Abstract
Gold and silver nanoparticles have unique optical properties. For instance, the intense colour of nanoparticle suspensions results from the excitation of a collective oscillation of surface conduction electrons, named surface plasmons. This excitation is done using an electromagnetic radiation that interacts with nanoparticles having a negative real and small positive imaginary dielectric constant, such as nanoparticles of gold or silver. The plasmonic optical properties of metal nanostructures are dependent on their shape and size, the dielectric properties of the metal and the surroundings and on the possible electromagnetic coupling with the localized surface plasmons in nearby other plasmonic objects. The other important consequence of the excitation of surface plasmons is a local significant enhancement of the electromagnetic field at some places of the illuminated nanoparticles. Specific plasmonic properties of gold and silver nanoparticles have allowed the development of many sensors for chemical analysis, including sensors dedicated for environmental analysis. Some of these sensors are so sensitive that recording of the reliable analytical signal of a single molecule is possible. Here, we review analytical techniques based on plasmonic properties of metallic nanoparticles for environmental analysis. We present the theory and mechanism of interaction of the electromagnetic radiation with the plasmonic nanoparticles. We detail analytical techniques including methods utilizing local enhancement of the intensity of the electromagnetic field induced by plasmons, and hence increase in the efficiency of some optical processes in the proximity of the plasmonic nanoparticles. Those techniques are surface-enhanced Raman scattering, surface-enhanced infrared absorption and metal-enhanced fluorescence and methods based on the change in the optical properties of plasmonic nanoparticles caused by the analyte-induced aggregation or by analyte-influenced growth or etching of plasmonic nanostructures. Environmental compounds include heavy metal cations, metallo-organic compounds, polycyclic aromatic hydrocarbons, pesticides, nitrite ions, bacterial cells and bacterial pathogens.
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References
Albrecht MG, Creighton JA (1974) Anomalously intense Raman spectra of pyridine at a silver electrode. J Am Chem Soc 99:5215–5217. https://doi.org/10.1021/ja00457a071
Anderson MS (2000) Locally enhanced Raman spectroscopy with an atomic force microscope. Appl Phys Lett 76:3130–3132. https://doi.org/10.1063/1.126546
Aroca RF, Ross DJ (2004) Surface-enhanced infrared spectroscopy. Appl Spectrosc 58:324–338. https://doi.org/10.1366/0003702042475420
Bastys V, Pastoriza-Santos I, Rodríguez-González B, Vaisnoras R, Liz-Marzán LM (2006) Formation of silver nanoprisms with surface plasmons at communication wavelengths. Adv Funct Mater 16:766–773. https://doi.org/10.1002/adfm.200500667
Bjerke AE, Griffiths PR (1999) Surface-enhanced infrared absorption of CO on platinized platinum. Anal Chem 71:1967–1974. https://doi.org/10.1021/ac981093u
Bjerke AE, Griffiths PR (2002) Surface-enhanced infrared absorption spectroscopy of p-nitrothiophenol on vapor-deposited platinum films. Appl Spectrosc 56:1275–1280. https://doi.org/10.1366/000370202760355226
Bondre N, Zhang Y, Geddes CD (2011) Metal-enhanced fluorescence based calcium detection: greater than 100-fold increase in signal/noise using fluo-3 or fluo-4 and silver nanostructures. Sens Actuator B Chem 152:82–87. https://doi.org/10.1016/j.snb.2010.09.041
