Abstract
Macroscopic and microscopic drying patterns were observed on a cover glass, a watch glass, and a Petri glass dish during the course of dryness of aqueous solutions of α-cyclodextrin (αCD), β-cyclodextrin (βCD), and γ-cyclodextrin (γCD), i.e., cone shape oligomers of polysaccharide. For all CD molecules, two kinds of macroscopic patterns, outside and inner broad rings and spoke lines formed. Multi-broad rings were formed for βCD in the inner region of the main broad ring at the outside edge especially at the high concentrations. Cooperative drying processes of the convection, sedimentation, and solidification were clarified. Microscopic drying patterns showing the formation of rod-like and/or sward-like crystals were observed mainly in the direction along the spoke lines. The microscopic patterns of βCD were similar to those of some of polysaccharides and polynucleotides the authors studied previously. α- and γ-cyclodextrins were slightly hygroscopic, and clear-cut drying patterns were not observed.
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Acknowledgments
Research funds from AMX Co. (Tokyo) are thanked deeply. Financial supports from the Ministry of Education, Culture, Sports, Science and Technology, Japan and Japan Society for the Promotion of Science for Grants-in-Aid for Exploratory Research and Scientific Research (B), respectively, are also greatly acknowledged.
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Okubo, T. Inclusional association as studied by the drying dissipative structure. Part 1. Drying patterns of α-, β- and γ-cyclodextrin. Colloid Polym Sci 291, 2447–2454 (2013). https://doi.org/10.1007/s00396-013-2972-3
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DOI: https://doi.org/10.1007/s00396-013-2972-3