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An investigation of accelerated temperature-induced ageing of four wood species: colour and FTIR

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Abstract

The study investigated and compared the behaviour of four wood species, originating from Europe and China, in terms of temperature-induced artificial ageing. It was conducted at 100 °C for a total period of 288 h. Ageing effects were evaluated by colour measurements in the CIE Lab system and by FTIR analysis. Colour changes were then related to chemical changes in the wood. The investigated wood species were European ash (Fraxinus excelsior), European walnut (Juglans regia), Chinese ash (Fraxinus mandshurica) and Chinese walnut (Juglans mandshurica). Colour changes were maximum for European ash and minimum for Chinese ash, while European walnut and Chinese walnut evolved quite similarly. Main chemical changes due to temperature ageing were reduction of hydroxyl groups, increase of the unconjugated carbonyl groups and an apparent slight increase of lignin, more evident for European ash and delayed for European walnut. Formation of aromatic carbonyl conjugated groups as quinoid structures as a result of oxidative reactions was revealed especially for European ash. The different behaviour of the studied wood species may be explained by their different chemical composition, especially hemicelluloses, lignin and extractives content.

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References

  • Borrega M, Kärenlampi PP (2008) Effect of relative humidity on thermal degradation of Norway spruce (Picea abies). J Wood Sci 54:323–328

    Article  CAS  Google Scholar 

  • Calienno L, Lo Monaco A, Pelosi C, Picchio R (2014) Colour and chemical changes on photodegraded beech wood with or without red heartwood. Wood Sci Technol 48:1167–1180

    Article  CAS  Google Scholar 

  • Cavicchioli A, Araújo de Faria DL, Neves CA, Antunes MT (2008) Automatic devices for monitoring environmentally induced auto-oxidative degradation of artistic materials in conservation sites. Sens Actuat B 131:462–469

    Article  CAS  Google Scholar 

  • Chang TC, Chang HT, Wu CL, Chang ST (2010a) Influences of extractives on the photodegradation of wood. Polym Degrad Stab 95:516–521

    Article  CAS  Google Scholar 

  • Chang TC, Chang HT, Wu CL, Lin HY, Chang ST (2010b) Stabilizing effect of extractives on the photo-oxidation of Acacia confusa wood. Polym Degrad Stab 95:1518–1522

    Article  CAS  Google Scholar 

  • Chen Y, Gao J, Fan Y, Tshabalala MA, Stark NM (2012) Heat-induced chemical and color changes of extractive-free black locust (Robinia pseudoaccacia) wood. BioResources 7(2):2236–2248

    CAS  Google Scholar 

  • Chen Y, Tshabalala MA, Gao J, Stark NM, Fan Y (2014) Color and surface chemistry changes of extracted wood flour after heating at 120 °C. Wood Sci Technol 48:137–150

    Article  CAS  Google Scholar 

  • Chiantore O, Lazzari M (2001) Photo-oxidative stability of paraloid acrylic protective polymers. Polymer 42:17–27

    Article  CAS  Google Scholar 

  • Colom X, Carrillo F, Nogués F, Garriga P (2003) Structural analysis of photodegraded wood by means of FTIR spectroscopy. Polym Degrad Stab 80:543–549

    Article  CAS  Google Scholar 

  • David E (2009) Aging of polymeric materials: principles, Universite du Quebec. http://www.textilescience.ca/downloads/presentation%20Eric%20David.pdf

  • Emandi A, Vasiliu CI, Budrugeac P, Stamatin I (2011) Quantitative investigation of wood composition by integrated FT-IR and thermogravimetric methods. Cell Chem Technol 45:579–584

    CAS  Google Scholar 

  • Esteves B, Velez Marques A, Domingos I, Pereira H (2013) Chemical changes of heat treated pine and Eucalypt wood monitored by FTIR. Maderas. Ciencia y tecnología 15(2):245–258

    CAS  Google Scholar 

  • Fabiyi JS, Ogunleye BM (2015) Mid-infrared spectroscopy and dynamic mechanical analysis of heat treated obeche (Triplochiton scleroxylon) wood. Maderas: Ciencia y Technologia 17(1):5–16

    Google Scholar 

  • Feller RL (1994) Accelerated aging—photochemical and thermal aspects. J Paul Getty Trust, pp 276, Printed in USA, ISBN 0-89236-125-5

  • Fengel D, Wegener G (1984) Wood—chemistry, ultra-structure, reactions. Walter de Gruyter, Berlin and New York

    Google Scholar 

  • Froidevaux J, Navi P (2013) Aging law of spruce wood. Wood Mat Sci Eng 8(1):46–52

    Article  CAS  Google Scholar 

  • González-Peña MM, Curling SF, Hale MDC (2009) On the effect of heat on the chemical composition and dimensions of thermally-modified wood. Polym Degrad Stab 94:2184–2193

    Article  Google Scholar 

  • Hill C (2006) Wood modification: chemical, thermal and other processes. pp 233, Wiley, ISBN: 0-470-02172-1

