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Carbonate cements and grains in submarine fan sandstones—the Cergowa Beds (Oligocene, Carpathians of Poland) recorded by cathodoluminescence

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Abstract

The cathodoluminescence (CL) observations with cold cathode, supplemented by reconnaissance scanning electron microscope analyses, bring new data on petrology, provenance and diagenesis of the Oligocene-age Cergowa sandstones from the Outer Carpathians (SE Poland). The sandstones represent a variety of mass gravity flow sediments deposited on a submarine fan, which now forms a lenticular lithosome—a part of the Menilite Beds–Krosno Beds suite important for the hydrocarbons industry. The most common components of the Cergowa sandstones observed under the CL are carbonates—cement and grains that are mainly represented by lithoclasts. Carbonate cement is represented by five generations: brown (Cb), orange (Co), yellow (Cy), zoned (Cz) and black (Ck). Pore-filling Cb and Co calcite cements are interpreted as genetically related to eo- and mesodiagenetic phases. The mesodiagenetic phase is characterised by randomly distributed relatively large monocrystalline-zoned rhombs of dolomite cement (Cz) and ankerite/ferroan dolomite (Ck). The telodiagenetic phase is represented by pore-filling yellow calcite (Cy) that crystallised under the influence of suboxic meteoric waters. Lithoclasts represent six microfacies of carbonate rocks eroded in the source area, i.e. microbreccia, tectonised immature calcarenite/wacke, microsparite, sparite, biomicrosparite/packstone and dolostone. Pronounced indentations of terrigenous sand grains into intraclasts of packstone/biomicrosparite, coupled with commonly present similar packstone-type matrix, suggest that a significant part of matrix resulted from compaction of soft biomicrosparite grains. Terrigenous grains bound by calcite cement are commonly corroded by acidic diagenetic fluids, and partial or even complete replacement of silicates by calcite and clay minerals is illustrated here by feldspar grains. Substantial carbonate cementation has resulted in both the significant hardness and abrasion resistance of the Cergowa sandstones as well giving rise to their very low porosity and permeability.

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References

  • Adams A, MacKenzie W (1998) A colour atlas of carbonate sediments and rocks under the microscope. Manson Publishing, London

    Google Scholar 

  • Boles JR (1978) Active ankerite cementation in the subsurface Eocene of southwest Texas. Contrib Mineral Petrol 68:13–22

    Article  Google Scholar 

  • Buijs GJA, Goldstein R (2012) Sequence architecture and Palaeoclimatie controls on diagenesis related to subaerial exposure icehouse cyclic Pennsylvanian and Permian carbonates. In: Morad S, Ketzer M, de Ros LF (eds) Linking diagenesis to sequence stratigraphy. IAS Special Publication 45. Wiley, Oxford, pp 55–80

  • Cieszkowski M, Ślączka A, Zuchiewicz W (1990) Detailed geological map of Poland 1:50000, Jaśliska sheet. Polish Geological Institute, Warszawa

    Google Scholar 

  • Dirnerová D, Prekopová M, Janocko J (2012) Sedimentary record of the Dukla Basin (Outer Carpathians, Slovakia and Poland) and its implications for basin evolution. Geol Q 56(3):547–560

    Article  Google Scholar 

  • Dziadzio PS, Borys Z, Kuk S, Masłowski E, Probulski J, Pietrusiak M, Górka A, Moryc J, Baszkiewicz A, Karnkowski P, Karnkowski PH, Pietrusiak M (2006) Hydrocarbon resources of the Polish Outer Carpathians—reservoir parameters, trap types, and selected hydrocarbon fields: A Stratigraphic Review. In: Golonka J, Picha FJ (eds) The Carpathians and Their foreland: geology and hydrocarbon resources. Memoir, vol 84. American Association of Petroleum Geologist, Tulsa, pp 259–291

  • Gawthorpe RL (1987) Burial dolomitization and porosity development in a mixed carbonate-clastic sequence: an example from the Bowland Basin, northern England. Sedimentol 34:533–558

    Article  Google Scholar 

  • Górecki W (ed) (2013) Geothermal atlas of the Eastern Carpathians. AGH University of Science and Technology, Kraków, pp 1–791

  • Götze J, Habermann D, Neuser RD, Richter DK (1999) High-resolution cathodoluminescence spectrometric analysis of rare earth elements-activated cathodoluminescence in feldspar minerals. Chem Geol 153:81–91

    Article  Google Scholar 

  • Götze J, Krbetschek MR, Habermann D, Wolf D (2000) High-resolution cathodoluminescence studies of feldspar minerals. In: Pagel M, Barbin V, Blanc P, Ohnenstetter D (eds) Cathodoluminescence in geoscience. Springer, Berlin, pp 245–270

    Chapter  Google Scholar 

  • Hellmann R, Penisson JM, Hervig RL, Thomassin JH, Abrioux MF (2003) An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation. Phys Chem Miner 30:192–197

    Article  Google Scholar 

  • Hendry JP, Wilkinson M, Fallick AE, Haszeldine RS (2000) Ankerite cementation in deeply buried Jurassic sandstone reservoirs of the Central North Sea. J Sediment Res 70(1):227–239

    Article  Google Scholar 

  • Horbury AD, Adams AE (1989) Meteoric phreatic diagenesis in cyclic late Dinantian carbonates, northwest England. Sediment Geol 65:319–344

    Article  Google Scholar 

  • Kotarba MJ, Koltun YV (2006) The origin and habitat of hydrocarbons of the Polish and Ukrainian parts of the Carpathian Province. In: Golonka J, Picha FJ (eds) The Carpathians and their foreland: geology and hydrocarbon resources. Memoir, vol 84. American Association of Petroleum Geologists, Tulsa, pp 395-442

