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Refining the timing of eclogite metamorphism: a geochemical, petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains, Slovenia (Eastern Alps)

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Abstract

High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a 206Pb/238U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.

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References

  • Altherr R, Lugovic B, Meyer HP, Majer V (1995) Early Miocene post-collisional calc-alkaline magmatism along the easternmost segment of the Periadriatic fault system (Slovenia and Croatia). Mineral Petrol 54:225–247

    Article  Google Scholar 

  • Anczkiewicz R, Thirlwall F (2003) Improving precision of Sm-Nd garnet dating by H2SO4 leaching-a simple solution to the phosphate inclusion problem. In: Vance D, Müller W, Villa IM (eds) Geochronology: linking the isotopic record with petrology and textures. J Geol Soc London Spec Publ 220:83–91

    Google Scholar 

  • Becker H (1993) Garnet peridotite and eclogite Sm-Nd mineral ages from the Lepontine dome (Swiss Alps): new evidence for Eocene high-pressure metamorphism in the central Alps. Geology 21:599–602

    Article  Google Scholar 

  • Begemann F (2001) Call for an improved set of decay constants for geochronological use. Geochim Cosmochim Acta 65:111–121

    Article  Google Scholar 

  • Berman RG (1988) Internally consistent thermodynamic data for minerals in the system Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2. J Petrol 28:389–414

    Google Scholar 

  • Berman RG (1990) Mixing properties of Ca-Mg-Fe-Mn garnets. Am Mineral 75:328–344

    Google Scholar 

  • Berman RG (1991) Thermobarometry using multi-equilibrium calculations: a new technique, with petrological applications. Canad Mineral 29:833–855

    Google Scholar 

  • Bohlen SR, Wall VJ, Boettcher AL (1983) Experimental investigation and geological applications of equilibria in the system FeO-TiO2-Al2O3-SiO2-H2O. Am Mineral 68:1049–1058

    Google Scholar 

  • Boynton WV (1984) Cosmochemistry of the rare earth elements: meteorite studies. In: Henderson P (ed) Rare earth element geochemistry. Elsevier, Amsterdam, pp 63–114

    Google Scholar 

  • Brandelik A, Massonne HJ (2004) PTGIBBS-an EXCELTM Visual Basic program for computing and visualizing thermodynamic functions and equilibria of rock-forming minerals. Comput Geosci 30:909–923

    Article  Google Scholar 

  • Burton KW, Kohn MJ, Cohen AS, O’Nions RK (1995) The relative diffusion of Pb, Nd, Sr and O in garnet. Earth Planet Sci Lett 107:649–671

    Article  Google Scholar 

  • Carswell DA, O’ Brien PJ, Wilson RN, Zhai M (1997) Thermobarometry of phengite-bearing eclogites in the Dabie Mountains of central China. J Metam Geol 15:239–252

    Article  Google Scholar 

  • Chopin C, NV Sobolev (1995) Principal mineralogic indicators of UHP in crustal rocks. In: Coleman RG and Wang X (eds) Ultrahigh pressure metamorphism. Cambridge Univ Press, New York, pp 96–131

    Google Scholar 

  • Coggon R, Holland TJB (2002) Mixing properties of phengitic micas and garnet-phengite thermobarometers. J Metam Geol 20:683–696

    Article  Google Scholar 

  • De Capitani C (1994) Gleichgewichts-Phasendiagramme: Theorie und Software. Beihefte Eur J Min 6:48–72

    Google Scholar 

  • Faninger E (1970) Pohorski tonalit in njegovi diferenciati. Geologija 13:35–104

    Google Scholar 

  • Ganguly J, Tirone M, Hervig RL (1998) Diffusion kinetics of samarium and neodymium in garnet, and a method of determining cooling rates of rocks. Science 281:805–807

    Article  PubMed  Google Scholar 

  • Goldstein S, O’Nions RK, Hamilton PJ (1984) A Sm-Nd isotopic study of atmospheric dusts and particulates from major river systems. Earth Planet Sci Lett 70:221–236