  • Hon DNS (2001) Weathering and Photochemistry of Wood. In: Hon DNS, Shiraishi N (eds) Wood and cellulosic chemistry. (2nd ed. rev. and expanded) Marcel Decker Inc., New York, pp 513–546

    Google Scholar 

  • Jamalirad L, Doosthoseini JK, Koch G, Mirshokraie SA, Welling J (2012) Investigation on bonding quality of beech wood (Fagus orientalis L.) veneer during high temperature drying and aging. Eur J Wood Prod 70:497–506

    Article  CAS  Google Scholar 

  • Kačík F, Šmíra P, Kacínová D, Reinprecht L, Nassewettrová A (2014) Chemical changes in fir wood from old buildings due to ageing. Cellulose Chem Technol 48(1-2):79–88

    Google Scholar 

  • Kataoka Y, Kiguchi M, Williams R, Evans D (2007) Violet light causes photodegradation of wood beyond the zone affected by ultraviolet radiation. Holzforschung 61:23–27

    Article  CAS  Google Scholar 

  • Kocaefe D, Kocaefe Y, Oumarou N (2015) A novel high temperature heat treatment process for wood. Conference paper. http://www.researchgate.net/publication/279852678

  • Kránitz K, Sonderegger W, Bues CT, Niemz P (2016) Effects of aging on wood: a literature review. Wood Sci Technol 50(1):7–22

    Article  Google Scholar 

  • Lazzari M, Chiantore O (2000) Thermal ageing of paraloid acrylic protective polymers. Polymer 41:6447–6455

    Article  CAS  Google Scholar 

  • Le Van SL (1989) Thermal degradation. In: Schniewind AP (ed) Concise encyclopedia of wood and wood- based materials, 1st edn. Pergamon Press, Elmsford, pp 271–273

    Google Scholar 

  • Liu XY, Cionca M, Timar MC (2015a) A comparative study of 17th century Ming and western European chairs. Eur J Sci Theol 11(1):253–262

    Google Scholar 

  • Liu XY, Cionca M, Varodi A, Timar MC (2015b) A comparative study of Qing and European Rococo chairs (18th century). Ciência e Técnica Vitivinícola 30(2):17–27

    Google Scholar 

  • Matsuo M, Yokohama M, Umemura K, Sugiyama J, Kawai S, Gril J, Yano K, Kubodera S, Mitsutani T, Ozaki H, Sakamoto M, Imamura M (2009) Evaluation of the aging wood from historical buildings as compared with the accelerated aging wood and cellulose—analysis of color properties. In: International conference on wooden cultural heritage, Evaluation of deterioration and management of change, p 6, ct 2009, Germany. https://hal.archives-ouvertes.fr/hal-00796389/document

  • Matsuo M, Yokoyama M, Umemura K, Gril J, Yano H, Kawai S (2010) Color changes in wood during heating: kinetic analysis by applying time–temperature superposition method. Appl Phys A Mater Sci Process 99(1):47–52. doi:10.1007/s00339-010-5542-2

    Article  CAS  Google Scholar 

  • Matsuo M, Yokoyama M, Umemura K, Sugiyama J, Kawai S et al (2011) Aging of wood—analysis of color changing during natural aging and heat treatment. Holzforschung 65(3):361–368

    Article  CAS  Google Scholar 

  • Mehrotra R, Singh P, Kandpal H (2010) Near infrared spectroscopic investigation of the thermal degradation of wood. Themochimica Acta 507–508:60–65

    Article  Google Scholar 

  • Militz H (2002) Heat Treatment Technologies in Europe: Scientific Background and Technological State-of-Art. In: Proceedings of Conference on Enhancing the durability of lumber and engineered wood products. Kissimmee, Orlando. Forest Products Society, Madison, US, 11–13 Feb 2002

  • Millis SM (2013) Understanding pyrography, the photochemistry of ‘scorched’ decoration. Pro Ligno 9849:684–692

    Google Scholar 

  • Niemz P, Hofmann T, Retfalvi T (2010) Investigation of chemical changes in the structure of thermally modified wood. Maderas Ciencia y Tecnologia 12(2):69–78

    CAS  Google Scholar 

  • Pandey KK (1999) A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy. J Appl Polym Sci 71:1969–1975

    Article  CAS  Google Scholar 

  • Pandey KK (2005) Study of the effect of photo-irradiation on the surface chemistry of wood. Polym Degrad Stab 90:9–20

    Article  CAS  Google Scholar 

  • Pandey KK, Vuorinen T (2008) Comparative study of photodegradation of wood by a UV laser and a xenon light source. Polym Degrad Stab 93:2138–2146

    Article  CAS  Google Scholar 

  • Paţachia S, Croitoru C, Friedrich C (2012) Effect of UV exposure on the surface chemistry of wood veneers treated with ionic liquids. Appl Surf Sci 258:6723–6729

    Article  Google Scholar 

  • Persze L, Tolvaj L (2012) Photodegradation of wood at elevated temperature: colour change. J Photochem Photobiol B Biol 108:44–47

    Article  CAS  Google Scholar 

  • Rosu D, Teacă CA, Bodîrlău R, Rosu L (2010) FTIR and colour change of the modified wood as a result of artificial light irradiation. J Photochem Photobiol B 99(3):144–149

