Skip to main content
Log in

Heavy metal sources in Sultan Marsh and its neighborhood, Kayseri, Turkey

  • Original Article
  • Published:
Environmental Geology

Abstract

Sultan Marsh (Turkey) is one of the largest wet lands of the Middle East and Europe. The aim of this study was to determine average concentrations of heavy metals, variations of the obtained values in a large scale, geogenic and anthropogenic sources of the pollution and effects of the pollution on the environment in Sultan Marsh. To these aims, a total of 176 surface soil samples (0–10 cm depth) were collected from 80 ha land in Sultan Marsh. Using a bench-top Spectro-Xepos X-ray fluorescence spectrometer, we analyzed all samples to determine the near-total concentrations of 26 chemical elements. Basic and multivariate statistics were used for statistical analyses. GIS mapping, a powerful tool for identifying possible sources of pollutants, was used to classify and identify the elements. Relatively high concentrations of the elements Fe, Pb, Zn, Sb, W, Mo, Co, Cu, Hg, Ni, Cr, Mn and Cd were found in Sultan Marsh, surrounding rocks (geogenic sources), mines of Fe and Pb/Zn, industrial facilities, residential and agricultural areas and major traffic routes (anthropogenic sources).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Adachia K, Tainoshob Y (2004) Characterization of heavy metal particles embedded in tire dust. Environ Int 30:1009–1017

    Article  Google Scholar 

  • Aksoy A, Demirezen D, Duman F (2005) Bioaccumulation, detection and analyses of heavy metal pollution in Sultan Marsh and its environment. Water Air Soil Pollut 164(1–4):241–255

    Article  Google Scholar 

  • Boyle RW (1975) The geochemistry of antimony, Keno Hill area, Yukon, Canada. In: Tugarinov AI (ed) Recent contributions to geochemistry and analytical chemistry. Wiley, New York, pp 354–370

    Google Scholar 

  • Brady NC (1974) The nature and properties of soils, 8th edn. Macmillan, New York, p 636

    Google Scholar 

  • Brooks RR (1972) Geobotany and biogeochemistry in mineral exploration. Harper and Row, New York, p 290

    Google Scholar 

  • CKGM, Sultansazlıgı (1998) T.C. Cevre Bakanlıgı Cevre Koruma Genel Müdürlügü Yayını, p 25 (in Turkish)

  • Connor JJ, Shacklette HT (1975) Background geochemistry of some soils, plants and vegetable in the conterminous United States. US Geol Survey paper 574, p 164

  • Davies BE (1978) Plant-available lead and other metals in British garden soils. Sci Total Environ 9(3):243–262

    Article  Google Scholar 

  • Demirezen D, Aksoy A (2004) Accumulation of heavy metals in Typha angustifolia (L.) and Potamogeton pectinatus (L.) living in Sultan Marsh (Kayseri, Turkey) Chemosphere 56:685–696

    Article  Google Scholar 

  • Demirezen D, Aksoy A (2006) Common hydrophytes as bioindicators of iron and manganese pollutions Ecological Indicators. Ecol Indic 6:388–393

    Article  Google Scholar 

  • Dhont D, Chorowicz J, Yurur T, Froger J-L, Kose O, Gundogdu N (1998) Emplacement of volcanic vents and geodynamics of Central, Anatolia, Turkey. J Volcanol Geother Res 85:33–54

    Article  Google Scholar 

  • Dirik K (2001) Neotectonic evolution of the northwestward arched segment of the Central Anatolian Fault Zone, Central Anatolia, Turkey. Geodinamica Acta 14:147–158

    Article  Google Scholar 

  • Erol O (1999) A geomorphological study of the Sultansazligi Lake, central Anatolia. Q Sci Rev 18:647–657

    Article  Google Scholar 

  • Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Pollut 114:313–324

    Article  Google Scholar 

  • Farmer JG, Lyon TDB (1977) Lead in Glasgow street dirt and soil. Sci Total Environ 8:89–93

    Article  Google Scholar 

  • Fuge R (2005) Anthropogenic sources. In: Selinus O (ed) Essentials of medical geology: impacts of the natural environment on public health. Academic, Amsterdam, pp 43–60

