Abstract
Thirty-one plugs of alkaline volcanic rocks of Cenozoic age (37 Ma in mean) occur in the Upper Benue valley, northern Cameroon (Central Africa). The complete alkaline series (alkaline basalts, hawaiites, mugearites, phonolites, trachytes and rhyolites) is represented. Basalts contain phenocrysts of olivine, Al-Ti-rich diopside, and Ti-magnetite, and hawaiites-abundant microphenocrysts of plagioclase. Mugearites have a trachytic texture and contain xenocrysts of K-feldspar, apatite, quartz and unstable biotite. Phonolites are peralkaline. Trachytes (peralkaline and non-peralkaline) and rhyolites are characterised by their sodic mineralogy with aegirine-augite, richterite, and arfvedsonite phenocrysts. There is a large compositional gap between basaltic and felsic lavas, except the mugearites. Despite this gap, major- and trace-element distributions are in favour of a co-magmatic origin for the basaltic and felsic lavas. The Upper Benue valley basalts are similar in their chemical and isotopic features to other basalts from both the continental and oceanic sectors of the Cameroon Line. The Upper Benue valley basaltic magmas (87Sr/86Sr≈0.7035; ε Nd=+3.9) originate from an infra-lithospheric reservoir. The Sr–Nd isotopic composition and high Sr contents of the mugearites suggest that they are related to mantle-derived magmas and that they result from the mixing, at shallow crustal levels, of a large fraction of trachytic magma with a minor amount of basaltic magma. Major-element modelling of the basalt–trachyte evolution (through hawaiite and mugearite compositions) does not support an evolution through fractional crystallization alone. The fluids have played a significant role in the felsic lavas genesis, as attested by the occurrence of F-rich minerals, calcite and analcite. An origin of the Upper Benue valley rhyolitic magmas by fractional crystallization of mantle-derived primitive magmas of basaltic composition, promoted or accompanied by volatile, halogen-rich fluid phases, may be the best hypothesis for the genesis of these lavas. These fluids also interact with the continental crust, resulting in the high Sr-isotope initial ratios (0.710) in the rhyolites, whereas the Nd isotopic composition has been less affected (ε Nd=+0.4).
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References
Ashwal LD, Demaiffe D, Torsvik, TH (2002) Petrogenesis of Neoproterozoic granitoids and related rocks from the Seychelles: the case for an Andean-type arc origin. J Petrol 43:45–83
Azambre B, Rossy M, Albarède F (1992) Petrology of the alkaline magmatism from the Cretaceous North-Pyrenean Rift Zone (France and Spain). Eur J Mineral 4:813–834
Ballentine CJ, Lee D-C, Halliday AN (1997) Hafnium isotopic studies of the Cameroon line and new HIMU paradoxes. Chem Geol 139:111–124
Barth TFW (1963) The composition of nepheline. Schweiz Mineral Petrog Mitt 43:153–164
Benkhelil J (1988) Structure et évolution géodynamique du bassin intracontinental de la Bénoué (Nigéria). Bull Centre Rech Explor Prod Elf-Aquitaine 12:29–128
Bonhomme M, Thuizat R, Pinault Y, Clauer N, Wendling A, Winkler R (1975) Méthode de datation potassium-argon. Appareillage et technique. Notes Techn Inst Géol Univ Louis Pasteur Strasbourg 3:1–53
Bonnefoi CC, Provost A, Albarède F (1995) The 'Daly gap' as a magmatic catastrophe. Nature 378:270–272