Carrasco EA, Campos-Vallette M, Leyton P, Diaz G, Clavijo RE, Garcia-Ramos JV, Inostroza N, Domingo C, Sanchez-Cortes S, Koch R (2003) Study of the interaction of pollutant nitro polycyclic aromatic hydrocarbons with different metallic surfaces by surface-enhanced vibrational spectroscopy (SERS and SEIR). J Phys Chem A 107:9611–9619. https://doi.org/10.1021/jp035242a
Carrasco-Flores EA, Clavijo RE, Campos-Vallette MM, Aroca RF (2004) Vibrational spectra and surface-enhanced vibrational spectra of 1-nitropyrene. Appl Spectrosc 58:555–561. https://doi.org/10.1366/000370204774103381
Cheng ZH, Li G, Liu MM (2015) Metal-enhanced fluorescence effect of Ag and Au nanoparticles modified with rhodamine derivative in detecting Hg2+. Sens Actuator B Chem 212:495–504. https://doi.org/10.1016/j.snb.2015.02.050
Daniel WL, Han MS, Lee J-S, Mirkin ChA (2009) Colorimetric nitrite and nitrate detection with gold nanoparticle probes and kinetic end points. J Am Chem Soc 131:6362–6363. https://doi.org/10.1021/ja901609k
Dasary SSR, Rai US, Yu H, Anjaneyulu Y, Dubey M, Ray PC (2008) Gold nanoparticle based surface enhanced fluorescence for detection of organophosphorus agents. Chem Phys Lett 460:187–190. https://doi.org/10.1016/j.cplett.2008.05.082
Dong K, Zhou J, Yang T, Dai S, Tan H, Chen Y, Pan H, Chen J, Audit B, Zhang S, Xu J (2018) Sensitive Hg2+ ion detection using metal enhanced fluorescence of novel polyvinyl pyrrolidone (PVP)-templated gold nanoparticles. Appl Spectrosc 72:1645–1652. https://doi.org/10.1177/0003702818775704
Enders D, Pucci A (2006) Surface enhanced infrared absorption of octadecanethiol on wet-chemically prepared Au nanoparticle films. Appl Phys Lett 88:1–4. https://doi.org/10.1063/1.2201880
Fallah MA, Stanglmair Ch, Pacholski C, Hauser K (2016) Devising self-assembled-monolayers for surface-enhanced infrared spectroscopy of pH-driven poly-l-lysine conformational changes. Langmuir 32:7356–7364. https://doi.org/10.1021/acs.langmuir.6b01742
Fleischmann M, Hendra PJ, McQuillan AJ (1974) Raman spectra of pyridine adsorbed at a silver electrode. Chem Phys Lett 26:163–166. https://doi.org/10.1016/0009-2614(74)85388-1
Gao J, Guo L, Wu J, Feng J, Wang S, Lai F, Xie J, Tian Z (2014) Simple and sensitive detection of cyanide using pinhole shell-isolated nanoparticleenhanced Raman spectroscopy. J Raman Spectrosc 45:619–626. https://doi.org/10.1002/jrs.4497
Geddes CD (2013) Metal-enhanced fluorescence. Phys Chem Chem Phys 15:19537. https://doi.org/10.1039/c3cp90129g
Geddes CD, Lakowicz JR (2002) Metal-enhanced fluorescence. J Fluoresc 12:121–129. https://doi.org/10.1023/A:1016875709579
Guo Y, Zhang Y, Shao H, Wang Z, Wang X, Jiang X (2014) Label-free colorimetric detection of cadmium ions in rice samples using gold nanoparticles. Anal Chem 86:8530–8534. https://doi.org/10.1021/ac502461r
Guzman MG, Dille J, Godet S (2009) Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity. Int J Chem Biomol Eng 2:104–111. https://doi.org/10.1080/17458080.2016.1139196
Hahn F, Melendres CA (2001) Anodic oxidation of methane at noble metal electrodes: an ‘in situ’ surface enhanced infrared spectroelectrochemical study. Electrochim Acta 46:3525–3534. https://doi.org/10.1016/S0013-4686(01)00649-1
Hambly AC, Arvin E, Pedersen LF, Pedersen PB, Seredynska-Sobecka B, Stedmon CA (2015) Characterising organic matter in recirculating aquaculture systems with fluorescence EEM spectroscopy. Water Res 83:112–120. https://doi.org/10.1016/j.watres.2015.06.037
Hao E, Schatz GC (2004) Electromagnetic fields around silver nanoparticles and dimers. J Chem Phys 120:357–366. https://doi.org/10.1063/1.1629280