    Article  Google Scholar 

  • Griffin WL, Brueckner HK (1985) REE, Rb-Sr and Sm-Nd studies of Norwegian eclogites. Chem Geol 52:249–271

    Google Scholar 

  • Hinterlechner-Ravnik A, Moine B (1977) Geochemical characteristics of the metamorphic rocks of the Pohorje Mountains. Geologija 20:107–140

    Google Scholar 

  • Hoskin PWO, Schaltegger U (2003) The composition of zircon and igneous and metamorphic petrogenesis. Rev Mineral Geochem 53:27–62

    Article  Google Scholar 

  • Ippen JA (1892) Zur Kenntnis der Eklogite und Amphibolite des Bachergebirges. Mitt naturw Ver Steiermark:328–369

  • Jagoutz E (1988) Nd and Sr systematics in an eclogite from Tanzania: Evidence for frozen mineral equilibria in the continental lithosphere. Geochim Cosmochim Acta 52:1285–1293

    Article  Google Scholar 

  • Jagoutz E (1995) Isotopic constraints on garnet equilibration. Terra Abstracts 7:339

    Google Scholar 

  • Janák M, Froitzheim N, Lupták B, Vrabec M, Krogh Ravna EJ (2004) First evidence for ultrahigh-pressure metamorphism of eclogites in Pohorje, Slovenia: Tracing deep continental subduction in the Eastern Alps. Tectonics 23 TC5014, doi:10.1029/2004TC001641

  • Kleemann U, Reinhardt J (1994) Garnet-biotite thermometry revisited: The effect of AlVI and Ti in biotite. Eur J Mineral 6:925–941

    Google Scholar 

  • Koziol MA, Newton RC (1988) Redetermination of the anorthite breakdown reaction and improvement of the plagioclase-garnet-Al2SiO5–quartz geobarometer. Amer Mineral 73:216–223

    Google Scholar 

  • Kretz R (1983) Symbols for rock-forming minerals. Amer Mineral 68:277–279

    Google Scholar 

  • Krogh Ravna EJ (2000) The garnet-clinopyroxene Fe2+ -Mg geothermometer: an updated calibration. J Metam Geol 18:211–219

    Article  Google Scholar 

  • Krogh Ravna EJ, Terry P (2004) Geothermobarometry of UHP and HP eclogites and schists – an evaluation of equilibria among garnet-clinopyroxene-kyanite-phengite-coesite/quartz. J Metam Geol 22:579–592

    Article  Google Scholar 

  • Ludwig KR (1980) Calculations of uncertainties of U-Pb isotopic data. Earth Planet Sci Lett 46:212–220

    Article  Google Scholar 

  • Ludwig KR (2003) User’s manual for Isoplot 3.00. Berkeley Geochronoloy Center Special Publication: 74pp

  • Meyre C, De Capitani C, Partzsch JH (1997) A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland). J Metam Geol 15:687–700

    Article  Google Scholar 

  • Mezger K, Essene EJ, Halliday AN (1992) Closure temperatures of the Sm-Nd system in metamorphic garnets. Earth Planet Sci Lett 113:397–409

    Article  Google Scholar 

  • Michard P, Gurriet P, Soudant N, Albarède F (1985) Nd isotopes in French Phanerozoic shales: external vs. internal aspects of crustal evolution. Geochim Cosmochim Acta 49:601–610

    Article  Google Scholar 

  • Miller C (1990) Petrology of the type locality eclogites from the Koralpe and Saualpe (Eastern Alps), Austria. Schweiz Mineral Petrogr Mitt 70:287–300

    Google Scholar 

  • Miller C, Konzett J. (2005) Comment on “ First evidence for ultrahigh-pressure metamorphism of eclogites in Pohorje, Slovenia: Tracing deep continental subduction in the Eastern Alps”. Tectonics (in press)

  • Miller C, Thöni M (1995) Origin of eclogites from the Austroalpine Ötztal basement (Tirol, Austria): geochemistry and Sm-Nd vs. Rb-Sr isotope systematics. Chem Geol 122:199–225