Carignan J, Hild P, Mévelle G, Morel J, Yeghicheyan D (2001) Routine analyses of trace elements in geological samples using flow injection and low pressure on-line liquid chromatography couples to ICPMS: a study of geochemical reference materials BR, DR-N, UB-N, AN-G and GH. Geostand Newslett 25:187–198
Carmichael ISE, Turner FJ, Verhoogen J (1974) Igneous petrology. McGraw-Hill, New York, pp 1–739
Charles RW (1975) The phase equilibrium of richterite and ferrorichterite. Am Mineral 60:367–374
Cox A, Dalrymple GB (1967) Statistical analysis of geomagnetic reversal data and the precision of potassium-argon dating. J Geophys Res 72:2603–2614
Creaser RA, Price RC, Wormald RJ (1991) A-type granites revisited: assessment of a residual-source. Geology 19:163–166
Dautria JM, Dupuy C, Takherist D, Dostal J (1992) Carbonate metasomatism in the lithospheric mantle: peridotitic xenoliths from a melilitic district of the Sahara basin. Contrib Mineral Petrol 111:37–52
DePaolo DJ (1981) Trace element and isotopic effects of combined wallrock assimilation and fractional crystallization. Earth Planet Sci Lett 53:189–202
Déruelle B, N'ni J, Kambou R (1987) Mont Cameroon, an active volcano of the Cameroon Line. J Afr Earth Sci 6:197–214
Déruelle B, Moreau C, Nkoumbou C, Kambou R, Lissom J, Njongfang E, Ghogomu RT, Nono A (1991) The Cameroon Line: a review. In: Kampunzu AB, Lubala RT (eds) Magmatism in extensional structural settings. The Phanerozoic African Plate. Springer, Berlin Heidelberg New York, pp 274–327
Déruelle B, Ngounouno I, Nkoumbou C (1998) Mt Cameroon, Mt Etinde, and Bioko Island volcanoes of the "Cameroon hot Line". In: Program Abstr Vol Conf Evolution of Ocean Island Volcanoes, Galapagos Islands, 4–12 June. Penrose Conf Ser, p 28
Déruelle B, Bardintzeff J-M, Cheminée J-L, Ngounouno I, Lissom J, Nkoumbou C, Etame J, Hell JV, Tanyileke G, N'ni J, Bekoa A, Ntomu N, Nono A, Wandji P, Fosso J, Nkouathio DG (2000) Eruptions simultanées de basalte alcalin et de hawaiite au Mont Cameroun (28 mars–17 avril 1999). C R Acad Sci Paris Sér IIA Earth Planet Sci 331:525–531
Draper DS (1991) Late Cenozoic bimodal magmatism in the northern Basin and Range Province of southeastern Oregon. J Volcanol Geotherm Res 47:299–328
Duggan MB (1988) Zirconium-rich sodic pyroxenes in felsic volcanics from the Warrumbungle Volcano, Central New South Wales. Mineral Mag 52:491–946
Duncan R (1981) Hotspots in the southern oceans—an absolute frame of reference for motion of the Gondwana continents. Tectonophysics 74:29–42
Ernst WG (1962) Synthesis, stability relations and occurrence of riebeckite-arfvedsonite solid solutions. J Geol 70:689–736
Esperança S, Holloway JR (1987) On the origin of some mica lamprophyres: experimental evidence from a mafic minette. Contrib Mineral Petrol 95:207–216
Ezangono J, Déruelle B, Ménard J-J (1995) Benmoreites from Tchabal Djinga volcano (Adamawa, Cameroon): products of kaersutite + plagioclase assimilation by a trachytic magma. Terra AbstSuppl Terra Nova 5,1:161
Farges F, Brown GE Jr, Velde D (1994) Structural environment of Zr in two inosilicates from Cameroon: mineralogical and geochemical implications. Am Mineral 79:838–847
Ferguson AK (1977) The natural occurrence of aegirine–neptunite solid solution. Contrib Mineral Petrol 60:247–253
Fitton JG (1980) The Benue trough and Cameroon line—a migration rift system in West Africa. Earth Planet Sci Lett 51:132–138
