Abstract
A sensitive and high selective chemiluminescence (CL) method was developed for the determination of lincomycin in acid medium using diperiodatonickelate as a reagent. The mechanism leading to luminescence is discussed by comparing the spectra of fluorescence and CL. Relative CL intensity is linear in the range from 8.0 ng mL−1 to 1.0 µg mL−1, the limit of detection is 2.5 ng mL−1 (3σ), and the relative standard deviation is 4.0% at 0.1 µg mL−1 of lincomycin (n = 7). The method was successfully applied to the determination of lincomycin in injections, human urine, and in serum samples.
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Yang, C., Zhang, Z. & Shi, Z. A novel chemiluminescence reaction system for the determination of lincomycin with diperiodatonickelate(IV). Microchim Acta 168, 293–298 (2010). https://doi.org/10.1007/s00604-010-0293-5
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DOI: https://doi.org/10.1007/s00604-010-0293-5