    Article  Google Scholar 

  • Miller C, Thöni M (1997) Eo-Alpine eclogitisation of Permian MORB-type gabbros in the Koralpe (Austria): new petrological, geochemical and geochronological data. Chem Geol 137:283–310

    Article  Google Scholar 

  • Miller C, Stosch HG, Hoernes S (1988) Geochemistry and origin of eclogites from the type locality Koralpe and Saualpe, Eastern Alps, Austria. Chem Geol 67:103–118

    Article  Google Scholar 

  • Mørk MBE, Mearns EW (1986) Sm-Nd isotopic systematics of a gabbro-eclogite transition. Lithos 19:255–267

    Article  Google Scholar 

  • Muehlenbachs K (1986) Alteration of the oceanic crust and the 18O history of seawater. Rev Mineral 16:425–444

    Google Scholar 

  • Mundil R, Metcalfe I, Ludwig KR, Renne PR, Oberli F, Nicoll RS (2001) Timing of the Permian-Triassic biotic crisis: implications for new zircon U/Pb age data (and their limitations). Earth Planet Sci Lett 187:131–145

    Article  Google Scholar 

  • Mundil R, Ludwig KR, Metcalfe I, Renne PR (2004) Age and timing of the Permian mass extinctions: U/Pb dating of closed-system zircons. Science 305:1760–1763

    Article  PubMed  Google Scholar 

  • Powell R (1985) Regression diagnostics and robust regression in geothermometer/geobarometer calibration: the garnet-clinopyroxene geothermometer revisited. J Metam Geol 3:231–243

    Article  Google Scholar 

  • Prince CI, Kosler J, Vance D, Günther D (2000) Comparison of laser ablation ICP-MS and isotope dilution REE analyses–implications for Sm-Nd garnet geochronology. Chem Geol 168:255–274

    Article  Google Scholar 

  • Renne PR, Karner DB, Ludwig KR (1998) Radioisotope dating–absolute ages aren‘t exactly. Science 282:1840–1841

    Article  Google Scholar 

  • Rubatto D (2002) Zircon trace element geochemistry: partitioning with garnet and the link between U-Pb ages and metamorphism. Chem Geol 184:123–138

    Article  Google Scholar 

  • Rubatto D, Gebauer D (1999) Eo/Oligocene (35 Ma) high-pressure metamorphism in the Gornergrat Zone (Monte Rosa, Western Alps): implications for paleogeography. Schweiz Mineral Petrogr Mitt 79:353–362

    Google Scholar 

  • Rubatto D, Gebauer D (2000) Use of cathodoluminescence for U-Pb zircon dating by ion microprobe: some examples from the Western Alps. In: Pagel M, Barbin V, Blanc P, Ohnenstetter D (eds) Cathodoluminescence in geosciences. Springer, Berlin Heidelberg New York, pp 373–400

    Google Scholar 

  • Rubatto D, Hermann J (2003) Zircon formation during fluid circulation in eclogites (Monviso, Western Alps): implications for Zr and Hf budget in subduction zones. Geochim Cosmochim Acta 67:2173–2187

    Article  Google Scholar 

  • Rubatto D, Gebauer D, Compagnoni R (1999) Dating of eclogite-facies zircons: the age of Alpine metamorphism in the Sesia–Lanzo Zone (Western Alps). Earth Planet Sci Lett 167:141–158

    Article  Google Scholar 

  • Sassi R, Mazzoli C, Miller C, Konzett J (2004) Geochemistry and metamorphic evolution of the Pohorje Mountain eclogites from the easternmost Austroalpine basement, Eastern Alps, Slovenia. Lithos 78:235–261

    Article  Google Scholar 

  • Schmädicke E, Mezger K, Cosca MA, Okrusch M (1995) Variscan Sm-Nd and Ar-Ar ages of eclogite facies rocks from the Erzgebirge, Bohemian Massif. J Metam Geol 13:537–552

    Article  Google Scholar 

  • Stacey JS, Kramers JD (1975) Approximation of terrestrial lead isotope evolution by a two-stage model. Earth Planet Sci Lett 26:207–221