Fitton JG (1983) Active versus passive continental rifting: evidence from the West African rift system. Tectonophysics 94:473–481
Fitton JG (1987) The Cameroon line, West Africa: a comparison between oceanic and continental alkaline volcanism. In: Fitton JG, Upton BGJ (eds) Alkaline igneous rocks. Geol Soc Lond Spec Publ 30:273–291
Gèze B (1943) Géographie physique et géologie du Cameroun Occidental. Mém Mus Hist Nat Nouv Sér 17:1–272
Giret A, Bonin B, Léger J-M (1980) Amphibole compositional trends in oversaturated and undersaturated alkaline plutonic ring-complexes. Can Mineral 18:481–495
Grant NK, Rex DC, Freeth SJ (1972) Potassium-argon ages and strontium isotope ratio measurements from volcanic rocks in northeastern Nigeria. Contrib Mineral Petrol 69:97–103
Guiraud R (1993) Late Jurassic-Early Cretaceous rifting and Late Cretaceous transpressional inversion in the Upper Benue basin (NE Nigeria). Bull Centre Rech Explor Prod Elf-Aquitaine 17:371–383
Guiraud R, Bosworth W (1997) Senonian basin inversion and rejuvenation of rifting in Africa and Arabia: synthesis and implications to plate-scale tectonics. Tectonophysics 282:39–82
Halliday AN, Dickin AP, Fallick AE, Fitton JG (1988) Mantle dynamics: a Nd, Sr, Pb and O isotopic study of the Cameroon line volcanic chain. J Petrol 29:181–211
Hamilton DL (1961) Nephelines as crystallization temperature indicators. J Geol 22:433–466
Hansen K (1980) Lamprophyres and carbonatitic lamprophyres related to rifting in the Labrador Sea. Lithos 13:145–153
Hauri EH, Shimizu N, Dieu JJ, Hart SR (1993) Evidence for hotspot-related carbonatite metasomatism in the oceanic upper mantle. Nature 365:221–227
Hofmann AW (1988) Chemical differentiation of the Earth: the relationship between mantle, continental crust, oceanic crust. Earth Planet Sci Lett 90:297–314
Kampunzu AB, Popoff M (1991) Distribution of the main Phanerozoic African rifts and associated magmatism: introductory notes. In: Kampunzu AB, Lubala RT (eds) Magmatism in extensional structural settings. The Phanerozoic African Plate. Springer, Berlin Heidelberg New York, pp 2–10
Larsen LM (1977) Aenigmatite from the Ilimaussaq intrusion, south Greenland: chemistry and petrological implications. Lithos 10:257–270
Leake BE et al. (1997) Nomenclature of amphiboles: report of the subcommittee on amphiboles of the International Mineralogical Association Commission on new minerals and mineral names. Mineral Mag 61:295–321
Leeman WP (1978) Distribution of Mg between olivine and silicate melt and its complications regarding melt structure. Geochim Cosmochim Acta 42:789–800
Lightfoot PC, Hawkesworth CJ, Sethna SF (1987) Petrogenesis of rhyolites and trachytes from the Deccan Trap: Sr, Nd and Pb isotope and trace element evidence. Contrib Mineral Petrol 95:44–54
MacDonald R (1987) Quaternary peralkaline silicic rocks and caldera volcanoes of Kenya. In: Fitton JG, Upton BGJ (eds) Alkaline igneous rocks. Geol Soc Lond Spec Publ 30:313–333
Mahood GA, Stimac JA (1990) Trace-element partitioning in pantellerites and trachytes. Geochim Cosmochim Acta 54:2257–2276
Marsh JS (1975) Aenigmatite stability in silica-undersaturated rocks. Contrib Mineral Petrol 50:135–144
Marzoli A, Renne PR, Piccirillo EM, Francesca C, Bellieni G, Melfi AJ, Nyobe JB, N'ni J (1999) Silicic magmas from the continental Cameroon Volcanic Line (Oku, Bambouto and Ngaoundere): 40Ar-39Ar dates, petrology, Sr-Nd-O isotopes and their petrogenetic significance. Contrib Mineral Petrol 135:133–150