Hartstein A, Kirtley JR, Tsang JC (1980) Enhancement of the infrared absorption from molecular monolayers with thin metal overlayers. Phys Rev Lett 45:3–21. https://doi.org/10.1103/PhysRevLett.45.201
Hea L, Chena T, Labuza TP (2014) Recovery and quantitative detection of thiabendazole on apples using a surface swab capture method followed by surface-enhanced Raman spectroscopy. Food Chem 148:42–46. https://doi.org/10.1016/j.foodchem.2013.10.023
Hu H, Jin Q, Kavan P (2014) A study of heavy metal pollution in China: current status, pollution-control policies and countermeasures. Sustainability 6:5820–5838. https://doi.org/10.3390/su6095820
Huang K-W, Yu Ch-J, Tseng W-L (2010) Sensitivity enhancement in the colorimetric detection of lead(II) ion using gallic acid–capped gold nanoparticles: improving size distribution and minimizing interparticle repulsion. Biosens Bioelectron 25:984–989. https://doi.org/10.1016/j.bios.2009.09.006
Jacobson MZ (2008) Review of solutions to global warming, air pollution, and energy security. Energy Environ Sci 2:148–173. https://doi.org/10.1039/b809990c
Jeanmaire DL, Van Duyne RP (1977) Surface Raman spectroelectrochemistry part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. J Electroanal Chem 84:1–20. https://doi.org/10.1016/S0022-0728(77)80224-6
Jensen TR, Van Dyune RP, Johnson SA, Maroni VA (2000) Surface-enhanced infrared spectroscopy: a comparison of metal island films with discrete and nondiscrete surface plasmons. Appl Spectrosc 54:371–377. https://doi.org/10.1366/0003702001949654
Jin T, Zhang Y, Li Y, Jing W, Li Y, Fan L, Li X (2019) Ag@SiO2 nanoparticles performing as a nanoprobe for selective analysis of 2-aminoanthracene in wastewater samples via metal-enhanced fluorescence. Talanta 200:242–248. https://doi.org/10.1016/j.talanta.2019.03.054
Johnson E, Aroca R (1995) Surface-enhanced infrared spectroscopy of monolayers. J Phys Chem 99:9325–9330. https://doi.org/10.1021/j100023a004
Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J Phys Chem B 107:668–677. https://doi.org/10.1021/jp026731y
Kim Y, Johnson RC, Hupp JT (2001) Gold nanoparticle-based sensing of “spectroscopically silent” heavy metal ions. Nano Lett 1:165–167. https://doi.org/10.1021/nl0100116
Kim M, Kwon JE, Lee K, Koh WG (2018) Signal-amplifying nanoparticle/hydrogel hybrid microarray biosensor for metal-enhanced fluorescence detection of organophosphorus compounds. Biofabrication. 10:035002-1–035002-13. https://doi.org/10.1088/1758-5090/aab004
Kokaislova A, Parchansky V, Matejka P (2015) Surface-enhanced infrared spectra of nicotinic acid and pyridoxine on copper substrates: what is the effect of temperature on deposition conditions? J Phys Chem C 119:26526–26539. https://doi.org/10.1021/acs.jpcc.5b08206
Kołątaj K, Krajczewski J, Kudelski A (2018) Nanosensors for environmental analysis based on plasmonic nanoparticles. In: Dasgupta N, Ranjan S, Lichtfouse E (eds) Environmental nanotechnology. Springer, Basel, pp 255–287
Lenhardt L, Bro R, Zekovic I, Dramicanin T, Dramicanin MD (2015) Fluorescence spectroscopy coupled with PARAFAC and PLS DA for characterization and classification of honey. Food Chem 175:284–291. https://doi.org/10.1016/j.foodchem.2014.11.162
Li J, Chen L, Lou T, Wang Y (2011a) Highly sensitive SERS detection of As3+ ions in aqueous media using glutathione functionalized silver nanoparticles. ACS Appl Mater Interfaces 3:3936–3941. https://doi.org/10.1021/am200810x
Li Y, Cui Z, Li D, Li H (2011b) Colorimetric determination of pyrethroids based on core-shell Ag@SiO2 nanoparticles. Sens Actuators B Chem 155:878–883. https://doi.org/10.1016/j.snb.2011.01.064