    Article  CAS  PubMed  Google Scholar 

  • Smidt E, Schwanninger M, Tintner J, Böhm K (2012) Ageing and deterioration of materials in the environment—application of multivariate data analysis. In: Multivariate analysis in management, engineering and the sciences, chap 8, pp 133–160. licencee InTech. http://dx.doi.org/10.5772/53984

  • Tdjeersma BF, Militz H (2005) Chemical changes in hydrothermal treated wood: FTIR analysis of combined hydrothermal and dry heat-treated wood. Holz Roh- Werkst 63:102–111

    Article  Google Scholar 

  • Teacă CA, Rosu D, Bodîrlău R, Rosu L (2013) Structural changes in wood under artificial UV light irradiation determined by FTIR spectroscopy and color measurements—a brief review. BioRes 8(1):1478–1507

    Google Scholar 

  • Timar MC, Gurău L, Varodi AM (2016) Comparative study of photodegradation of six wood species after short time UV exposure. Wood Sci Technol 50(1):135–163

    Article  CAS  Google Scholar 

  • Tolvaj L, Faix O (1995) Artificial ageing of wood monitored by DRIFT spectroscopy and CIELab color measurements. 1. Effect of UV light. Holzforschung 49:397–404

    Article  CAS  Google Scholar 

  • Tolvaj L, Persze L, Albert L (2011) Thermal degradation of wood during photodegradation. J Photochem Photobiol B 105:90–93

    Article  CAS  PubMed  Google Scholar 

  • Tolvaj L, Molnar Z, Nemeth R (2013) Photodegradation of wood at elevated temperature: infrared spectroscopic study. J Photochem Photobiol, B 121:32–36

    Article  CAS  Google Scholar 

  • Tolvaj L, Molnar Z, Magoss E (2014a) Measurement of photodegradation-caused roughness of wood using a new optical method. J Photochem Photobiol B 134:23–26

    Article  CAS  PubMed  Google Scholar 

  • Tolvaj L, Nemeth R, Pasztory Z, Bejo L, Takats P (2014b) Colour stability of thermally modified wood during short-term photodegradation. BioRes 9(4):6644–6651

    Article  CAS  Google Scholar 

  • Umney N, Rivers S (2003) Conservation of furniture. Butterworth—Heinemann, Linacre House, Jordan Hill, Oxford, ISBN 0 7506 09583

  • Unger A, Schniewind AP, Unger W (2001) Conservation of wooden artifacts. Springer, Berlin. ISBN 3-540-41580-7

    Book  Google Scholar 

  • Wagenführ R (2000) Holzatlas (Wood atlas) (In German). Hanser Fachbuchverlag, Leipzig

    Google Scholar 

  • Wang SX (1989) Study on Ming furniture. Sanlian Publishing House, Hong Kong, pp 12–24

    Google Scholar 

  • Williams RS (2005) Weathering of wood. In: Rowell RM (ed) Handbook of wood chemistry and wood composite. Taylor and Francis (CRC Press), Florida, pp 139–185

    Google Scholar 

  • Windeisen E, Strobel C, Wegener G (2007) Chemical changes during the production of thermo-treated beech wood. Wood Sci Technol 41:523–536

    Article  CAS  Google Scholar 

  • Yildiz S, Tomak ED, Yildiz UC, Ustaomer D (2013) Effect of artificial weathering on the properties of heat treated wood. Polym Degrad Stab 98:1419–1427

    Article  CAS  Google Scholar 

  • Yu DH (2011) Research on digital preservation for Chinese traditional furniture. In: Proceedings of the 12th international conference on computer-aided industrial design and conceptual design l(2):1002–1004

  • Zen WH (2011) A research into the traditional Chinese paintings (the Ruler Paintings) and the Ancient Furniture Culture. In: Proceedings of the 12th international conference on computer-aided industrial design & conceptual design. 2:1046–1050

  • Živković V, Arnold M, Radmanović K, Richter K, Turkulin H (2014) Spectral sensitivity in the photodegradation of fir wood (Abies alba Mill.) surfaces: colour changes in natural weathering. Wood Sci Technol 48:239–252

    Article  Google Scholar 

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Acknowledgments

We hereby acknowledge the structural founds project PRO-DD (POS-CCE, O.2.2.1., ID 123, SMIS 2637, Ctr. No 11/2009) for providing the infrastructure used in this work. This research is part of a 3-year Ph.D. project sustained by Transilvania University of Brasov, Romanian Ministry of Education and Research, the Government of Republic of China and the Embassy of China in Bucharest. We are also grateful to our sponsors providing the wood material for experiments: JF Furnir (European Species) and Beijing Forestry University (Chinese species).

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Correspondence to Maria Cristina Timar.

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Liu, X.Y., Timar, M.C., Varodi, A.M. et al. An investigation of accelerated temperature-induced ageing of four wood species: colour and FTIR. Wood Sci Technol 51, 357–378 (2017). https://doi.org/10.1007/s00226-016-0867-4

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