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Molecularly imprinted solid-phase extraction and flow-injection chemiluminescence for trace analysis of 2,4-dichlorophenol in water samples

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Abstract

Highly sensitive flow-injection chemiluminescence (CL) combined with molecularly imprinted solid-phase extraction (MISPE) has been used for determination of 2,4-dichlorophenol (2,4-DCP) in water samples. The molecularly imprinted polymer (MIP) for 2,4-DCP was prepared by non-covalent molecular imprinting methods, using 4-vinylpyridine (4-VP) and ethylene glycol dimethacrylate (EGDMA) as the monomer and cross-linker, respectively. 2,4-DCP could be selectively adsorbed by the MIP and the adsorbed 2,4-DCP was determined by its enhancing effect on the weak chemiluminescence reaction between potassium permanganate and luminol. The enhanced CL intensity was linear in the range from 1 × 10−7 to 2 × 10−5g mL−1. The LOD (S/N = 3) was 1.8 × 10−8g mL−1, and the relative standard deviation (RSD) was 3.0% (n = 11) for 1.4 × 10−6g mL−1. The proposed method had been successfully applied to the determination of 2,4-DCP in river water.

Effect of 4-VP content on the ultraviolet spectrum of 2,4-DCP in chloroform

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References

  1. Gary W, Gary L, James T (1982) Arch Environ Contam Toxicol 11:73–82

    Article  Google Scholar 

  2. Li XD, Yue YD, Hua R, Huang HS, Yu L, Liao M, Li XH (2002) Agro-Environ Prot 21:156–158

    Google Scholar 

  3. Tsuji N, Hirooka T, Nagase H, Hirata K, Miyamoto K (2003) Biotechnol Lett 25:241–244

    Article  CAS  Google Scholar 

  4. Contreras S, Rodríguez M, Al Momani F, Sans C, Esplugas S (2003) Water Res 37:3164–3171

    Article  CAS  Google Scholar 

  5. Swaminathan G, Ramanujam TK (1999) Bioprocess Eng 21:169–173

    Article  CAS  Google Scholar 

  6. Oliveira R, Manuel FA, Santos L, Madeira LM (2006) Ind Eng Chem Res 45:1266–1276

    Article  CAS  Google Scholar 

  7. Gao JJ, Liu LH, Liu XR, Zhou HD, Huang SB, Wang ZJ (2007) Chemosphere, in press

  8. Wang HT, Zhu K, Wei X, Zhang L, Yang JT, Ma J (2003) J Lanzhou Railway University 22:31–33

    Google Scholar 

  9. Ureta-Zañartu MS, Bustos P, Berríos C, Diez MC, Mora ML, Gutiérrez C (2002) Electrochim Acta 47:2399–2406

    Article  Google Scholar 

  10. Hahn D, Cozzolino A, Piccolo A, Armenante PM (2007) Ecotoxicol Environ Saf 66:335–342

    Article  CAS  Google Scholar 

  11. Laurent F, Debrauwer L, Pascal-Lorber S (2006) Pest Manag Sci 62:558–564

    Article  CAS  Google Scholar 

  12. Gallizia I, McClean S, Banat IM (2003) J Chem Technol Biotechnol 78:959–963

    Article  CAS  Google Scholar 

  13. Drzewicz P, Pahta P, Gluszewski W, Trojanowicz M (1999) J Radioanal Nucl Chem 242:601–609

    Article  CAS  Google Scholar 

  14. Zhang W, Danielson ND (2003) Anal Chim Acta 493:167–177

    Article  CAS  Google Scholar 

  15. Tsukagoshi K, Kameda T, Yamamoto M, Nakajima R (2002) J Chromatogr A 978:213–220

    Article  CAS  Google Scholar 

  16. Hindson BJ, Barnett NW (2001) Anal Chim Acta 445:1–19

    Article  CAS  Google Scholar 

  17. Yang CY, Zhang ZJ, Chen SM, Yang F (2007) Microchim Acta 159:299–304

    Article  CAS  Google Scholar 

  18. Xiong Y, Zhou HJ, Zhang ZJ, He DY, He C (2006) Analyst 31:829–834

    Article  Google Scholar 

  19. Caro E, Masque N, Marce RM, Borrulla F, Cormack PAG, Sherrington DC (2002) J Chromatogr A 963:169–178

    Article  CAS  Google Scholar 

  20. Muldoon MT, Stanker LH (1997) Anal Chem 69:803–808

    Article  CAS  Google Scholar 

  21. Andersson LI, Paprica A, Arvidsson T (1997) Chromatographia 46:57–62

    Article  CAS  Google Scholar 

  22. Urraca JL, Moreno-Bondi MC, Hall AJ, Sellergren B (2007) Anal Chem 79:695–701

    Article  CAS  Google Scholar 

  23. Caro E, Marce RM, Cormack Peter AG, Sherrington DC, Borrull F (2003) J Chromatogr A 995:233–238

    Article  CAS  Google Scholar 

  24. Masque N, Marce RM, Borrull F, Cormack PAG, Sherrington DC (2000) Anal Chem 72:4122–4126

    Article  CAS  Google Scholar 

  25. Garcia R, Pinel C, Madic C, Lemaire M (1998) Tetrahedron Lett 39:8651–8654

    Article  CAS  Google Scholar 

  26. Möller K, Nilsson U, Crescenzi C (2001) J Chromatogr A 938:121–130

    Article  Google Scholar 

  27. Tsuru N, Kikuchi M, Kawaguchi H, Shiratori S (2006) Thin Solid Films 449:380–385

    Article  Google Scholar 

  28. He DY, Zhang ZJ, Zhou HJ, Huang Y (2006) Talanta 69:1215–1220

    Article  CAS  Google Scholar 

  29. Lavignac N, Allender CJ, Brain KR (2004) Anal Chim Acta 510:139–145

    Article  CAS  Google Scholar 

  30. Piletsky SA, Piletska EV, Bossi A, Karim K, Lowe P, Turner APF (2001) Biosens Bioelectron 16:701–707

    Article  CAS  Google Scholar 

  31. Huang JT, Zheng SH, Zhang JQ (2004) Polymer 45:4349–4354

    Article  CAS  Google Scholar 

  32. Southard GE, Van Houten KA, Murray GM (2007) Macromolecules 40:1395–1400

    Article  CAS  Google Scholar 

  33. Xiong Y, Zhou HJ, Zhang ZJ, He DY, He C (2007) Spectrochim Acta A 66:341–346

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 20437020 and 20621703) and the Major Research Program of the Chinese Academy of Sciences (KZCX3-SW-432).

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Authors and Affiliations

  1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P. O. Box 2871, Beijing, 100085, China

    Qin-Zhong Feng, Li-Xia Zhao, Wei Yan, Feng Ji, Yan-Lin Wei & Jin-Ming Lin

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  1. Qin-Zhong Feng
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  2. Li-Xia Zhao
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  3. Wei Yan
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  4. Feng Ji
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Correspondence to Li-Xia Zhao or Jin-Ming Lin.

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Feng, QZ., Zhao, LX., Yan, W. et al. Molecularly imprinted solid-phase extraction and flow-injection chemiluminescence for trace analysis of 2,4-dichlorophenol in water samples. Anal Bioanal Chem 391, 1073–1079 (2008). https://doi.org/10.1007/s00216-008-2059-z

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  • DOI: https://doi.org/10.1007/s00216-008-2059-z

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