Li F, Wang J, Lai Y, Wu Ch, Sun S, He Y, Ma H (2013) Ultrasensitive and selective detection of copper(II) and mercury(II) ions by dye-coded silver nanoparticle-based SERS probes. Biosens Bioelectron 39:82–87. https://doi.org/10.1016/j.bios.2012.06.050
Li Y, Sun J, Wu L, Ji J, Sun X, Qian Y (2014) Surface-enhanced fluorescence immunosensor using Au nano-crosses for the detection of microcystin-LR. Biosens Bioelectron 62:255–260. https://doi.org/10.1016/j.bios.2014.06.064
Li Q, Wang J, He Y (2016) Selective chemiluminescent sensor for detection of mercury(II) ions using non-aggregated luminol-capped gold nanoparticles. Sens Actuator B Chem 231:64–69. https://doi.org/10.1016/j.snb.2016.03.007
Li L, Zhang L, Lou T, Chen Z (2017) Iodide-responsive Cu@Au nanoparticle-based colorimetric assay for sensitive mercury (II) detection. Sens Actuators B Chem 252:663–670. https://doi.org/10.1016/j.snb.2017.06.054
Liang L, Lan F, Ge S, Yu J, Ren N, Yan M (2017) Metal-enhanced ratiometric fluorescence/naked eye bimodal biosensor for lead ions analysis with bifunctional nanocomposite probes. Anal Chem 89:3597–3605. https://doi.org/10.1021/acs.analchem.6b04978
Liu ChW, Tsai TCh, Osawa M, Chang HCh, Yang RJ (2018) Aptamer-based sensor for quantitative detection of mercury (II) ions by attenuated total reflection surface enhanced infrared absorption spectroscopy. Anal Chim Acta 1033:137–147. https://doi.org/10.1016/j.aca.2018.05.037
Liz-Marzan LM (2004) Nanometals: formation and color. Mater Today 7:26–31. https://doi.org/10.1016/S1369-7021(04)00080-X
Ma YW, Wu ZW, Zhang LH, Zhang J (2010) Theoretical studies of optical properties of silver nanoparticles. Chin Phys Lett 27:1–4. https://doi.org/10.1088/0256-307X/27/2/024207
Ma W, Sun M, Xu L, Wang L, Kuang H, Xu Ch (2013) A SERS active gold nanostar dimer for mercury ion detection. Chem Commun 49:4989–4991. https://doi.org/10.1039/c3cc39087j
Maiman TH (1960) Stimulated optical radiation in ruby. Nature 187:493–494. https://doi.org/10.1038/187493a0
Makam P, Shilpa R, Kandjani AE, Periasamy SR, Sabri YM, Madhu Ch, Bhargava SK, Govindaraju T (2018) SERS and fluorescence-based ultrasensitive detection of mercury in water. Biosens Bioelectron 100:556–564. https://doi.org/10.1016/j.bios.2017.09.051
Miao LJ, Xin JW, Shen ZY, Zhang YJ, Wang HY, Wu AG (2013) Exploring a new rapid colorimetric detection method of Cu2+ with high sensitivity and selectivity. Sens Actuators B 176:906–912. https://doi.org/10.1021/acs.analchem.6b04978
Orrit M, Bernard J (1990) Single pentacene molecules detected by fluorescence excitation in a p-terphenyl crystal. Phys Rev Lett 65:2716–2719. https://doi.org/10.1103/PhysRevLett.65.2716
Osawa M (2001) Surface-enhanced infrared absorption. Topics Appl Phys 81:163–187. https://doi.org/10.1007/3-540-44552-8_9
Pang Y, Rang Z, Xiao R, Wang S (2015) ‘‘Turn on’’ and label-free core-shell Ag@SiO2 nanoparticles-based metal-enhanced fluorescent (MEF) aptasensor for Hg2+. Sci Rep 5:9451. https://doi.org/10.1038/srep09451
Pastoriza-Santos I, Liz-Marzán LM (2008) Colloidal silver nanoplates. State of the art and future challenges. J Mater Chem 18:1724–1737. https://doi.org/10.1039/b716538b
Peron O, Rinnert E, Toury T, Lamy de la Chapelle M, Compere C (2011) Quantitative SERS sensors for environmental analysis of naphthalene. Analyst 136:1018–1022. https://doi.org/10.1039/C0AN00797H
Priyadarshini E, Pradhan N (2017) Metal-induced aggregation of valine capped gold nanoparticles: an efficient and rapid approach for colorimetric detection of Pb2+ ions. Sci Rep 7:9278-1–9278-8. https://doi.org/10.1038/s41598-017-08847-5