    Article  Google Scholar 

  • Staudigel H, Muehlenbachs K, Richardson SH, Hart SR (1981) Agents of low temperature ocean crust alteration. Contrib Mineral Petrol 77:150–157

    Article  Google Scholar 

  • Stosch HG, Lugmair GW (1990) Geochemistry and evolution of MORB-type eclogites from the Münchberg Massif, southern Germany. Earth Planet Sci Lett 99:230–249

    Article  Google Scholar 

  • Thöni M (1999) A review of geochronological data from the Eastern Alps. Schweiz Mineral Petrogr Mitt 79:209–230

    Google Scholar 

  • Thöni M (2002) Sm-Nd isotope systematics in garnet from different lithologies (Eastern Alps): age results, and an evaluation of potential problems for Sm-Nd garnet chronometry. Chem Geol 185:255–281

    Article  Google Scholar 

  • Thöni M, Jagoutz E (1992) Some new aspects of dating eclogites in orogenic belts: Sm-Nd, Rb-Sr, and Pb-Pb isotopic results from the Austroalpine Saualpe and Koralpe type-locality (Carinthia/Styria, southeastern Austria). Geochim Cosmochim Acta 56:347–368

    Article  Google Scholar 

  • Thöni M, Miller C (1996) Garnet Sm-Nd data from the Saualpe and the Koralpe (Eastern Alps, Austria): chronological and P-T constraints on the thermal and tectonic history. J Metam Geol 14:453–466

    Article  Google Scholar 

  • Thöni M, Blichert-Toft J, Armstrong R, Miller C (2001) Garnet Lu-Hf and zircon SHRIMP U-Pb data confirm a Late Cretaceous age and fast exhumation rate for the type-locality eclogites in SE Austria (Saualpe, Eastern Alps). Conference Abstracts (EUG XI) 6/1, 590

  • Tiepolo M, Bottazzi P, Palenzona M, Vannucci R (2003) A laser probe coupled with ICP-double-focusing sector-field mass spectrometer for in-situ analysis of geological samples and U-Pb dating of zircon. Canadian Mineral 41:259–272

    Article  Google Scholar 

  • Vance D, O’Nions RK (1990) Isotopic chronometry of zoned garnets: growth kinetics and metamorphic histories. Earth Planet Sci Lett 97:227–240

    Article  Google Scholar 

  • Vance D, O’Nions RK (1992) Prograde and retrograde thermal histories from the central Swiss Alps. Earth Planet Sci Lett 114:113–129

    Article  Google Scholar 

  • Visonà D, Hinterlechner-Ravnik A, Sassi FP (1991) Geochemistry and crustal P-T polymetamorphic path of the mantle-derived rocks from the Pohorje area (Austrides, Eastern Alps, Slovenia). Min Slovaca 23:515–525

    Google Scholar 

  • Waters DJ, Martin HN (1993) Geobarometry in phengite-bearing eclogites. Terra Abst 5:410–411

    Google Scholar 

  • Whitehouse MJ, Platt JP (2003) Dating high-grade metamorphism-constraints from rare-earth elements in zircon and garnet. Contrib Mineral Petrol 145:61–74

    Article  Google Scholar 

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Acknowledgements

We thank M. Jelenc (University of Vienna) for performing the Sr isotope analytical work and A. Zanetti (Pavia) for the LA-ICP-MS analyses. Rb-Sr and Sm-Nd analytical work was supported by the Austrian Science Foundation (FWF), project P13227-GEO, the U/Pb work by the Ann and Gordon Getty Foundation. The University of Innsbruck funded the LA-ICP-MS analyses. Thoughtful reviews by K. Mezger and U. Schaltegger helped improve the manuscript.

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Correspondence to Christine Miller.

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Miller, C., Mundil, R., Thöni, M. et al. Refining the timing of eclogite metamorphism: a geochemical, petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains, Slovenia (Eastern Alps). Contrib Mineral Petrol 150, 70–84 (2005). https://doi.org/10.1007/s00410-005-0004-0

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