürses, A., S., Karaca, Ç., Doğar, R., Bayrak, M., Açıkyıldız, and M. Yalçın, “Determination of Adsorptive Properties of Clay/Water System,” Journal of Colloid and Interface Science, 269, 310–314 (2004).
Ho, Y.S. and C.C. Chiang, “Sorption Studies of Acid Dye by Mixed Sorbents,” Adsorption, 7, 139–147 (2001).
Ho, Y.S. and G. McKay, “Sorption of Dye from Aqueous Solution by Peat,” Chemical Eng Journal, 70, 115–124 (1998a).
Ho, Y.S. and G. McKay, “The Kinetics of Sorption of Basic Dyes from Aqueous Solution by Sphagnum Moss Peat,” Canadian Journal of Chemical Engineering, 76(4), 822–827 (1998b).
Ho, Y.S. and G. McKay, “Kinetic Model for Lead (II) Sorption on to Peat,” Adsorption Science & Technology, 16(4), 243–255 (1998c).
Ho, Y.S. and G. McKay, “The Sorption of Lead (II) Ions on Peat,” Water Research, 33, 578–584 (1999).
Ho, Y.S. and G. McKay, “The Kinetics of Sorption of Divalent Metal Ions onto Sphagnum Moss Flat,” Water Research, 34(3), 735–742 (2000).
Ho, Y.S. “Removal of Copper Ions from Aqueous Solution by Tree Fern,” Water Research, 37, 2323–2330 (2003).
Ho, Y.S. and G. McKay, “Kinetic Models for the Sorption of Dye from Aqueous Solution by Wood,” Process Saf. Environ. Protect, 76B, 183–191 (1998d).
Jain, C.K. and M.K. Sharma, “Adsorption of Cadmium on Bed Sediments of River Hindon: Adsorption Models and Kinetics,” Water Air and Soil Pollution, 137, 1–19 (2002).
Kao, P.C., J.H. Tzeng, and T.L. Huang, “Removal of Chlorophenols from Aqueous Solution by Fly Ash,” Journal Hazardous Material, 76(2–39), 237–249 (2000).
Lagergren, S., “Zur Theorie der Sogenannten Adsorption gelöster Stoffe. Kungliga Svenska Vetenskapsakademiens,” Handlingar, Band, 24(4), 1–39 (1898).
Mohan, S.V. and J., Karthikeyan, “Removal of Lignin and Tannin Colour from Aqueous Solution by Adsorption onto Activated Charcoal,” Environmental Pollution, 97(1–2), 183–187 (1997).
Montgomery J.M., Consulting Engineers Water Treatment Principles and Design, Wiley Interscience, New York, NY (1985).
Mott, H.V. and W.J. Weber, “Sorption of Low Molecular Weight Organic Contaminants by Flyash: Consideration of Enhancement of Cut-Off Barrier Performance,” Environmental Science & Technology, 26(6), 1234–1242 (1992).
Naseem, R. and S.S. Tahir, “Removal of Pb (II) From Aqueous/Acidic Solutions by Using Bentonite as an Adsorbent,” Water Research, 35(16), 3982–3986, (2001).
Rodriguez, I., M.P. Llompart, and R. Cela, “Solid-Phase Extraction of Phenols,” Journal of Chromatography, 885, 291–304 (2000).
Rytwo, G., D. Trop, and C. Serban, “Adsorption of Diquat, Paraquat and Methyl Green on Sepiolite: Experimental Results and Model Calculations,” Applied Clay Science, 20, 273–282 (2002).
Sabah E., M. Turan, and M.S. Celik, “Adsorption Mechanism of Cationic Surfactants onto Acid-and Heat-Activated Sepiolites,” Water Research, 36, 3957–3964 (2002).
Sivaraj, R., C. Namasivayam, and K. Kadirvelu, “Orange Peel as an Adsorbent in the Removal of Acid Violet 17(Acid Dye) from Aqueous Solutions,” Waste Management, 21, 105–110 (2001).
Sun, Q. and L. Yang, “The Adsorption of Basic Dyes from Aqueous Solution on Modified Peat-Resin Particle,”Water Research, 37, 1535–1544 (2003).
Tseng R.L., F.C. Wu, and R.S. Juang, “Liquid-Phase Adsorption of Dyes and Phenols Using Pinewood-Based Activated Carbons, Carbon, 41, 487–495 (2003).
US EPA. Federal Register. vol. 52, pp. 25861–25962, Washington, D.C, USA, (1987).
Viraghavan, T. and F.M. Alfaro, “Adsorption of Phenol from Wastewater by Peat, Fly Ash and Bentonite,” Journal of Hazardous Materials, 57, 59–70 (1998).
Weber, W.J. and Morris, J.C. “Kinetics of Adsorption on Carbon from Solution,” J Sanit Eng Div Am Soc Civ Eng, 89, pp. 31–60 (1963).
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Ugurlu, M., Gurses, A., Yalcin, M. et al. Removal of Phenolic and Lignin Compounds from Bleached Kraft Mill Effluent by Fly Ash and Sepiolite. Adsorption 11, 87–97 (2005). https://doi.org/10.1007/s10450-005-1096-6
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DOI: https://doi.org/10.1007/s10450-005-1096-6