Abstract
Film over nanosphere (FON) patterns are formed by depositing a silver film on top of a close-packed polystyrene (PS) sphere template. Multiple localized surface plasmon resonance (LSPR) peaks are experimentally measured in the three-dimensional FON pattern for thin silver films. Increasing the sphere size in the close-packed template or the deposited silver film thickness red shifts the LSPR peaks to varying degrees. A finite difference time domain analysis reveals that the main LSPR peaks originate from a quadrupole and a dipole coupling mode near the triangle gap surrounded by three adjacent PS spheres. The physical location and the electromagnetic enhancement of the two resonant modes are determined for different thicknesses of deposited silver films.
Similar content being viewed by others
References
P. Freunscht, R.P. Van Duyne, S. Scheider, Chem. Phys. Lett. 281, 372 (1997)
P. Stiles, J.A. Dieringer, N.C. Shah, R.P. Van Duyne, Annu. Rev. Anal. Chem. 1, 601 (2008)
X. Zhang, R.P. Van Duyne, In: Mater. Res. Soc. Symp. Proc., vol. 876E (2005)
L.A. Dick, A.D. McFarland, C.L. Haynes, R.P. Van Duyne, J. Phys. Chem. B 106, 853 (2002)
K.B. Biggs, J.P. Camden, J.N. Anker, R.P. Van Duyne, J. Phys. Chem. A 113, 4581 (2009)
H. Li, J. Low, K.S. Brown, N.Q. Wu, IEEE Sens. J. 8, 880 (2008)
A.F. Oskooi, D. Roundy, M. Ibanescu, P. Bermel, J.D. Joannopoulos, S.G. Johnson, Comput. Phys. Commun. 181, 687 (2010)
A. Taflove, S. Hagness, Computational Electrodynamics: The Finite-Difference Time-Domain Method (Artech House, Norwood, 2000)
E.D. Palik, Handbook of Optical Constants of Solids (Academic Press, New York, 1985)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cushing, S.K., Hornak, L.A., Lankford, J. et al. Origin of localized surface plasmon resonances in thin silver film over nanosphere patterns. Appl. Phys. A 103, 955–958 (2011). https://doi.org/10.1007/s00339-011-6393-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-011-6393-1