    Google Scholar 

  • Haktanir K, Arcak S, Ergül G, Tan A (1997) Yol kenarlarındaki Topraklarda Trafikten Kaynaklanan Ağır Metal Birikimi. Tr J Eng Environ Sci 19:432–431

    Google Scholar 

  • Harrison RM, Laxen DPH, Wilson SJ (1981) Chemical associations of lead, cadmium, copper, and zinc in street dusts and roadside soils. Environ Sci Technol 15(11):1378–1383

    Article  Google Scholar 

  • Ho YB, Tai KM (1988) Elevated levels of lead and other metals in roadside soil and grass and their use to monitor aerial metal depositions in Hong Kong. Environ Pollut 49(1):37–51

    Article  Google Scholar 

  • Kelly J, Thornton I, Simpson PR (1996) Urban geochemistry: a study of the influence of anthropogenic activity on the heavy metal content of soils in traditionally industrial and nonindustrial areas of Britain. Appl Geochem 11(1e2):363–370

    Article  Google Scholar 

  • Kocyigit A, Beyhan A (1998) A new intracontinental transcurrent structure: the Central Anatolian Fault Zone, Turkey. Tectonophysics 284:317–336

    Article  Google Scholar 

  • Krauskopf K (1979) Introduction to geochemistry. McGraw-Hill, NewYork, p 123

  • Li XD, Poon CS, Liu PS (2001) Heavy metal contamination of urban soils and street dusts in Hong Kong. Appl Geochem 16(11–12):1361–1368

    Article  Google Scholar 

  • Li XD, Lee SL, Wong SC, Shi WZ, Thornton I (2004) The study of metal contamination in urban soils of Hong Kong using a GIS-based approach. Environ Pollut 129(1):113–124

    Article  Google Scholar 

  • Liu X, Wu J, Xu J (2005) Characterizing the risk assessment of heavy metals and sampling uncertainty analysis in paddy field by geostatistics and GIS. Environ Pollut 141:1–8

    Google Scholar 

  • Maynard JB (1983) Geochemistry of Toprakary ore deposits, vol 89. Springer, New York, p 119

    Google Scholar 

  • McGrath D, Zhang C, Carton OT (2004) Geostatistical analyses and hazard assessment on soil lead in Silvermines area, Ireland. Environ Pollut 127:239–248

    Article  Google Scholar 

  • Mielke HW, Gonzales CR, Smith MK, Mielke PW (2000) Quantities and associations of lead, zinc, cadmium, manganese, chromium, nickel, vanadium, and copper in fresh Mississippi delta alluvium and New Orleans alluvial soils. Sci Total Environ 246:249–259

    Article  Google Scholar 

  • Olajire AA, Ayodele ET (1997) Contamination of roadside soil and grass with heavy metals. Environ Int 28:91–101

    Article  Google Scholar 

  • Öncel MS, Zedef V, Mert S (2004) Lead contamination of roadside soils and plants between Istanbul and Sakarya, Nw Turkey. Fresenius Bull 13:1525–1529

    Google Scholar 

  • Oudwater N, Martin A (2003) Methods and issues in exploring local knowledge of soils. Geoderma 111:387–401

    Article  Google Scholar 

  • Pekey H (2006) The distribution and sources of heavy metals in Izmit Bay surface sediments affected by a polluted stream. Mar Pollut Bull 52:1197–1208

    Article  Google Scholar 

  • Peltola P, Astrom M (2003) Urban geochemistry: a multimedia and multielement survey of a small town in Northern Europe. Environ Geochem Health 25(4):397–419

    Article  Google Scholar 

  • Purves D (1966) Contamination of urban garden soils with copper and boron. Nature 210:1077–1078

    Article  Google Scholar 

  • Reimann C, Siewers U, Tarvainen T, Bityukova L, Eriksson J, Giucis A, Gregorauskiene V, Lukashev VK, Matinian NN, Pasieczna A (2003) Agricultural Soils in Northern Europe: A Geochemical Atlas. Geologisches Jahrbuch, Sonderhefte, Reihe D, Heft SD5. E. Schweizerbart’sche Verlagsbuchhandlung, Stuttgart, 279 pp