Raman CV, Krishnan KS (1928) A new type of secondary radiation. Nature 121:501–502. https://doi.org/10.1038/121501c0
Samanta SK, Singh OV, Jain RK (2002) Polycyclic aromatic hydrocarbons: environmental pollution and bioremediation. Trends Biotechnol 20:243–248. https://doi.org/10.1016/S0167-7799(02)01943-1
Sanchez-Cortes S, Domingo C, Garcıa-Ramos JV, Aznarez JA (2001) Surface-enhanced vibrational study (SEIR and SERS) of dithiocarbamate pesticides on gold films. Langmuir 17:1157–1162. https://doi.org/10.1021/la001269z
Sánchez-Cortés S, Guerrini L, García Ramos JV, Domingo C (2007) Functionalization of metal nanoparticles with synthetic and natural hosts for the surface-enhanced spectroscopic detection of polycyclic aromatic hydrocarbons. Opt Pura Apl 40:235–242
Sevick-Muraca EM, Houston JP, Gurfinkel M (2002) Fluorescence-enhanced, near infrared diagnostic imaging with contrast agents. Curr Opin Chem Biol 6:642–650. https://doi.org/10.1016/S1367-5931(02)00356-3
Sharma P, Kukkar M, Ganguli AK, Bhasin A, Suri CR (2013) Plasmon enhanced fluoro-immunoassay using egg yolk antibodies for ultra-sensitive detection of herbicide diuron. Analyst 138:4312–4320. https://doi.org/10.1039/c3an00505d
Singh R, Gautam N, Mishra A, Gupta R (2011) Heavy metals and living systems: an overview. Indian J Pharmacol 43:246–253. https://doi.org/10.4103/0253-7613.81505
Song L, Mao K, Zhou X, Hu J (2016) A novel biosensor based on Au@Ag core-shell nanoparticles for SERS detection of arsenic(III). Talanta 146:285–290. https://doi.org/10.1016/j.talanta.2015.08.052
Song C, Yang B, Zhu Y, Yang Y, Wang L (2017) Ultrasensitive sliver nanorods array SERS sensor for mercury ions. Biosens Bioelectron 87:59–65. https://doi.org/10.1016/j.bios.2016.07.097
Stam J, Lindqvist C, Hansson R, Ericsson L, Moons E (2015) Fluorescence and UV/VIS absorption spectroscopy studies on polymer blend films for photovoltaics. Proc SPIE. https://doi.org/10.1117/12.2188618
Stamplecoskie KG, Scaiano JC (2012) Silver as an example of the applications of photochemistry to the synthesis and uses of nanomaterials. J Photochem Photobiol 88:762–768. https://doi.org/10.1111/j.1751-1097.2012.01103.x
Stockle RM, Suh YD, Deckert V, Zenobi R (2000) Nanoscale chemical analysis by tip-enhanced Raman spectroscopy. Chem Phys Lett 318:131–136. https://doi.org/10.1016/S0009-2614(99)01451-7
Sui N, Wang L, Yan T, Liu F, Sui J, Jiang Y, Wan J, Liu M, Yu WW (2014) Selective and sensitive biosensors based on metal-enhanced fluorescence. Sens Actuator 202:1148–1153. https://doi.org/10.1016/j.snb.2014.05.122
Thatai S, Khurana P, Prasad S, Soni SK, Kumar D (2016) Trace colorimetric detection of Pb2+ using plasmonic gold nanoparticles and silica–gold nanocomposites. Microchem J 124:104–110. https://doi.org/10.1016/j.microc.2015.07.006
Tuteja SK, Kukkar M, Kumar P, Paul AK, Deep A (2014) Synthesis and characterization of silica-coated silver nanoprobe for paraoxon pesticide detection. BioNanoSci 4:149–156. https://doi.org/10.1007/s12668-014-0129-6
Weiss S (1999) Fluorescence spectroscopy of single biomolecules. Science 12:1676–1683. https://doi.org/10.1126/science.283.5408.1676
Willets KA, Van Duyne RP (2007) Localized surface plasmon resonance spectroscopy and sensing. Annu Rev Phys Chem 58:267–297. https://doi.org/10.1146/annurev.physchem.58.032806.104607
Xu Q, Guo X, Xu L, Ying Y, Wu Y, Wen Y, Yang H (2017) Template-free synthesis of SERS-active gold nanopopcorn for rapid detection of chlorpyrifos residues. Sens Actuators B Chem 241:1008–1013. https://doi.org/10.1016/j.snb.2016.11.021
