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Determination of nereistoxin-related insecticide via quantum-dots-doped covalent organic frameworks in a molecularly imprinted network

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Abstract

Quantum-dots-doped covalent organic frameworks in a molecularly imprinted network (QDs-doped COFs@MIP) were developed for detection of nereistoxin (NRT)-related insecticide in tap water. The preparation of QDs-doped COFs@MIP was easy to accomplish via one-pot synthesis at room temperature. QDs-doped COFs@MIP quenched by targeting thiosultap due to the photoinduced charge transfer. A Brunauer–Emmett–Teller surface area of 186.20 m2 g−1 and a maximum adsorption capacity of 771 mg g−1 of the QDs-doped COFs@MIP exhibited good selectivity and adsorption capacity. Direct fluorescence determination was established over the range 5–100 μg L−1 (R2 = 0.9959) with a detection limit of 1.60 μg L−1. Furthermore, 86.5–106.5% recoveries of spiked tap water were achieved. The determination system was feasible for tracing the NRT-related insecticide with high accuracy and good repeatability and reproducibility.

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Acknowledgments

This work was supported by the National Key R&D Program of China (No. 2018YFC1602300), the National Natural Science Foundation of China (No. 31822040), the Young Top-Notch Talent of High-Level Innovation and Entrepreneurs Support Program (No. 2017000026833ZK28), and School Level Cultivation Fund of Beijing Technology and Business University for Distinguished and Excellent Young Scholars (BTBUYP2020).

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  1. Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Engineering and Technology Research Center of Food Additives, Beijing Technology and Business University (BTBU), No. 11 Fucheng Road, Beijing, 100048, People’s Republic of China

    Ying Zhang, Xinyue Yuan, Wei Jiang & Huilin Liu

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  1. Ying Zhang
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  2. Xinyue Yuan
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  3. Wei Jiang
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  4. Huilin Liu
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Correspondence to Huilin Liu.

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Zhang, Y., Yuan, X., Jiang, W. et al. Determination of nereistoxin-related insecticide via quantum-dots-doped covalent organic frameworks in a molecularly imprinted network. Microchim Acta 187, 464 (2020). https://doi.org/10.1007/s00604-020-04435-z

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