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Chemistry of chromium bis-acetylide complexes

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Abstract

Stable paramagnetic Cr(II) and Cr(III) bis(alkynyl) complexes of the type [trans(RC≡C)2Cr(dmpe)2]n+ (R = Ph, SiMe3, SiEt3, C≡C–SiMe3 n = 0, 1) were prepared and characterised by NMR, cyclic voltammetry, EPR, magnetic measurements, and X-ray single-crystal diffraction studies.

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Acknowledgments

Funding from the Swiss National Science Foundation (SNSF) and from the University of Zürich is gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, 8057, Zürich, Switzerland

    A. López-Hernández, K. Venkatesan, H. W. Schmalle & Heinz Berke

Authors
  1. A. López-Hernández
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  2. K. Venkatesan
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  3. H. W. Schmalle
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  4. Heinz Berke
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Corresponding author

Correspondence to Heinz Berke.

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López-Hernández, A., Venkatesan, K., Schmalle, H.W. et al. Chemistry of chromium bis-acetylide complexes. Monatsh Chem 140, 845–857 (2009). https://doi.org/10.1007/s00706-008-0094-2

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  • DOI: https://doi.org/10.1007/s00706-008-0094-2

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