Xue CA, Mirkin ChA (2007) pH-switchable silver nanoprism growth pathways. Angew Chem Int Ed 46:2036–2038. https://doi.org/10.1002/anie.200604637
Yang J-K, Kang H, Lee H, Jo A, Jeong S, Jeon S-J, Kim H-I, Lee H-Y, Jeong DH, Kim J-H, Lee Y-S (2014) Single-step and rapid growth of silver nanoshells as SERS-active nanostructures for label-free detection of pesticides. ACS Appl Mater Interfaces 6:12541–12549. https://doi.org/10.1021/am502435x
Yang X, He Y, Wang X, Yuan R (2017) A SERS biosensor with magnetic substrate CoFe2O4@Ag for sensitive detection of Hg2+. Appl Surf Sci 416:581–586. https://doi.org/10.1016/j.apsusc.2017.04.106
Zamarion VM, Timm RA, Araki K, Toma HE (2008) Ultrasensitive SERS nanoprobes for hazardous metal ions based on trimercaptotriazine-modified gold nanoparticles. Inorg Chem 47:2934–2936. https://doi.org/10.1021/ic800122v
Zhang F, Zhang L, Mao SC, Chen P, Cui JC, Tang YG, Wang K, Lin L, Qi XD (2012) Use of metal-enhanced fluorescence spectroscopy for detection of polycyclic aromatic hydrocarbons in diesel oil emulsions in artificial seawater. Environ Technol 33:2071–2075. https://doi.org/10.1080/09593330.2012.660643
Zhang K, Hu Y, Li G (2013) Diazotization-coupling reaction-based selective determination of nitrite in complex samples using shell-isolated nanoparticle-enhanced Raman spectroscopy. Talanta 116:712–718. https://doi.org/10.1016/j.talanta.2013.07.019
Zhang Y, Wang Z, Wu L, Pei Y, Chen P, Cui Y (2014a) Rapid simultaneous detection of multi-pesticide residues on apple using SERS technique. Analyst 139:5148–5154. https://doi.org/10.1039/c4an00771a
Zhang Z, Zhao C, Ma Y, Li G (2014b) Rapid analysis of trace volatile formaldehyde in aquatic products by derivatization reaction-based surface enhanced Raman spectroscopy. Analyst 139:3614–3621. https://doi.org/10.1039/c4an00200h
Zhao L, Gu W, Zhang C, Shi X, Xian Y (2016) In situ regulation nanoarchitecture of Au nanoparticles/reduced graphene oxide colloid for sensitive and selective SERS detection of lead ions. J Colloid Interface Sci 465:279–285. https://doi.org/10.1016/j.jcis.2015.11.073
Zhao Y, Gui L, Chen Z (2017) Colorimetric detection of Hg2+ based on target-mediated growth of gold nanoparticles. Sens Actuator B Chem 241:262–267. https://doi.org/10.1016/j.snb.2016.10.084
Zhou T, Lin L, Rong M, Jiang Y, Chem X (2013) Silver−gold alloy nanoclusters as a fluorescence-enhanced probe for aluminum ion sensing. Anal Chem 85:9839–9844. https://doi.org/10.1021/ac4023764
Zhou L, Zhang H, Luan Y, Cheng S, Fan LJ (2014) Amplified detection of iron ion based on plasmon enhanced fluorescence and subsequently fluorescence quenching. Nano-Micro Lett 6:327–334. https://doi.org/10.1007/s40820-014-0005-5
Zohora N, Kumar D, Yazdani M, Rotello VM, Ramanathan R, Bansal V (2017) Rapid colorimetric detection of mercury using biosynthesized gold nanoparticles. Colloids Surf 532:451–457. https://doi.org/10.1016/j.colsurfa.2017.04.036
Zrimsek AB, Wong NL, Van Duyne RP (2016) Single molecule surface-enhanced Raman spectroscopy: a critical analysis of the bianalyte versus isotopologue proof. J Phys Chem C 120:5133–5142. https://doi.org/10.1021/acs.jpcc.6b00606
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Kołątaj, K., Krajczewski, J. & Kudelski, A. Plasmonic nanoparticles for environmental analysis. Environ Chem Lett 18, 529–542 (2020). https://doi.org/10.1007/s10311-019-00962-1
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DOI: https://doi.org/10.1007/s10311-019-00962-1