Marzoli A, Piccirillo EM, Renne PR, Bellieni G, Lacumin M, Nyobe JB, Tongwa AT (2000) The Cameroon Volcanic Line revisited: petrogenesis of continental basaltic magmas from lithospheric and asthenospheric mantle sources. J Petrol 41:87–109
McDonough WF, Rudnick RL (1998) Mineralogy and composition of the upper mantle. In: Hemley RJ (ed) Ultrahigh-pressure mineralogy: physics and chemistry of the Earth's deep interior. Mineral Soc Am Rev Mineral 37:139–175
Meyers JB, Rosendahl BR, Harrison CGA, Ding Z-A (1998) Deep-imaging seismic and gravity results from the offshore Cameroon Volcanic Line, and speculation of African hotlines. Tectonophysics 284:31–63
Montigny R, Le Mer O, Thuizat R, Whitechurch H (1988) K–Ar and 40Ar–39Ar study of metamorphic rocks associated with the Oman ophiolite: tectonic implications. Tectonophysics 151:341–362
Moreau C, Regnoult J-M, Déruelle B, Robineau B (1987) A new tectonic model for the Cameroon Line, Central Africa. Tectonophysics 139:317–334
Morgan WJ (1983) Hotspot tracks and the early rifting of the Atlantic. Tectonophysics 94:123–139
Morimoto N (1989) Nomenclature of pyroxenes. Can Mineral 27:143–156
Mysen OB (1991) Volatiles in magmatic liquids. In: Perchuk LL (ed) Progress in metamorphic and magmatic petrology: a memorial volume in honor of D.S. Korzhinskiy. University Press, Cambridge, pp 435–475
Ngounouno I (1993) Pétrologie du magmatisme cénozoïque de la vallée de la Bénoué et du plateau Kapsiki (nord du Cameroun). Thèse Doct Université Pierre et Marie Curie, Paris, pp 1–280
Ngounouno I, Nkoumbou C, Loulé J-P (1997) Relations entre l'évolution tectono-sédimentaire et le magmatisme du bassin de Garoua (nord du Cameroun). Afr Geosci Rev 4:451–460
Ngounouno I, Déruelle B, Demaiffe D (2000) Petrology of the bimodal Cenozoic volcanism of the Kapsiki Plateau (northernmost Cameroon, Central Africa). J Volcanol Geotherm Res 102:21–44
Ngounouno I, Moreau C, Déruelle B, Demaiffe D, Montigny R (2001) Pétrologie du complexe alcalin sous-saturé de Kokoumi (nord du Cameroun). Bull Soc Géol Fr 172:675–686
Nielsen TFD (1979) The occurrence and formation of Ti-aegirines in peralkaline syenites. An example from the Tertiary ultramafic alkaline Gardiner complex, East Greenland. Contrib Mineral Petrol 69:235–244
Nimis P (1999) Clinopyroxene geobarometry of magmatic rocks. Part 2. Structural geobarometers for basic to acid tholeiitic and mildly alkaline magmatic systems. Contrib Mineral Petrol 135:62–74
Nono A, Déruelle B, Demaiffe D, Kambou R (1994) Tchabal Nganha volcano in Adamawa (Cameroon): petrology of a continental alkaline lava series. J Volcanol Geotherm Res 60:147–178
Pearce JA, Norry MJ (1979) Petrogenetic implications of Ti, Zr, Y, and Nb variations in volcanic rocks. Contrib Mineral Petrol 69:33–47
Poudjom Djomani YH, Nnange JM, Diament M, Ebinger GJ, Fairhead JD (1995) Effective elastic thickness and crustal thickness variations in West-Central Africa inferred from gravity data. J Geophys Res 100:22047–22070
Poudjom Djomani YH, Diament M, Wilson M (1997) Lithospheric structure across the Adamawa plateau (Cameroon) from gravity studies. Tectonophysics 273:317–327
