Abstract
A 3D metal-organic framework, [C6H3CdN2O4]·NH4, was synthesized solvothermally and structurally characterized by single-crystal X-ray structure determination. This compound crystallizes in the tetragonal system with the space group P42/nmc. The crystal structure presents a 3D framework and open channels, exhibiting guest-coordination sites at channel walls and strong fluorescent emission.
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Acknowledgments
We are grateful to the Starting Fund for the Doctoral Program of Xi’an University of Architecture and Technology (RC0737) for financial support.
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Dang, F., Wang, X., Han, G. et al. The 3D porous metal-organic framework constructed by Cd(II) with 2-methylimidazole-4,5-dicarboxylic acid. Monatsh Chem 140, 615–617 (2009). https://doi.org/10.1007/s00706-008-0102-6
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DOI: https://doi.org/10.1007/s00706-008-0102-6