  • Sadiq M, Alam I, El-Mubarek A, Al-Mohdhar HM (1989) Preliminary evaluation of metal pollution from wear of auto tires. Bulletin of Environ Contam Toxicol 42(5):743–748

    Article  Google Scholar 

  • Schuhmacher M, Meneses M, Granero S, Llobet JM, Domingo JL (1997) Trace element pollution of soil collected near a municipal solid waste incinerator: human health risk. Bull Environ Contam Toxicol 59(6):861–867

    Article  Google Scholar 

  • Simonson RW (1995) Airborne dust and its significance to soils. Geoderma 65:1e2–1e43

    Article  Google Scholar 

  • Smolders E, Degryse F (2002) Fate and effect of zinc from tire debris in soil. Environ Sci Technol 36(17):3706–3710

    Article  Google Scholar 

  • Tam NFY, Liu WK, Wang MH, Wong YS (1987) Heavy metal pollution in roadside urban parks and gardens in Hong Kong. Sci Total Environ 59:325–328

    Article  Google Scholar 

  • TD, Traffic Density (2005) 2005-yılı ortalama günlük trafik yogunlugu, Kayseri Karayolları 6.Bölge Müdürlügü, pp 2

  • Thornton I (1991) Metal contamination of soils in urban areas. Soils in the urban environment. Blackwell, London, pp 47–75

    Google Scholar 

  • Tijhuis L, Brattli B, Sæther OM (2002) A geochemical survey of topsoil in the city of Oslo, Norway. Environ Geochem Health 24(1):67–94

    Article  Google Scholar 

  • Topbas M, Brohi A, Karaman M (1998) Çevre Kirliliği, Çevre Bakanlığı Yayınları, 35–61, 105–111, 141–152 (in Turkish)

  • Viard B, Pihan F, Promeyrat S, Pihan JC (2004) Integrated assessment of heavy metal (Pb, Zn, Cd) highway pollution: bioaccumulation in soil, Graminaceae and land snails. Chemosphere 55:1349–1359

    Article  Google Scholar 

  • Wedepohl KL (1969–1978) Handbook of geochemistry, vol 1. Springer, Berlin, p 442

  • Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59(7):1217–1232

    Article  Google Scholar 

  • Wilkins C (1978) The distribution of lead in the soils and herbage of West Pembrokeshire. Environ Pollut 15(1):23–30

    Article  Google Scholar 

  • Yalcin MG, Narin I, Soylak M (2006) Heavy metal contents of the Karasu Creek Sediments. Nigde, Turkey, Environ Monit Assess, p 7. DOI 10.1007/s10661-006-9318-2 (in press)

  • Yalcin MG, Battaloglu R (2007) Investigation of Heavy Metals Pollution along the Nigde-Kayseri Road, Turkey. Asian J of Chem 19(3):2257–2264

    Google Scholar 

  • Yalcin MG, Battaloglu R, Ilhan, S, Tumuklu A, Topuz D (2007) Heavy metal contamination along the Nigde-Adana Highway, Turkey. Asian J Chem 19(2):1506–1518

    Google Scholar 

  • Yassoglou N, Kosmas C, Asimakopoulos J, Kallianou C (1987) Heavy metal contamination of roadside soils in the Greater Athens area. Environ Pollut 47:293–304

    Article  Google Scholar 

  • Yüksel B (1989) Investigations on water birds which were found in winter, in Kayseri-Sultanmarsh, I.Uni. Orman Fakultesi, Yuksek Lisans Tezi, Istanbul, p 95 (in Turkish)

  • Zhang C (2005) Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environ Pollut 142:1–11

    Google Scholar 

Download references

Acknowledgments

The authors would like to thank Kayseri Environment and Forest Province Directorate for providing vehicles during field studies, OYSA-Nigde Cement Factory for XRF analyses and Dilek ERDAG for the GIS mappings from the Department of Geology Engineering, Istanbul University.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Gurhan Yalcin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yalcin, M.G., Battaloglu, R. & Ilhan, S. Heavy metal sources in Sultan Marsh and its neighborhood, Kayseri, Turkey. Environ Geol 53, 399–415 (2007). https://doi.org/10.1007/s00254-007-0655-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00254-007-0655-4

Keywords

Navigation