  • Machel HG (2000) Application of cathodoluminescence to carbonate diagenesis. In: Pagel M, Blanc P, Ohnenstetter D (eds) Cathodoluminescence in geoscience. Springer, Berlin, pp 271–301

    Chapter  Google Scholar 

  • Marshall DJ (1988) Cathodoluminescence of geological material. Allen and Unwin, London

    Google Scholar 

  • Miller J (1988) Cathodoluminescence microscopy. In: Tucker M (ed) Techniques in sedimentology. Blackwell Scientific Publications, Oxford, pp 174–190

    Google Scholar 

  • Morad S (ed) (1998) Carbonate cementation in sandstones. Special Publication, vol 26. The International Association of Sedimentologists, Oxford, pp 1–26

  • Mozley PS (1989) Relation between depositional environment and the elemental composition of early diagenetic siderite. Geology 17(8):704–706

    Article  Google Scholar 

  • Pahl JK, Sikorska M (2004) Cathodoluminescence study of carbonate cements in the Upper Cambrian conglomerates from the Wonominta Block, north western New South Wales. Aust J Earth Sci 51:247–259

    Article  Google Scholar 

  • Peszat C (1984) Variations of mineral composition of the Cergowa sandstones in the light of their deposition conditions and diagenetic alterations (in Polish with English abstract). Bull Pol Geol Inst 346(24):207–234

    Google Scholar 

  • Pszonka J (2009) The influence of sedimentation and diagenetic processes on economic significance of the Cergowa sandstones from “Lipowica II-1” deposit. Miner Resour Manag 25(3):333–342

    Google Scholar 

  • Pszonka J, Wendorff M (2014) Cathodoluminescence-revealed diagenesis of carbonates and feldspars in Cergowa sandstones (Oligocene), Outer Carpathians. Miner Resour Manag 30(4):21–36

    Google Scholar 

  • Reed RM, Milliken KL (2003) How to overcome imaging problems associated with carbonate minerals on SEM-based cathodoluminescence systems. J Sediment Res 73(2):328–332

    Article  Google Scholar 

  • Scholle P (1979) A Colour Illustrated Guide To Constituents, Textures, Cements and Porosities of Sandstones and Associated Rocks. Memoir 28, vol 28. American Association of Petroleum Geologists Tulsa

  • Scholle P, Ulmer-Scholle D (2003) A Colour Guide to the Petrography of Carbonate Rocks: Grains, textures, porosity, diagenesis. Memoir 77. American Association of Petroleum Geologists Tulsa

  • Ślączka A (1970) On the possibility of occurrence of bitumen deposits in the western part of the Dukla Unit in the Polish Eastern Carpathians (in Polish with English abstract). Kwartalnik Geologiczny (Geological Quarterly) 14(2):344–349

    Google Scholar 

  • Ślączka A (1971) The Geology of the Dukla Unit, Polish Flysch Carpathians (in Polish with English summary and figure captions), vol 63. Prace Instytutu Geologicznego. Polski Instytut Geologiczny, Warszawa

    Google Scholar 

  • Ślączka A, Unrug R (1976) Trends of textural and structural variation in turbidite sandstones: the Cergowa Sandstone (Oligocene, Outer Carpathians). Ann Soc Geol Pol 46:55–76

    Google Scholar 

  • Ślączka A, Krugłov S, Golonka J, Oszczypko N, Popadyuk I (2006) Geology and Hydrocarbon Resources of the Outer Carpathians, Poland, Slovakia, and Ukraine: General Geology. In: Golonka J, Picha FJ (eds) The Carpathians and their foreland: geology and hydrocarbon resources, vol 84., American Association of Petroleum Geologists Memoir, vol 84American Association of Petroleum Geologist, Tulsa, pp 221–258

    Google Scholar 

  • Taylor TS (1990) The influence of calcite dissolution on reservoir porosity in Miocene sandstones, Picaroon Field, offshore Texas Gulf Coast. J Sediment Res 60:322–334

    Google Scholar 

  • Worden RH, Burley SD (2003) Sandstone diagenesis: the evolution of sand to stone. In: Burley SD, Worden RH (eds) Sandstone diagenesis: recent and ancient. Reprint Series vol 4. International Association of Sedimentologists, pp 3–44

  • Worden RH, Morad S (2009) Quartz cementation in sandstones. Special Publication, vol 29. The International Association of Sedimentologists, Oxford, pp 1–352

Download references

Acknowledgments

The authors wish to acknowledge the help of ‘Ziggy’ Sawłowicz in making the CL equipment of the Jagiellonian University available and Irenka Brunarska who helped with the SEM analyses. We sincerely thank the Editor—Prof. Hans Machel and the reviewers—Prof. Jens Götze and Drs. Thomas Götte and Francis Witkowski for constructive criticisms and valuable suggestions, which greatly contributed to the improvement of an earlier version this paper. The laboratory analytical part of this research was funded by Postgraduate Grant Scheme of the International Association of Sedimentologists (second session 2011) to Joanna Pszonka. Fieldwork was supported by a Statutory Grant No. 11.11.140.175 from AGH University of Science and Technology to Marek Wendorff.

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Pszonka, J., Wendorff, M. Carbonate cements and grains in submarine fan sandstones—the Cergowa Beds (Oligocene, Carpathians of Poland) recorded by cathodoluminescence. Int J Earth Sci (Geol Rundsch) 106, 269–282 (2017). https://doi.org/10.1007/s00531-016-1318-z

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