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Pb-Laden CRT glass as classifying hazardous waste definition or exemption in landfill disposal in China

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Abstract

Disposal of waste CRT glass is now an urgent environmental protection issue. We collected waste CRT glass from monochrome and color television sets, analyzed their chemical compositions using X-ray fluorescence, and studied the leaching characteristics of Pb in the glass using sulfuric and nitric acids and acetic acid buffer leaching toxicity tests. The results showed that the order of the Pb leaching levels was color panel glass < monochrome glass < color funnel glass. The average Pb concentrations leached in sulfuric and nitric acids from color funnel and panel glasses and from monochrome funnel and panel glasses did not exceed the regulatory limits for Pb according to the China Identification Standards for Hazardous Waste—Identification for Extraction Toxicity. Only the average concentration of Pb leached in acetic acid buffer from color funnel glass exceeded the regulatory levels for Pb while those from other glasses were lower than 1 mg/L. Monochrome panel and funnel glasses and color panel glass can be disposed off as common industrial solid waste or co-disposed off with municipal solid waste. Color funnel glass, however, should be managed and disposed off in strict conformity with the requirements for hazardous waste disposal.

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References

  1. Poon CS (2008) Management of CRT glass from discarded computer monitors and TV sets. Waste Manage 28(9):1499

    Article  Google Scholar 

  2. Yamashita Masaru, Wannagon Anucha, Matsumoto Sachiko (2010) Leaching behavior of CRT funnel glass. J Hazard Mater 184(1–3):58–64

    Article  Google Scholar 

  3. Stephen E, Musson Jang YC, Timothy G, Townsend TG (2000) Characterization of lead leachability from cathode ray tubes using the toxicity characteristic leaching procedure. Environ Sci Technol 34(20):4376–4381

    Article  Google Scholar 

  4. Ling TC, Poon CS, Kou SC (2011) Feasibility of using recycled glass in architectural cement mortar. Cement Concr Compos 33(8):848–854

    Article  Google Scholar 

  5. Chen M, Zhang FS, Zhu JX (2009) Detoxification of cathode ray tube glass by self-propagating process. J Hazard Mater 165(1–3):980–986

    Article  Google Scholar 

  6. Bernardo E, Albertini F (2006) Glass foams from dismantled cathode ray tubes. Ceram Int 32(6):603–608

    Article  Google Scholar 

  7. Matamoros-Veloza Z, Rendón-Angeles JC, Yanagisawa K (2008) Preparation of foamed glasses from CRT TV glass by means of hydrothermal hot-pressing technique. J Eur Ceram Soc 28(4):739–745

    Article  Google Scholar 

  8. Bernardo E, Scarinci G, Hreglich S (2005) Development and mechanical characterization of Al2O3 platelet-reinforced glass matrix composites obtained from glasses coming from dismantled cathode ray tubes. J Eur Ceram Soc 25(9):1541–1550

    Article  Google Scholar 

  9. Andreola F, Barbieri L, Karamanova E (2008) Recycling of CRT panel glass as fluxing agent in the porcelain stoneware tile production. Ceram Int 34(5):1289–1295

    Article  Google Scholar 

  10. Ling TC, Poon CS (2012) A comparative study on the feasible use of recycled beverage and CRT funnel glass as fine aggregate in cement mortar. J Clean Prod 29–30(1):46–52

    Article  Google Scholar 

  11. Miyoshi H, Chen DP, Akai T (2004) A novel process utilizing subcritical water to remove lead from wasted lead silicate glass. Chem Lett 33(1):956–957

    Article  Google Scholar 

  12. Méar F, Yot P, Cambon M, Ribes M (2006) The characterization of waste cathode-ray tube glass. Waste Manage 26(12):1468–1476

    Article  Google Scholar 

  13. Menad N (1999) Cathode ray tube recycling. Resour Conserv Recycl 26(3–4):143–154

    Article  Google Scholar 

  14. Jang YC, Townsend TG (2003) Leaching of lead from computer printed wire boards and cathode ray tubes by Municipal Solid Waste Landfill Leachates. Environ Sci Technol 37(20):4778–4784

    Article  Google Scholar 

  15. Townsend TG, Musson S, Jang YC, Chung IH (1999) Characterization of lead leachability from cathode ray tubes using the toxicity characteristic leaching procedure. In: Report #99-5, Florida center for solid and hazardous waste management. Gainesville, Florida

  16. State environmental protection administration (2007) Solid waste-extraction procedure for leaching toxicity-sulphuric and nitric acid method (HJ/T299-2007). China environmental science press, China

    Google Scholar 

  17. State environmental protection administration (2007) Solid waste-extraction procedure for leaching toxicity-Acetic acid buffer method (HJ/T300-2007). China environmental science press, China

    Google Scholar 

  18. State environmental protection administration (2007) Identification standards for hazardous wastes-Identification for toxic substance content (GB5085.6-2007). China environmental science press, China

    Google Scholar 

  19. State environmental protection administration (2007) Identification standards for hazardous wastes-Identification for extraction procedure toxicity (GB5085.3-2007). China environmental science press, China

    Google Scholar 

  20. US EPA, EPA Office of Solid Waste (1994) Determination of Ground Water Dilution Attenuation Factors

  21. 40 CFR 261.24-Toxicity Characteristic. http://www.gpo.gov/fdsys/pkg/CFR-2011-title40-vol26/pdf/CFR-2011-title40-vol26-sec261-24.pdf

  22. 40 CFR 261.39(c), Conditional Exclusion for Used, Broken Cathode Ray Tubes (CRTs) and Processed CRT Glass Undergoing Recycling. http://www.epa.gov/wastes/hazard/recycling/electron/

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Acknowledgments

This research was supported by the National Natural Science Foundation of China (51178439).

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Correspondence to Yufei Yang.

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Gao, H., Yang, Y., Huang, Q. et al. Pb-Laden CRT glass as classifying hazardous waste definition or exemption in landfill disposal in China. J Mater Cycles Waste Manag 19, 241–246 (2017). https://doi.org/10.1007/s10163-015-0411-x

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  • DOI: https://doi.org/10.1007/s10163-015-0411-x

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