Presnall DC, Dixon SA, Dixon JR, O'Donneil TH, Brenner NL, Scrock RL, Dycus DW (1978) Liquidus phase relations on the join diopside–forsterite–anorthite from 1 atm to 20 kb: their bearing on the generation and crystallization of basaltic magma. Contrib Mineral Petrol 66:203–220
Price JG, Rubin JN, Henry CD, Pinkston TL, Tweedy SW, Koppenaal DW (1990) Rare-metal enriched peraluminous rhyolites in a continental arc, Sierra Blanca area, Trans-Pecos Texas; chemical modification by vapor-phase crystallization. In: Stein HJ, Hannah JL (eds) Ore-bearing granite systems; petrogenesis and mineralizing processes. Geol Soc Am Spec Pap 246:103–120
Roeder PL, Emslie RF (1970) Olivine–liquid equilibrium. Contrib Mineral Petrol 29:275–289
Rudnick RL, McDonough, WF Chappell BW (1993) Carbonatite metasomatism in the northern Tanzanian mantle: petrographic and geochemical characteristics. Earth Planet Sci Lett 114:463–475
Steiger RH, Jäger E (1977) Subcommission of geochronology: convention on the use of decay constants in geo- and cosmo-chronology. Earth Planet Sci Lett 36:359–362
Stormer Jr C (1983) The effects of recalculation on estimates of temperature and oxygen fugacity from analyses of multicomponent iron-titanium oxides. Am Mineral 68:586–594
Strong DF, Taylor RP (1984) Magmatic-subsolidus and oxidation trends in composition of amphiboles from silica-saturated peralkaline igneous rocks. Tschermaks Mineral Petrogr Mitt 32:211–222
Stuart GW, Fairhead JD, Dorbath L, Dorbath C (1985) A seismic refraction study of the crustal structure associated with the Adamawa Plateau and Garoua Rift, Cameroon, West Africa. Geophys J R Astron Soc 81:1–12
Thompson GM, Smith IEM, Malpas JG (2001) Origin of oceanic phonolites by crystal fractionation and the problem of the Daly gap: an example from Rarotonga. Contrib Mineral Petrol 142:336–346
Thornton CP, Tuttle OF (1960) Chemistry of igneous rocks. I. Differentiation index. Am J Sci 258:664–684
Van Houten FB (1983) Sirte Basin, northcentral Libya: Cretaceous rifting above a fixed mantle hotspot? Geology 11:115–118
Watson EB (1979) Zircon saturation in felsic liquids: experimental results and applications to trace element geochemistry. Contrib Mineral Petrol 70:407–419
Wellman TR (1970) The stability of sodalite in a synthetic syenite plus aqueous chloride fluid system. J Petrol 11:149–171
Acknowledgements
The French Ministère de la Coopération is acknowledged for providing grants to I.N. for stays in France in the Laboratoire de Magmatologie et de Géochimie Inorganique et Expérimentale, Université Pierre et Marie Curie, Paris, and for financially supporting the research work. This work is part of a Thèse de l'Université Pierre et Marie Curie (Paris VI) by I.N. Fieldwork (B.D. and I.N.) was substantially supported by the Faculty of Sciences of the University of Yaoundé (Dean, Prof. G. Valet). The isotopic measurements in the Université Libre de Bruxelles were financially supported by the Ministère des Affaires Économiques (projet SGB/NAT 91-98). The constructive comments of J. Keller and an anonymous reviewer are greatly appreciated.
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Ngounouno, I., Déruelle, B., Demaiffe, D. et al. Petrology of the Cenozoic volcanism in the Upper Benue valley, northern Cameroon (Central Africa). Contrib Mineral Petrol 145, 87–106 (2003). https://doi.org/10.1007/s00410-002-0438-6
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DOI: https://doi.org/10.1007/s00410-002-0438-6